Biphenyl-4-boronic Acid 4-联苯硼酸

CAS 5122-94-1 MFCD00093311

化学结构图

5122-94-1
SMILES: OB(O)c1ccc(-c2ccccc2)cc1

化学属性

Mol. FormulaC12H11BO2
Mol. Weight198.03
Melting Point232-245°C
TSCANo
Density1.18
Boiling Point385.5°C at 760 mmHg

别名和识别编码

Chemical NameBiphenyl-4-boronic Acid
CAS Number5122-94-1
Alfabeta NameBIPHENYLBORONICACID 4-
MDL NumberMFCD00093311
Synonym [1,1'-Biphenyl]-4-ylboronic acid {LY} [1,1'-Biphenyl]-4-ylboronic acid {} {LY} [1,1'-Biphenyl]-4-ylboronic acid {} {} {LY} [1,1'-Biphenyl]-4-ylboronic acid {} {} {} {LY} [1,1'-Biphenyl]-4-ylboronic acid {} {} {} {} {LY} [1,1'-Biphenyl]-4-ylboronic acid {} {} {} {} {} {LY} [1,1'-Biphenyl]-4-ylboronic acid {} {} {} {} {} {} {LY} [1,1'-Biphenyl]-4-ylboronic acid {} {} {} {} {} {} {} {LY} [1,1'-Biphenyl]-4-ylboronic acid {} {} {} {} {} {} {} {} {LY} [1,1'-Biphenyl]-4-ylboronic acid {} {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {} {LY} [1,1'-Biphenyl]-4-ylboronic acid {} {} {} {} {} {} {} {} {} {} {LY} [1,1'-Biphenyl]-4-ylboronic acid {} {} {} {} {} {} {} {} {} {} {} {LY} [1,1'-Biphenyl]-4-ylboronic acid {} {} {} {} {} {} {} {} {} {} {} {} {LY} [1,1'-Biphenyl]-4-ylboronic acid {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} [1,1'-Biphenyl]-4-ylboronic acid {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} [1,1'-Biphenyl]-4-yl
EC Number000-000-0
Beilstein Registry Number2937410
PubChem Substance ID151253
Reaxys-RN2937410
Chemical Name Translation4-联苯硼酸
InChIKeyXPEIJWZLPWNNOK-UHFFFAOYSA-N
LabNetwork Molecule IDLN00139420
InChIInChI=1S/C12H11BO2/c14-13(15)12-8-6-11(7-9-12)10-4-2-1-3-5-10/h1-9,14-15H
Canonical SMILESOB(O)C1=CC=C(C2=CC=CC=C2)C=C1
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分类

  • {SNA} Aryl Boronic Acids, Boronic Acids, Boronic Acids and Derivatives, Chemical Synthesis, Monosubstituted Aryl Boronic Acids, Organometallic Reagents

相关文献及参考

  • Beilstein:16(4)1679
  • The absolute configuration of 1-arylethane-1,2-diols has been determined by analysis of the CD spectra of the 4-biphenylboronates: Org. Lett., 1, 2093 (1999).

安全信息

Warnings IRRITANT
Safety Statements
  • S24/25 Avoid contact with skin and eyes 避免皮肤和眼睛接触;
Risk Statements
  • R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
Signal word Warning
GHS Symbol
WGK Germany3
Precautionary statements
  • P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P262 Do not get in eyes, on skin, or on clothing. 不要接触眼睛,皮肤或衣服。
  • P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P305+P351+P338
  • P332+P313
  • P362 Take off contaminated clothing and wash before reuse. 脱掉污染的衣服,清洗后方可重新使用
Personal Protective Equipment Eyeshields, Gloves, type N95 (US), type P1 (EN143) respirator filter
Hazard Codes Xi
Hazard statements
  • H315 Causes skin irritation 会刺激皮肤
Storage condition 2-8°C {LY} 2-8°C {} {LY} 2-8°C {} {} {LY} 2-8°C {} {} {} {LY} 2-8°C {} {} {} {} {LY} 2-8°C {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {

其他信息

  • MOL 文件:5122-94-1.mol
  • Acros Organics:[1,1'-Biphenyl!-4-ylboronic acid, TECH(5122-94-1)
  • Alfa Aesar:4-联苯基硼酸,98+% Biphenyl-4-boronic acid, 98+%(5122-94-1)
  • TCI Shanghai:4-联苯硼酸 4-Biphenylboronic Acid (contains varying amounts of Anhydride)(5122-94-1)
  • Sigma Aldrich:5122-94-1(sigmaaldrich)
  • Hazard Note:Irritant
  • 4-联苯硼酸价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2014/06/02 B2294 4-联苯硼酸(含有数量不等的酸酐) 4-Biphenylboronic Acid (contains varying amounts of Anhydride) 5G 194元 2014/06/02 B2294 4-联苯硼酸(含有数量不等的酸酐) 4-Biphenylboronic Acid (contains varying amounts of Anhydride) 25G 730元 2010/05/25 B23703 4-联苯基硼酸, 98+% Biphenyl-4-boronic acid, 98+% 25g 2814元
  • 检测方法:HPLC,NMR

系列性分类


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