4-Fluorobenzylamine 对氟苄胺

CAS 140-75-0 MFCD00008120

化学结构图

140-75-0
SMILES: NCc1ccc(F)cc1

化学属性

Mol. FormulaC7H8FN
Mol. Weight125
Boiling Point183°C(lit.)
Refractive index1.5120 to 1.5150
Density1.095
Flash Point66°C(lit.)
TSCAYes

别名和识别编码

Chemical Name4-Fluorobenzylamine
CAS Number140-75-0
Alfabeta NameFLUOROBENZYLAMINE 4-
MDL NumberMFCD00008120
Synonym Benzylamine, p-fluoro- 4-Fluorobenzenemethanamine 4-FLUOROBENZYLAMINE 98+% 对氟苄胺 AURORA KA-7685 LABOTEST-BB LTBB000702 4-Fluorobenzylamine 98% (4-Fluorophenyl)methanamine AKOS BBS-00003618 4-fluoroBenzenemethanamine 1-(4-Fluorophenyl)methanamine 4-氟苄胺, 97+% P-FLUOROBENZYLAMINE 对氟苄胺(对氟苯甲胺) 4-FLUOROBENZYLAMINE, 97+% 4-氟卞胺 [(4-Fluorophenyl)methyl]amine 4-fluoro-benzenemethanamin 4-FLUOROBENZYLAMINE Benzenemethanamine, 4-fluoro- Para Fluorobenzyamine p-Fluorobenzylamine 对氟苯甲胺 4-氟苄胺 RARECHEM AL BW 0026 NSC 158269 4-氟苯甲胺 4-Fluorobenzylamine ,99%
PubChem Substance ID87570029
EC Number205-430-4
Beilstein Registry Number636501
Reaxys-RN636501
Chemical Name Translation对氟苄胺
InChIKeyIIFVWLUQBAIPMJ-UHFFFAOYSA-N
LabNetwork Molecule IDLN00159960
InChIInChI=1S/C7H8FN/c8-7-3-1-6(5-9)2-4-7/h1-4H,5,9H2
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分类

  • {SNA} Amines, Aryl Fluorinated Building Blocks, Building Blocks, C7, C7-C8, Chemical Synthesis, Fluorinated Building Blocks, Nitrogen Compounds, Organic Building Blocks, Organic Fluorinated Building Blocks, Other Fluorinated Organic Building Blocks
  • Amines, Aryl Fluorinated Building Blocks, Bioactive Small Molecules, Building Blocks, C7, C7-C8, Cell Biology, Chemical Synthesis, F, Fluorinated Building Blocks, Nitrogen Compounds, Organic Building Blocks, Organic Fluorinated Building Blocks, Other Fluorinated Organic Building Blocks
  • {SNA} Am

产品应用

  • 抗过敏药物阿司咪唑,镇痛药Flupirine的中间体。

相关文献及参考

  • Beilstein: 12,IV,2358
  • ########

安全信息

Warnings AIR SENSITIVE, CORROSIVE
GHS Symbol
WGK Germany3
Hazard statements
  • H227 Combustible liquid 可燃液体
  • H314 Causes severe skin burns and eye damage 导致严重的皮肤灼伤和眼睛损伤
Personal Protective Equipment Faceshields, full-face respirator (US), Gloves, Goggles, multi-purpose combination respirator cartridge (US), type ABEK (EN14387) respirator filter
Hazard Codes C C,Xi
Precautionary statements
  • P210 Keep away from heat/sparks/open flames/hot surfaces. — No smoking. 远离热源/火花/明火/热的表面。——禁止吸烟。
  • P260 Do not breathe dust/fume/gas/mist/vapours/spray. 不要吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P301+P330+P331
  • P301+P330+P331+P310
  • P303+P361+P353+P310+P363
  • P304+P340
  • P304+P340+P310
  • P305+P351+P338
  • P305+P351+P338+P310
  • P314 Get medical advice/attention if you feel unwell. 获取医疗咨询/就医,如果你觉得不舒服
  • P361 Remove/Take off immediately all contaminated clothing. 立即去除/脱掉所有被污染的衣服。
  • P403+P235
  • P405 Store locked up. 上锁保管。
  • P501 Dispose of contents/container to..… 处理内容物/容器.....
Signal word
Safety Statements
Risk Statements
  • R34 Causes burns 会导致灼伤
  • R20/21/22 Harmful by inhalation, in contact with skin and if swallowed 吸入、皮肤接触和不慎吞咽有害
  • R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
UN Number 2735
Storage condition Air Sensitive
Packing GroupIII
Hazard Class8

其他信息

  • Sigma Aldrich:140-75-0(sigmaaldrich)
  • 用途一:用作医药、农药中间体
  • 方法一:在100ml反应瓶中加入N-(4-氟苯甲基)邻苯二甲酰亚胺25.5g(0.1mol)和25ml无水乙醇,再加入80%水合肼溶液6.3g(0.1mol),加热回流0.5g。加入过量的盐酸使析出的白色沉淀分解,冷却后加入适量的水搅拌,抽滤。滤液用NaOH溶液中和,用乙醚萃取,乙醚萃取液干燥后蒸除乙醚,减压蒸馏,收集44-46℃(67kPa)馏分,得对氟苄胺7.1g,收率56.5%。
  • 检测方法:GC
  • 海关编码:29214980
  • 敏感性:Air Sensitive
  • 下游产品:氟吡汀 --> 3-二已胺荃-1-丙胺
  • Alfa Aesar:4-氟苄胺,97% 4-Fluorobenzylamine, 98+%(140-75-0)
  • Acros Organics:4-氟苄胺 4-Fluorobenzylamine, 97%(140-75-0)
  • F:10-34
  • TCI Shanghai:4-氟苯甲胺 4-Fluorobenzylamine,>;98.0%(GC)(140-75-0)
  • 图谱信息:对氟苄胺(140-75-0)红外图谱(IR1) 对氟苄胺(140-75-0)质谱(MS)
  • 对氟苄胺价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2014/06/02 F0252 4-氟苯甲胺 4-Fluorobenzylamine 25G 558元 2010/06/21 SB01159EB 对氟苄胺 4-fluorobenzylamine 25 GR 360元 2010/06/21 171950250 对氟苄胺 4-Fluorobenzylamine 97% 25 GR 709元
  • MSDS 信息:4-Fluorobenzylamine(140-75-0).msds
  • Hazard Note:Irritant
  • 用途二:抗过敏药物阿司咪唑,镇痛药Flupirine的中间体。
  • MOL 文件:140-75-0.mol
  • 上游原料:邻苯二甲酰亚胺 --> 4-氟苯

系列性分类


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