1,2:5,6-Bis-O-(1-Methylethylidene)-D-Mannitol 双丙酮-D-甘露糖醇

CAS 1707-77-3 MFCD00003211

化学结构图

1707-77-3
SMILES: CC1(C)OC[C@H]([C@@H](O)[C@H](O)[C@H]2COC(C)(C)O2)O1

化学属性

Mol. FormulaC12H22O6
Mol. Weight262.30
Melting Point120-122°C
TSCANo
Density1.175
Solubilitymethanol: 100 mg/mL, clear, colorless
Refractive index6.5 ° (C=8, CHCl3)
Boiling Point382°C at 760 mmHg

别名和识别编码

Chemical Name1,2:5,6-Bis-O-(1-Methylethylidene)-D-Mannitol
CAS Number1707-77-3
Alfabeta NameBISMETHYLETHYLIDENEMANNITOL :OD12561()------,,
MDL NumberMFCD00003211
Synonym Diacetone-D-mannitol, 97% {LY} Diacetone-D-mannitol, 97% {} {LY} Diacetone-D-mannitol, 97% {} {} {LY} Diacetone-D-mannitol, 97% {} {} {} {LY} Diacetone-D-mannitol, 97% {} {} {} {} {LY} Diacetone-D-mannitol, 97% {} {} {} {} {} {LY} Diacetone-D-mannitol, 97% {} {} {} {} {} {} {LY} Diacetone-D-mannitol, 97% {} {} {} {} {} {} {} {LY} Diacetone-D-mannitol, 97% {} {} {} {} {} {} {} {} {LY} Diacetone-D-mannitol, 97% {} {} {} {} {} {} {} {} {} {LY} Diacetone-D-mannitol, 97% {} {} {} {} {} {} {} {} {} {} {LY} Diacetone-D-mannitol, 97% {} {} {} {} {} {} {} {} {} {} {} {LY} Diacetone-D-mannitol, 97% {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Diacetone-D-mannitol, 97% {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Diacetone-D-mannitol, 97% {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Diacetone-D-mannitol, 97% {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY
PubChem Substance ID96011
Beilstein Registry Number83765
EC Number216-954-8
Reaxys-RN83765
Chemical Name Translation双丙酮-D-甘露糖醇
InChIKeyODYBCPSCYHAGHA-ZYUZMQFOSA-N
LabNetwork Molecule IDLN00011222
Canonical SMILESO[C@H]([C@]1([H])OC(C)(OC1)C)[C@@H]([C@]2([H])OC(C)(OC2)C)O
InChIInChI=1S/C12H22O6/c1-11(2)15-5-7(17-11)9(13)10(14)8-6-16-12(3,4)18-8/h7-10,13-14H,5-6H2,1-4H3/t7-,8-,9-,10-/m1/s1
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分类

  • Pharmaceuticals
  • {SNA} Carbohydrate Chemistry, Carbohydrate Derivatives, Chemical Biology, Chemical Synthesis
  • Chiral Reagents
  • Intermediates & Fine Chemicals

产品应用

  • Nebivolol intermediate.

相关文献及参考

  • Beilstein:19(1)826
  • Ono, Y., et al.: Steroids, 71, 529 (2006),
  • Treatment with NaIO 4 affords the useful synthon 2,3-O-isopropylidene-D-glyceraldehyde (glyceraldehyde acetonide): J. Org. Chem., 56, 4056 (1991); Org. Synth. Coll., 9, 450 (1998). This in turn can be homologated diastereoselectively using 2-(Trimethyl­silyl)­thiazole, B21903: Org. Synth. Coll., 9, 52 (1998). For use of Pb(OAc) 4 in the formation of glyceraldehyde acetonide as a chiral precursor of cyclopropyl carbocyclic nucleosides as HIV reverse transcriptase inhibitors, see: J. Org. Chem., 60, 5236 (1995).

安全信息

Warnings IRRITANT
WGK Germany3
Personal Protective Equipment Eyeshields, Gloves, type N95 (US), type P1 (EN143) respirator filter
Signal word Warning
GHS Symbol
Safety Statements
  • S24/25 Avoid contact with skin and eyes 避免皮肤和眼睛接触;
Risk Statements
  • R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
Precautionary statements
  • P262 Do not get in eyes, on skin, or on clothing. 不要接触眼睛,皮肤或衣服。
Storage condition 2-8°C {LY} 2-8°C {} {LY} 2-8°C {} {} {LY} 2-8°C {} {} {} {LY} 2-8°C {} {} {} {} {LY} 2-8°C {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {

其他信息

  • 比旋光度:6 ° (c=5, Chloroform)
  • 双丙酮-D-甘露糖醇价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2014/06/02 D2024 1,2:5,6-二-O-亚异丙基-D-甘露醇 1,2:5,6-Di-O-isopropylidene-D-mannitol 5G 445元 2014/06/02 D2024 1,2:5,6-二-O-亚异丙基-D-甘露醇 1,2:5,6-Di-O-isopropylidene-D-mannitol 25G 1360元 2010/05/25 L12127 1,2,5,6-二邻异亚丙基-D-甘露醇 1,2:5,6-Di-O-isopropylidene-D-mannitol 5g 435元
  • Alfa Aesar:1,2,5,6-二邻异亚丙基-D-甘露醇 1,2:5,6-Di-O-isopropylidene-D-mannitol(1707-77-3)
  • 下游产品:(R)-(-)-甘油醇缩丙酮
  • Sigma Aldrich:1707-77-3(sigmaaldrich)
  • F:10-21
  • MOL 文件:1707-77-3.mol
  • TCI Shanghai:双丙酮-D-甘露糖醇 1,2:5,6-Di-O-isopropylidene-D-mannitol,>;95.0%(GC)(1707-77-3)

系列性分类


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