(11bR, 11'bR)-4,4'-(Oxydi-2,1-phenylene)bis-dinaphtho[2,1-d:, 1', 2'-f][1,3,2]dioxaphosphepin (11bS, 11′bS)-4,4′-(氧代二-2,1-亚苯基)双-二萘并[2,1-d: 1′, 2′-f][1,3,2]二噁磷环庚烷

CAS 898830-89-2 MFCD09842741

化学结构图

898830-89-2
SMILES:

化学属性

Mol. FormulaC52H32O5P
Mol. Weight767.78
Melting Point174-186 °C

别名和识别编码

Chemical Name(11bS, 11'bS)-4,4'-(Oxydi-2,1-phenylene)bis-dinaphtho[2,1-d: 1', 2'-f][1,3,2]dioxaphosphepin
Synonym (11bR, 11′bR)-4,4′-(氧代二-2,1-亚苯基)双-二萘并[2,1-d:, 1′, 2′-f][1,3,2]二噁磷环庚烷 (11bS, 11′bS)-4,4′-(氧代二-2,1-亚苯基)双-二萘并[2,1-d: 1′, 2′-f][1,3,2]二噁磷环庚烷 S, S-Reetz D-双亚磷酸酯
MDL NumberMFCD09842741
CAS Number898830-89-2
Chemical Name Translation(11bS, 11′bS)-4,4′-(氧代二-2,1-亚苯基)双-二萘并[2,1-d: 1′, 2′-f][1,3,2]二噁磷环庚烷
PubChem Substance ID329760785
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分类

  • Asymmetric Synthesis, Chemical Synthesis, Chiral Catalysts, Ligands, and Reagents, Hydrogenation, Privileged Ligands and Complexes, Reetz Ligands
  • {SNA} Asymmetric Synthesis, Chemical Synthesis, Chiral Catalysts, Ligands, and Reagents, Hydrogenation, Privileged Ligands and Complexes, Reetz Ligands

相关文献及参考

  • 1. Reetz, M. T.; Moulin, D.; Gosberg, A. Org. Lett. 3 , 4083, (2001) 摘要
  • 2. Reetz, M. T.; Li, X. Adv. Synth. Catal. 348 , 1157, (2006)

安全信息

GHS Symbol
WGK Germany3
Precautionary statements
  • P301+P310
  • P210 Keep away from heat/sparks/open flames/hot surfaces. — No smoking. 远离热源/火花/明火/热的表面。——禁止吸烟。
  • P331 Do NOT induce vomiting.. 不要催吐。
  • P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P281 Use personal protective equipment as required. 使用所需的个人防护装备。
Signal word Danger
Hazard statements
  • H228 Flammable solid 易燃固体
  • H315 Causes skin irritation 会刺激皮肤
  • H361d Suspected of damaging the unborn child 怀疑对未出生婴儿造成伤害
  • H373 May causes damage to organs through prolonged or repeated exposure 长期或频繁接触可能会损伤器官
  • H336 May cause drowsiness or dizziness 肯能导致嗜睡或头晕
Personal Protective Equipment dust mask type N95 (US), Eyeshields, full-face particle respirator type N100 (US), Gloves, respirator cartridge type N100 (US), type P1 (EN143) respirator filter, type P3 (EN 143) respirator cartridges dust mask type N95 (US), Eyeshields, Gloves
Safety Statements
  • S36/37 Wear suitable protective clothing and gloves 穿戴适当的防护服和手套；
Hazard Codes Xn F,Xn
Risk Statements
  • R11 Highly flammable 非常易燃
  • R63 Possible risk of harm to the unborn child 可能危害未出生婴儿
  • R48/20
  • R67 Vapours may cause drowsiness and dizziness 蒸汽可能导致嗜睡和昏厥

系列性分类

  1. Chemical Synthesis 化学合成
  2. Asymmetric Synthesis 不对称合成
  3. Chiral Catalysts, Ligands, and Reagents - Asymmetric Synthesis
  4. Privileged Ligands and Complexes - Chiral Catalysts, Ligands, and Reagents
  5. Reetz Ligands - Privileged Ligands and Complexes

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