Bismuth 铋

CAS 7440-69-9 MFCD00134033

化学结构图

7440-69-9
SMILES: [Bi]

化学属性

Mol. FormulaBi
Mol. Weight208.98
Density9.8 g/mL at 25 °C(lit.)
Boiling Point1560 °C at 760 mmHg
Melting Point271 °C
TSCAYes
Vapor Pressure<;0.1 mmHg ( 20 °C)
Solubility不溶
Appearance 银白色或微红色金属,有金属光泽,性脆质硬,斜方晶系粗粒结晶。熔点271.3℃。沸点(1560±5)℃。相对密度9.80。溶于热硫酸、硝酸,王水,缓慢溶于热盐酸,不溶于水。在常温下稳定,加热则呈淡蓝色火焰而燃烧,并生成黄色或褐色氧化铋。熔融的金属经凝结后体积增大。 shot

别名和识别编码

Chemical NameBismuth
MDL NumberMFCD00134033
PubChem Substance ID5359367
CAS Number7440-69-9
EC Number231-177-4
Synonym Bismuth ingot/button, ^=36mm (1.4in) dia x 8mm (0.3in) thick, 99.9% (metals basis) {LY} Bismuth ingot/button, ^=36mm (1.4in) dia x 8mm (0.3in) thick, 99.9% (metals basis) {} {LY} Bismuth ingot/button, ^=36mm (1.4in) dia x 8mm (0.3in) thick, 99.9% (metals basis) {} {} {LY} Bismuth ingot/button, ^=36mm (1.4in) dia x 8mm (0.3in) thick, 99.9% (metals basis) {} {} {} {LY} Bismuth ingot/button, ^=36mm (1.4in) dia x 8mm (0.3in) thick, 99.9% (metals basis) {} {} {} {} {LY} Bismuth ingot/button, ^=36mm (1.4in) dia x 8mm (0.3in) thick, 99.9% (metals basis) {} {} {} {} {} {LY} Bismuth ingot/button, ^=36mm (1.4in) dia x 8mm (0.3in) thick, 99.9% (metals basis) {} {} {} {} {} {} {LY} Bismuth ingot/button, ^=36mm (1.4in) dia x 8mm (0.3in) thick, 99.9% (metals basis) {} {} {} {} {} {} {} {LY} Bismuth ingot/button, ^=36mm (1.4in) dia x 8mm (0.3in) thick, 99.9% (metals basis) {} {} {} {} {} {} {} {} {LY} Bismuth ingot/button, ^=36mm (1.4in) dia x 8mm (0.3in) thick, 99.9% (metals basis)
Chemical Name Translation
Merck Number13,1256
LabNetwork Molecule IDLN00196769
InChIInChI=1S/Bi
Canonical SMILES[Bi]
信息真实价格透明    资金保障    专业采购外包团队在线服务   
信息真实价格透明    资金保障    专业采购外包团队在线服务   
品牌质保精细包装    现货库存    一流品牌服务   

分类

  • {uni_hamburg} no charge; 1fragme
  • {SNA} 83: Bi, Alternative Energy, Beaded Materials, Bi, Bismuth, Materials Science, Metal and Ceramic Science, Metals, Thermoelectric Materials, Thermoelectric Precursors, Ultra-High Purity Materials
  • {SNA} Alternative Energy, Bi,

