Isopropenyl acetate 乙酸异丙烯酯
CAS 108-22-5 MFCD00008709
化学结构图
SMILES: C=C(C)OC(C)=O
化学属性
| Mol. Formula | C5H8O2 |
|---|---|
| Mol. Weight | 100 |
| Refractive index | 1.3990 to 1.4020 |
| Boiling Point | 94 |
| Density | 0.909 |
| Flash Point | 16°C(lit.) |
| TSCA | Yes |
| Melting Point | -73°C |
| Solubility | 可混溶于醇、醚、酮等。 |
别名和识别编码
| Chemical Name | Isopropenyl acetate |
|---|---|
| Synonym | 1-Acetoxy-1-methylethylene 1-Propen-2-ol, acetate 1-Propen-2-yl acetate 1-甲基乙烯基乙酸酯 1-甲基乙烯基乙酸酯 IPA 2-Acetoxypropene 2-Propenyl acetate 2-acetoxy-propene Acetic Acid Isopropenyl Ester Aceton-enolacetat Acetonenolacetat Essigsäure-isopropenylester Essigsäureisopropenylester Propen-2-yl acetate acetic acid isopropenyl ester 乙酸异丙烯酯 醋酸异丙烯酯 |
| CAS Number | 108-22-5 |
| PubChem Substance ID | 87561738 |
| EC Number | 203-562-7 |
| Beilstein Registry Number | 1280347 |
| MDL Number | MFCD00008709 |
| Reaxys-RN | 1280347 |
| Merck Number | 5203 |
| Chemical Name Translation | 乙酸异丙烯酯 |
| Wiswesser Line Notation | 1VOY1&U1 |
| LabNetwork Molecule ID | LN00223719 |
信息真实价格透明
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信息真实价格透明
资金保障
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现货库存
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分类
- {uni_hamburg} no charge; ester; 1fragment
- Building Blocks, C2 to C5, Carbonyl Compounds, Chemical Synthesis, Esters, Organic Building Blocks
- {SA} Building Blocks, C2 to C5, Carbonyl Compounds, Chemical Synthesis, Esters, Organic Building Blocks
产品应用
- 烯醇的乙酰化和烷基化剂。
相关文献及参考
- Merck:14,5203 Beilstein:2(4)179
- Crossed aldol condensations with acetals are promoted by Lewis acids, e.g. TiCl4 to give ß-alkoxy ketones: Chem. Lett., 323 (1974).
- Merck:14,5203
- {A
- Short: III/38B
- For the (2 + 2) photochemical cycloaddition with isophorone, see: Org. Synth. Coll., 6, 1024 (1988).
- Short: IV/18B
- Enol acetate of acetone. Other carbonyl compounds can be converted to their enol acetates by exchange; see, e.g.: J. Org. Chem., 30, 2502 (1965).
安全信息
GHS Symbol
- H225 Highly flammable liquid and vapour 高度易燃液体和蒸气
- H335 May cause respiratory irritation 可能导致呼吸道刺激
- P210 Keep away from heat/sparks/open flames/hot surfaces. — No smoking. 远离热源/火花/明火/热的表面。——禁止吸烟。
- P233 Keep container tightly closed. ?保持容器密闭。
- P240 Ground/bond container and receiving equipment. 与地面接触/连接集装箱和接受设备。
- P241+P242+P243
- P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
- P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
- P303+P361+P353
- P305+P351+P338
- P305+P351+P338+P337+P313
- P312 Call a POISON CENTER or doctor/physician if you feel unwell. 如果你感觉不适，呼叫解毒中心或医生/医师。
- P332+P313
- P370+P378
- P403+P235
- P501 Dispose of contents/container to..… 处理内容物/容器.....
- S16 Keep away from sources of ignition - No smoking 远离火源，禁止吸烟；
- S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后，立即用大量水冲洗并征求医生意见；
- S29 Do not empty into drains 不要排入下水道；
- S33 Take precautionary measures against static discharges 对静电采取预防措施；
- S36/37/39 Wear suitable protective clothing, gloves and eye/face protection 穿戴适当的防护服、手套和眼睛/面保护；
- S9 Keep container in a well-ventilated place 保持容器在通风良好的场所；
- R11 Highly flammable 非常易燃
TYPE OF TEST : LD50 - Lethal dose, 50 percent kill ROUTE OF EXPOSURE : Oral SPECIES OBSERVED : Rodent - rat DOSE/DURATION : 3 gm/kg TOXIC EFFECTS : Details of toxic effects not reported other than lethal dose value REFERENCE : JIHTAB Journal of Industrial Hygiene and Toxicology. (Cambridge, MA) V.18-31, 1936-49. For publisher information, see AEHLAU. Volume(issue)/page/year: 31,60,1949
其他信息
- 水溶性: 34 g/l 水 (20°C) ，几乎和所有有机溶剂混溶。
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