Glycine, N-​(carboxymethyl)​-​N-​[(9,​10-​dihydro-​3,​4-​dihydroxy-​9,​10-​dioxo-​2-​anthracenyl)​methyl]​- 茜素络合指示剂

CAS 3952-78-1 MFCD00001202

化学结构图

3952-78-1
SMILES: O=C(O)CN(CC(=O)O)Cc1cc2c(c(O)c1O)C(=O)c1ccccc1C2=O

化学属性

Mol. FormulaC19H15NO8
Mol. Weight385.32
Melting Point-185 °C
TSCAYes
Density1.641
Solubility略溶于水 (0.2 G/L)
Appearance 姜黄色粉末。熔点180℃（分解）。微溶于水、乙醇和乙醚，在pH>5时微溶于水，pH<5时溶解度降低。
Boiling Point511.79 °C at 760 mmHg

别名和识别编码

Chemical NameGlycine, N-​(carboxymethyl)​-​N-​[(9,​10-​dihydro-​3,​4-​dihydroxy-​9,​10-​dioxo-​2-​anthracenyl)​methyl]​-
Synonym Alizarin complexone {LY} Alizarin complexone {} {LY} Alizarin complexone {} {} {LY} Alizarin complexone {} {} {} {LY} Alizarin complexone {} {} {} {} {LY} Alizarin complexone {} {} {} {} {} {LY} Alizarin complexone {} {} {} {} {} {} {LY} Alizarin complexone {} {} {} {} {} {} {} {LY} Alizarin complexone {} {} {} {} {} {} {} {} {LY} Alizarin complexone {} {} {} {} {} {} {} {} {} {LY} Alizarin complexone {} {} {} {} {} {} {} {} {} {} {LY} Alizarin complexone {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Alizarin complexone {} {} {} {} {} {} {} {} {} {} {} {} {LY} Alizarin complexone {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Alizarin complexone {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Alizarin complexone {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Alizarin complexone
MDL NumberMFCD00001202
PubChem Substance ID65132
Beilstein Registry Number2190028
CAS Number3952-78-1
EC Number223-544-2
Reaxys-RN2190028
Chemical Name Translation茜素络合指示剂
InChIKeyPWIGYBONXWGOQE-UHFFFAOYSA-N
LabNetwork Molecule IDLN00222196
InChIInChI=1S/C19H15NO8/c21-13(22)7-20(8-14(23)24)6-9-5-12-15(19(28)16(9)25)18(27)11-4-2-1-3-10(11)17(12)26/h1-5,25,28H,6-8H2,(H,21,22)(H,23,24)
Canonical SMILESO=C(C1=C(C(O)=C(C=C1C2=O)CN(CC(O)=O)CC(O)=O)O)C3=C2C=CC=C3
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分类

  • {SNA} Analytical Reagents, Analytical/Chromatography, Indicators, Titration, pH Indicators - Solids
  • {SNA} Biochemicals and Reagents, Enzyme Substrates, Enzymes, Inhibitors, and Substrates, Lipid Peroxidation, Substrates by Enzyme
  • {SNA} Biochemicals and Reagents, Enzyme Substrates, Lipid Peroxidation, Substrates by Enzyme,

产品应用

  • 分光测定氟，用作络合指示剂；测定铝、钡、锰、镍、钙、镉、钴、铜、铟、铅、锶、锌和稀土。配成0.5%的水溶液，做络合滴定指示剂。

相关文献及参考

  • Beilstein: 14,IV,931

安全信息

WGK Germany3
RTECSAH0585000
Personal Protective Equipment Eyeshields, Gloves, type N95 (US), type P1 (EN143) respirator filter
Signal word Warning
Hazard statements
  • H302+H312+H332
Precautionary statements
  • P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P262 Do not get in eyes, on skin, or on clothing. 不要接触眼睛，皮肤或衣服。
  • P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
  • P271 Use only outdoors or in a well-ventilated area.? 只能在室外或通风良好的地方使用。
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P302+P352+P312+P362+P364
  • P304+P340+P312
  • P305+P351+P338
  • P312 Call a POISON CENTER or doctor/physician if you feel unwell. 如果你感觉不适，呼叫解毒中心或医生/医师。
GHS Symbol
Safety Statements
  • S24/25 Avoid contact with skin and eyes 避免皮肤和眼睛接触；
Risk Statements
  • R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
Storage condition 2-8°C, protect from light, stored under nitrogen {LY} 2-8°C, protect from light, stored under nitrogen {} {LY} 2-8°C, protect from light, stored under nitrogen {} {} {LY} 2-8°C, protect from light, stored under nitrogen {} {} {} {LY} 2-8°C, protect from light, stored under nitrogen {} {} {} {} {LY} 2-8°C, protect from light, stored under nitrogen {} {} {} {} {} {LY} 2-8°C, protect from light, stored under nitrogen {} {} {} {} {} {} {LY} 2-8°C, protect from light, stored under nitrogen {} {} {} {} {} {} {} {LY} 2-8°C, protect from light, stored under nitrogen {} {} {} {} {} {} {} {} {LY} 2-8°C, protect from light, stored under nitrogen {} {} {} {} {} {} {} {} {} {LY} 2-8°C, protect from light, stored under nitrogen {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, protect from light, stored under nitrogen {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, protect from light, stored under nitrogen {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, protect from light, stored under nitr 
TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Intravenous
SPECIES OBSERVED        : Rodent - mouse
DOSE/DURATION           : 170 mg/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   EXPEAM Experientia.  (Birkhaeuser Verlag, POB 133, CH-4010 Basel,
   Switzerland)  V.1-    1945-  Volume(issue)/page/year: 28,180,1972

