Vanadium(III) Acetylacetonate 乙酰丙酮钒

CAS 13476-99-8 MFCD00000033

化学结构图

13476-99-8
SMILES: CC(=O)/C=C(/C)\O[V](O/C(/C)=C\C(C)=O)O/C(/C)=C\C(C)=O

化学属性

Mol. FormulaV(C5H7O2)3
Mol. Weight348.27
Melting Point181-184 °C(lit.)
TSCAYes
Stability对空气敏感
Appearance brown xtl.
Boiling Pointsubl. (170°C/0.05mm)

别名和识别编码

Chemical NameVanadium(III) Acetylacetonate
MDL NumberMFCD00000033
CAS Number13476-99-8
Synonym NSC 177701 Tris(acetylacetonato)vanadium(III) 三乙酰丙酮钒 O)钒 Vanadium acetylacetonate Vanadium(III)acetylacetonat Vanadium, tris(2,4-pentanedionato-κO,κO')-, (OC-6-11)- Vanadium, tris(2,4-pentanedionato-kO,kO')-, (OC-6-11)- Vanadium(III) acetylacetonate 乙酰丙酮钒 Vanadium(III) 2,4-pentanedionate Vanadium tris(acetylacetonate) Vanadium, tris(2,4-pentanedionato)- 4-戊二酸-O Tris(2,4-pentanedionato)vanadium Vanadium(III)-acetylacetonat 三(2 三乙酰丙酮钒,三(2,4-戊二酸-O,O)钒 Tris(acetylacetonato)vanadium 2,4-戊二酮 钒(III) 衍生物 乙酰丙酮钒(III) Vanadium, tris(2,4-pentanedionato-O,O')-, (OC-6-11)- Vanadium (III) 2,4-pentanedionate tris(pentane-2,4-dionato-O,O')vanadium α-Tris(2,4-pentanedionato)-vanadium(III) Tris-(2,4-pentandionato)-vanadium Vanadium(III) tris(acetylacetonate)
Beilstein Registry Number4148970
PubChem Substance ID24853612
EC Number236-759-1
Chemical Name Translation乙酰丙酮钒
InChIKeyZVFSRLXFKIWGRT-UHFFFAOYSA-N
LabNetwork Molecule IDLN02124322
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分类

  • {SNA} Catalysis and Inorganic Chemistry, Chemical Synthesis, Materials Science, Micro/NanoElectronics, Solution Deposition Precursors, Vanadium
  • {uni_hamburg} no charge; oxygen heterocycle; other heterocycle; fused rings; 6RingOnly; 6ring; 1fragment; zwitterion
  • {SNA} Catalysis and Inorganic Chemistry, Chemical Synthesis, Micro/NanoElectronics, Solution Deposition Precursors, Vanadium, 材料科学
  • Catalysis and Inorganic Chemistry, Chemical Synthesis, Materials Science, Micro/NanoElectronics, Solution Deposition Precursors, Vanadium

产品应用

  • 用作有机合成催化剂、树脂固化促进剂。

相关文献及参考

  • Beilstein: 1,IV,3672
  • Short: EINECS
  • Short: III/10a

安全信息

Precautionary statements
  • P301+P310
  • P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P305+P351+P338
Safety Statements
  • S27 Take off immediately all contaminated clothing 立即脱掉全部污染的衣服;
  • S20 When using do not eat or drink 使用时,不得进食,饮水;
  • S45 In case of accident or if you feel unwell seek medical advice immediately (show the label where possible) 发生事故时或感觉不适时,立即求医(可能时出示标签);
  • S60 This material and its container must be disposed of as hazardous waste 该物质及其容器必须作为危险废物处置;
  • S36/37/39 Wear suitable protective clothing, gloves and eye/face protection 穿戴适当的防护服、手套和眼睛/面保护;
  • S4 Keep away from living quarters 远离生活区;
  • S9 Keep container in a well-ventilated place 保持容器在通风良好的场所;
  • S36 Wear suitable protective clothing 穿戴适当的防护服;
  • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后,立即用大量水冲洗并征求医生意见;
WGK Germany3
GHS Symbol
Signal word Danger Warning
Hazard statements
  • H315 Causes skin irritation 会刺激皮肤
  • H319 Causes serious eye irritation 严重刺激眼睛
  • H335 May cause respiratory irritation 可能导致呼吸道刺激
  • H301 Toxic if swallowed 吞食有毒
Hazard Codes T Xi
Risk Statements
  • R25 Toxic if swallowed 吞咽有毒
  • R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
  • R23/24/25 Toxic by inhalation, in contact with skin and if swallowed 吸入,皮肤接触及吞食都有毒
Personal Protective Equipment dust mask type N95 (US), Eyeshields, Gloves
UN Number 3285 UN3285
Storage condition 对空气敏感,密封保存。 Air Sensitive
Packing GroupIII

其他信息

  • 对空气敏感。

系列性分类


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