Carbonylchlorohydridotris(triphenylphosphine)ruthenium(II) 羰基氯氢三(三苯基膦)钌(II)

CAS 16971-33-8 MFCD00049804

化学结构图

16971-33-8
SMILES: [C-]#[O+].Cl[Ru].C1=CC=CC=C1P(C1C=CC=CC=1)C1C=CC=CC=1.C1=CC=CC=C1P(C1C=CC=CC=1)C1C=CC=CC=1.C1=CC=CC=C1P(C1C=CC=CC=1)C1C=CC=CC=1

化学属性

Mol. Formula[(C6H5)3P]3Ru(CO)(Cl)H
Mol. Weight952.40
Melting Point204-206 °C (dec.)(lit.)
TSCANo
Solubility不溶
Appearance off-white to tan pwdr.

别名和识别编码

Chemical NameCarbonylchlorohydridotris(triphenylphosphine)ruthenium(II)
MDL NumberMFCD00049804
PubChem Substance ID24860276
EC Number241-051-0
CAS Number16971-33-8
Synonym 羰基氯氢三(三苯基膦)钌(II) Carbonylchlorohydridotris(triphenylphosphine)ruthenium(II)
Chemical Name Translation羰基氯氢三(三苯基膦)钌(II)
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分类

  • {SNA} Catalysis and Inorganic Chemistry, Chemical Synthesis, Ru Catalysts, Ruthenium Catalysts

安全信息

WGK Germany3
GHS Symbol
Precautionary statements
  • P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P305+P351+P338
Signal word Warning
Hazard statements
  • H315 Causes skin irritation 会刺激皮肤
  • H335 May cause respiratory irritation 可能导致呼吸道刺激
  • H319 Causes serious eye irritation 严重刺激眼睛
  • H302+H312+H332
  • H332 Harmful if inhaled 吸入有害
  • H302 Harmful if swallowed 吞食有害
  • H312 Harmful in contact with skin 皮肤接触有害
Personal Protective Equipment dust mask type N95 (US), Eyeshields, Gloves
Safety Statements
  • S22 Do not breathe dust 不要吸入粉尘；
  • S36/37/39 Wear suitable protective clothing, gloves and eye/face protection 穿戴适当的防护服、手套和眼睛/面保护；
  • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后，立即用大量水冲洗并征求医生意见；
  • S36/37 Wear suitable protective clothing and gloves 穿戴适当的防护服和手套；
  • S37/39 Wear suitable gloves and eye/face protection 穿戴适当的手套和眼睛/面保护；
Risk Statements
  • R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
  • R20/21/22 Harmful by inhalation, in contact with skin and if swallowed 吸入、皮肤接触和不慎吞咽有害
  • R22 Harmful if swallowed 吞咽有害
Storage condition Moisture & Light Sensitive
Hazard Codes Xn

系列性分类

  1. Chemical Synthesis 化学合成
  2. Catalysis and Inorganic Chemistry 催化剂和无机化学
  3. Ruthenium 钌
  4. Ru Catalysts - Ruthenium
  1. Catalysts
  2. Ruthenium

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