4-Benzyloxyphenol 4-苄氧基苯酚

CAS 103-16-2 MFCD00002333

化学结构图

103-16-2
SMILES: OC1CCC(OCc2ccccc2)CC1

化学属性

Mol. FormulaC13H12O2
Mol. Weight200.23
Melting Point119-120°C
Density1.260
TSCAYes
Solubility不溶于水,溶于有机溶剂
Boiling Point297.96 °C at 760 mmHg

别名和识别编码

Chemical Name4-Benzyloxyphenol
CAS Number103-16-2
Alfabeta NameBENZYLOXYPHENOL 4-
MDL NumberMFCD00002333
Synonym Monobenzone {LY} Monobenzone {} {LY} Monobenzone {} {} {LY} Monobenzone {} {} {} {LY} Monobenzone {} {} {} {} {LY} Monobenzone {} {} {} {} {} {LY} Monobenzone {} {} {} {} {} {} {LY} Monobenzone {} {} {} {} {} {} {} {LY} Monobenzone {} {} {} {} {} {} {} {} {LY} Monobenzone {} {} {} {} {} {} {} {} {} {LY} Monobenzone {} {} {} {} {} {} {} {} {} {} {LY} Monobenzone {} {} {} {} {} {} {} {} {} {} {} {LY} Monobenzone {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Monobenzone {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Monobenzone {} {} {} {} {} {} {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Monobenzone {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Monobenzone {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Monobenzone {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Monobenzone {} {} {} {} {} {} {} {}
PubChem Substance ID87564047
EC Number203-083-3
Beilstein Registry Number1958305
Reaxys-RN1958305
Merck Number6248
Chemical Name Translation4-苄氧基苯酚
Wiswesser Line NotationQR DO1R
LabNetwork Molecule IDLN00007635
InChIInChI=1S/C13H12O2/c14-12-6-8-13(9-7-12)15-10-11-4-2-1-3-5-11/h1-9,14H,10H2
Canonical SMILESOC1=CC=C(C=C1)OCC2=CC=CC=C2
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分类

  • {SNA} B, Bioactive Small Molecules, Building Blocks, C9 to C20+, Chemical Synthesis, Organic Building Blocks, Oxygen Compounds, Phenols, 细胞生物学
  • B, Bioactive Small Molecules, Building Blocks, C9 to C20+, Cell Biology, Chemical Synthesis, Organic Building Blocks, Oxyg
  • {SNA} B, Bioactive Small Molecules, Building Blocks, C9 to C20+, Cell Biology, Chemical Synthesis, Organic Building Blocks, Oxygen Compounds, Phenols
  • {uni_hamburg} no charge; carbocycle; aromatic; 6RingOnly; 6ring; alcohol; ether; 1fragment

相关文献及参考

  • Short: LC
  • Short: VIII/5A
  • Short: IV/7b
  • Short: III/5a
  • Merck:14,6248 Beilstein:6(3)4402
  • Merck:14,6248

安全信息

Warnings IRRITANT
GHS Symbol
WGK Germany2
Hazard statements
  • H316 Causes mild skin irritation 会轻微的刺激皮肤
  • H317 May cause an allergic skin reaction 可能导致皮肤过敏
  • H319 Causes serious eye irritation 严重刺激眼睛
Personal Protective Equipment dust mask type N95 (US), Eyeshields, Faceshields, Gloves
Hazard Codes Xi
RTECSSJ7700000
Precautionary statements
  • P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
  • P272 Contaminated work clothing should not be allowed out of the workplace. 污染的工作服不得带出工作场所。
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P302+P350
  • P302+P352+P333+P313+P362+P364
  • P305+P351+P338
  • P305+P351+P338+P337+P313
  • P333+P313
  • P337+P313
  • P501 Dispose of contents/container to..… 处理内容物/容器.....
Signal word Warning
Safety Statements
  • S24/25 Avoid contact with skin and eyes 避免皮肤和眼睛接触;
  • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后,立即用大量水冲洗并征求医生意见;
  • S37 Wear suitable gloves 戴适当手套;
Risk Statements
  • R36 Irritating to eyes 刺激眼睛
  • R43 May cause sensitisation by skin contact 皮肤接触会产生过敏反应
Storage condition 2-8°C {LY} 2-8°C {} {LY} 2-8°C {} {} {LY} 2-8°C {} {} {} {LY} 2-8°C {} {} {} {} {LY} 2-8°C {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {
TYPE OF TEST            : TDLo - Lowest published toxic dose
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Rodent - mouse
DOSE/DURATION           : 163 gm/kg/78W-I
TOXIC EFFECTS :
   Tumorigenic - equivocal tumorigenic agent by RTECS criteria
   Lungs, Thorax, or Respiration - tumors
   Liver - tumors
REFERENCE :
   NTIS** National Technical Information Service.  (Springfield, VA 22161)
   Formerly U.S. Clearinghouse for Scientific & Technical Information.
   Volume(issue)/page/year: PB223-159