产品应用

  • 主要用于制取铋制品和铋合金。

相关文献及参考

  • Merck: 14,1257
  • Short: III/13b
  • Short: III/13a
  • Short: II/5

安全信息

WGK Germanynwg
RTECSEB2600000
Personal Protective Equipment Eyeshields, Gloves, type N95 (US), type P1 (EN143) respirator filter Faceshields, full-face respirator (US), Gloves, Goggles, multi-purpose combination respirator cartridge (US), type ABEK (EN14387) respirator filter
Safety Statements
  • S45 In case of accident or if you feel unwell seek medical advice immediately (show the label where possible) 发生事故时或感觉不适时,立即求医(可能时出示标签);
  • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后,立即用大量水冲洗并征求医生意见;
  • S16 Keep away from sources of ignition - No smoking 远离火源,禁止吸烟;
  • S36/37/39 Wear suitable protective clothing, gloves and eye/face protection 穿戴适当的防护服、手套和眼睛/面保护;
  • S33 Take precautionary measures against static discharges 对静电采取预防措施;
UN Number UN 3264 8/PG 3 3089 UN3264 UN3089
Risk Statements
  • R8 Contact with combustible material may cause fire 遇到易燃物会导致起火
  • R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
  • R11 Highly flammable 非常易燃
  • R34 Causes burns 会导致灼伤
GHS Symbol
Hazard statements
  • H315 Causes skin irritation 会刺激皮肤
  • H335 May cause respiratory irritation 可能导致呼吸道刺激
  • H272 May intensify fire; oxidizer 可能加剧火势;氧化剂。
  • H319 Causes serious eye irritation 严重刺激眼睛
  • H228 Flammable solid 易燃固体
Precautionary statements
  • P210 Keep away from heat/sparks/open flames/hot surfaces. — No smoking. 远离热源/火花/明火/热的表面。——禁止吸烟。
  • P370+P378
  • P220 Keep/Store away from clothing/…/combustible materials. 保持远离/贮存远离服装/....../可燃材料。
  • P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P305+P351+P338
Signal word Danger
Packing GroupIII
Hazard Codes F F,C O,Xi
Storage condition RT, stored under nitrogen {LY} RT, stored under nitrogen Store at room temperature, keep dry and cool {} {LY} RT, stored under nitrogen {} {} {LY} RT, stored under nitrogen {} {} {} {LY} RT, stored under nitrogen {} {} {} {} {LY} RT, stored under nitrogen {} {} {} {} {} {LY} RT, stored under nitrogen {} {} {} {} {} {} {LY} RT, stored under nitrogen {} {} {} {} {} {} {} {LY} RT, stored under nitrogen {} {} {} {} {} {} {} {} {LY} RT, stored under nitrogen {} {} {} {} {} {} {} {} {} {LY} RT, stored under nitrogen {} {} {} {} {} {} {} {} {} {} {LY} RT, stored under nitrogen {} {} {} {} {} {} {} {} {} {} {} {LY} RT, stored under nitrogen {} {} {} {} {} {} {} {} {} {} {} {} {LY} RT, stored under nitrogen {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} RT, stored under nitrogen {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} RT, stored under nitrogen {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} RT, stored under nitro
Hazard Class8
TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Rodent - rat
DOSE/DURATION           : 5 gm/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   GTPZAB Gigiena Truda i Professional'nye Zabolevaniya.  Labor Hygiene and
   Occupational Diseases. (V/O Mezhdunarodnaya Kniga, 113095 Moscow, USSR)
   V.1-36, 1957-1992. For publisher information, see MTPEEI
   Volume(issue)/page/year: 30(6),16,1986

TYPE OF TEST            : LDLo - Lowest published lethal dose
ROUTE OF EXPOSURE       : Unreported
SPECIES OBSERVED        : Rodent - rabbit
DOSE/DURATION           : 535 mg/kg
TOXIC EFFECTS :
   Behavioral - food intake (animal)
   Behavioral - coma
   Kidney, Ureter, Bladder - urine volume decreased
REFERENCE :
   JPETAB Journal of Pharmacology and Experimental Therapeutics.  (Williams &
   Wilkins Co., 428 E. Preston St., Baltimore, MD 21202)  V.1-    1909/10-
   Volume(issue)/page/year: 28,121,1926

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Rodent - mouse
DOSE/DURATION           : 10 gm/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   GTPZAB Gigiena Truda i Professional'nye Zabolevaniya.  Labor Hygiene and
   Occupational Diseases. (V/O Mezhdunarodnaya Kniga, 113095 Moscow, USSR)
   V.1-36, 1957-1992. For publisher information, see MTPEEI
   Volume(issue)/page/year: 30(6),16,1986