其他信息

  • Sigma Aldrich:3952-78-1(sigmaaldrich)
  • 可燃性危险特性:可燃; 燃烧产生有毒氮氧化物烟雾
  • 方法一:由茜素和亚氨基二乙酸反应：16g茜素和22.5g亚氨基二乙酸悬浮于30ml水中，用含13.5g氢氧化钠的60ml水溶液处理。边搅拌滴加37%甲醛10ml。混合物用水稀释至230ml。加热至75℃，边搅拌边滴加37%甲醛7ml，保温14g。稀释至750ml，在45℃用5N盐酸处理至无沉淀出现为止。滤出结晶为粗品。将粗品溶于蒸馏水，加氢氧化钠溶液溶解，再加盐酸使之重新析出沉淀，过滤，洗涤可得纯品。未反应的茜素可用乙醚提取的方法除去。
  • 毒性分级:中毒
  • 类别:有毒物品
  • Alfa Aesar:茜素络合指示剂,3-茜素甲基胺-N,N-二乙酸 Alizarin Complexone(3952-78-1)
  • 用途二:分光测定氟，用作络合指示剂；测定铝、钡、锰、镍、钙、镉、钴、铜、铟、铅、锶、锌和稀土。配成0.5%的水溶液，做络合滴定指示剂。
  • TCI Shanghai:茜素氨羧络合剂 Alizarin Complexone,>;95.0%(LC)(T)(3952-78-1)
  • 茜素络合指示剂价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2011/08/23 71001661 茜素络合指示剂;茜素氨羧络合剂;3-茜素甲基胺-N,N-二乙酸;茜素络合剂 1g 37.5元 2011/04/16 A0440 茜素氨羧络合剂 Alizarin Complexone 5G 2800元 2011/04/16 A0440 茜素氨羧络合剂 Alizarin Complexone 1G 862元
  • 储运特性:库房通风低温干燥; 与食品原料分开存放
  • 上游原料:亚氨基二乙酸 --> 1,2-二羟基蒽醌
  • 灭火剂:干粉、泡沫、砂土、二氧化碳, 雾状水
  • 用途一:配成0.5%的水溶液，作络合滴定指示剂
  • MSDS 信息:Alizarin Fluorine Blue(3952-78-1).msds
  • 急性毒性:静脉-小鼠 LD50: 170 毫克/公斤
  • MOL 文件:3952-78-1.mol
  • 易溶于碱性水溶液，其颜色随pH不同而变化，微溶于水(0.2 g/L)、不溶于乙醚、乙醇和其他非极性有机溶剂。在pH>5时微溶于水。pH<5时溶解度降低。

系列性分类

  1. Analytical & Chromatography 分析化学与色谱
  2. Analytical Reagents
  3. Titration - Analytical Reagents
  4. Indicators - Titration
  5. pH Indicators - Solids - Indicators
  1. Life Science 生命科学
  2. Biochemicals and Reagents 生化试剂
  3. Enzymes, Inhibitors, and Substrates - Biochemicals and Reagents
  4. Enzyme Substrates - Enzymes, Inhibitors, and Substrates
  5. Substrates by Enzyme - Enzyme Substrates
  6. Lipid Peroxidation - Substrates by Enzyme
  1. Life Science 生命科学
  2. Biochemicals and Reagents 生化试剂
  3. Enzymes, Inhibitors, and Substrates - Biochemicals and Reagents
  4. Enzyme Substrates - Enzymes, Inhibitors, and Substrates
  5. Substrates by Enzyme - Enzyme Substrates
  6. Lipid Peroxidation - Substrates by Enzyme
  1. Analytical & Chromatography 分析化学与色谱
  2. Chelating Reagents
  1. Analytical & Chromatography 分析化学与色谱
  2. HPLC
  3. Test Kits and Indicators
  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Chemicals by Class 化学分类法
  4. Anthraquinones

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