TYPE OF TEST            : TDLo - Lowest published toxic dose
ROUTE OF EXPOSURE       : Subcutaneous
SPECIES OBSERVED        : Rodent - mouse
DOSE/DURATION           : 1000 mg/kg
TOXIC EFFECTS :
   Tumorigenic - neoplastic by RTECS criteria
   Lungs, Thorax, or Respiration - tumors
   Blood - tumors
REFERENCE :
   NTIS** National Technical Information Service.  (Springfield, VA 22161)
   Formerly U.S. Clearinghouse for Scientific & Technical Information.
   Volume(issue)/page/year: PB223-159

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Intraperitoneal
SPECIES OBSERVED        : Rodent - rat
DOSE/DURATION           : 4500 mg/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   85KYAH "Merck Index; an Encyclopedia of Chemicals, Drugs, and Biologicals",
   11th ed., Rahway, NJ 07065, Merck & Co., Inc. 1989 Volume(issue)/page/year:
   11,983,1989

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Intraperitoneal
SPECIES OBSERVED        : Rodent - mouse
DOSE/DURATION           : >600 mg/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   IPSTB3 International Polymer Science and Technology.  (Rapra Technology
   Ltd., Shawbury, Shrewsbury, Shropshire SY4 4NR, UK) Volume(issue)/page/year:
   3,93,1976

其他信息

  • 外观:白色晶体
  • 微溶于水,极易溶于乙醇、苯、乙醚;溶于丙酮和碱,实际上不溶于石油醚和烃。
  • 4-苄氧基苯酚价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2014/06/02 B1104 4-(苄氧基)苯酚 4-(Benzyloxy)phenol 500G 3590元 2014/06/02 B1104 4-(苄氧基)苯酚 4-(Benzyloxy)phenol 25G 423元 2010/06/21 169780500 4-苄氧基苯酚 4-Benzyloxyphenol 98% 50 GR 745元
  • Alfa Aesar:4-苯甲氧基苯酚,98+% 4-Benzyloxyphenol, 98+%(103-16-2)
  • 毒性分级:中毒
  • 用途一:用作医药中间体
  • 海关编码:29095090
  • 可燃性危险特性:可燃; 燃烧释放刺激烟雾
  • MOL 文件:103-16-2.mol
  • Sigma Aldrich:103-16-2(sigmaaldrich)
  • 脱色剂:4-苄氧基苯酚是一种局部使用的脱色剂,能分解皮肤中的黑色素(melamin),阻止皮肤中黑色素的生成,使皮肤恢复健康的色泽,而并不破坏黑色素细胞,从而起到脱色的作用。临床上主要用于治疗色素沉着过度,如各种色斑、老年斑、白癜风、黑色素瘤等。
  • MSDS 信息:对苄氧基苯酚(103-16-2).msds
  • Acros Organics:4-苄氧基苯酚 4-Benzyloxyphenol, 98%(103-16-2)
  • Hazard Note:Irritant
  • 储运特性:库房通风低温干燥; 与食品原料分开存放
  • 刺激数据:皮肤-豚鼠5%/48小时 轻度
  • 灭火剂:干粉、泡沫、砂土、二氧化碳, 雾状水
  • TCI Shanghai:4-苄氧基苯酚 4-(Benzyloxy)phenol,>;99.0%(GC)(103-16-2)
  • 急性毒性:腹腔-大鼠 LD50:4500 毫克/公斤
  • 图谱信息:4-苄氧基苯酚(103-16-2)核磁图( 1 HNMR) 4-苄氧基苯酚(103-16-2)红外图谱(IR1) 4-苄氧基苯酚(103-16-2)红外图谱(IR2) 4-苄氧基苯酚(103-16-2)核磁图( 13 CNMR) 4-苄氧基苯酚(103-16-2)质谱(MS)
  • 类别:有毒物品

系列性分类