TYPE OF TEST            : LDLo - Lowest published lethal dose
ROUTE OF EXPOSURE       : Unreported
SPECIES OBSERVED        : Human - man
DOSE/DURATION           : 221 mg/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   85DCAI "Poisoning; Toxicology, Symptoms, Treatments," 2nd ed., Arena, J.M.,
   Springfi

其他信息

  • 用途五:用于制合金如印刷用的活字合金、硬质合金、巴氏合金。还用于制锑盐、医药、颜料及半导体材料等。用于ICP-AES、AAS、AFS、ICP-MS、离子色谱等。滴定分析用标准溶液。校准仪器和装置;评价方法;工作标准;质量保证/质量控制;其他。
  • 参考质量标准:参考标准 指标名称 指标 高纯级 铋(Bi)/%≥ 99.99 硼(B)/%≤ 1×10 -4 锰(Mn)/%≤ 1×10 -5 铁(Fe) %≤5×10 -4 镁(Mg)/%≤ 5×10 -4 铬(Cr)/%≤ 5×10 -4 锡(Sn)/%≤ 5×10 -4 镍(Ni)/%≤ 5×10 -5 铝(AI)/%≤ 1×10 -4 钙(Ca)/%≤ 5×10 -4 银(Ag)/%≤ 1×10 -4 钴(Co)/%≤ 1×10 -5 铂(Pt)/%≤ 1×10 -5 钯(Pd)/%≤ 1×10 -5 镓(Ga)/%≤ 1×10 -5 钛(Ti)/%≤ 1×10 -5 钡(Ba)/%≤ 1×10 -5 铜(Cu)/%≤ 5×10 -4 铅(Pb)/%≤ 5×10 -4 镉(Cd)/%≤ 5×10 -4 锌(Zn)/%≤ 5×10 -4 硅(Si)/%≤ 5×10 -4 砷(As)/%≤ 5×10 -4 硫(S)/%≤ 5×10 -4
  • 用途六:主要用于制取铋制品和铋合金。
  • 灭火剂:干粉,砂土,二氧化碳, 雾状水
  • 方法一:以金属铋为原料,经区域熔融法精制,制得高纯铋成品。
  • 用途三:用于制低熔点合金、核反应堆冷却剂、铋汞齐、铋盐等
  • 用途一:用作原子反应堆的冷却剂,用于高纯铋化合物的制备
  • 蒸气压:<;0.1 mm Hg ( 20 °C)
  • 用途二:用作分析试剂、原子反应堆的冷却剂,也用于高纯铋化合物的制备
  • 急性毒性:未名-人 LDL0: 221 毫克/公斤
  • 下游产品:丙烯腈 --> 丙烯酸 --> 丙烯醛 --> 碱式碳酸铋 --> 五水合硝酸铋 --> 甲基丙烯腈 --> 铝酸铋 --> 丁烯氧化脱氢钼铋系催化剂 --> 铜铋催化剂
  • 类别:易燃固体
  • 是一种稀少元素,金属铋为银白色,表面略带玫瑰红色。有强烈的金属光泽,属斜方晶体。
  • 铋价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2011/08/23 53206560 铋 100ml 40元 2011/08/23 51003761 铋粉 25g 134元 2011/08/23 51003560 铋粒 10g 29元
  • 可燃性危险特性:近明火易燃烧; 与酸或酸雾反应排放有毒烟雾
  • Sigma Aldrich:7440-69-9(sigmaaldrich)
  • 毒性分级:高毒
  • MOL 文件:7440-69-9.mol
  • Alfa Aesar:铋针,5-20mm(0.2-0.8in)long,99.99%(metalsbasis) Bismuth needles, 5-20mm (0.2-0.8in) long, 99.99% (metals basis)(7440-69-9)
  • Acros Organics:铋粉 Bismuth, powder, 100 mesh, 99.50%(7440-69-9)
  • 用途四:用于半导体高纯材料、高纯铋化合物的制备。用作原子反应堆的冷却剂。
  • 储运特性:库房通风低温干燥; 与食品原料酸, 铝, 卤素等分开存放

系列性分类


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