Cadmium carbonate 碳酸镉

CAS 513-78-0 MFCD00010918

化学结构图

513-78-0
SMILES: O=C([O-])[O-].[Cd+2]

化学属性

Mol. FormulaCCdO3
Mol. Weight172.42
Density4.258 g/mL at 25 °C(lit.)
Melting Point500 °C
SolubilityVery slightly soluble in water. Soluble in dilute acids, concentrated solutions of ammonium salts
TSCAYes
Appearance 三方晶系，白色粉末。 不溶于水和有机溶剂，溶于酸、氰化钾、铵盐中。 powder
Stability对湿度敏感

别名和识别编码

Chemical NameCadmium carbonate
Synonym Cadmium carbonate {LY} Cadmium carbonate {} {LY} Cadmium carbonate {} {} {LY} Cadmium carbonate {} {} {} {LY} Cadmium carbonate {} {} {} {} { {} {} {} {} {LY} Cadmium carbonate {} {} {} {} {} {LY} Cadmium carbonate {} {} {} {} {} {} {} {} {} {} {} {} {LY} Cadmium carbonate {} {} {} {} {} {} {} {LY} Cadmium carbonate {} {} {} {} {} {} {} {} {LY} Cadmium carbonate {} {} {} {} {} {} {} {} {} {LY} Cadmium carbonate {} {} {} {} {} {} {} {} {} {} {LY} Cadmium carbonate {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Cadmium carbonate {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Cadmium carbonate {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Cadmium carbonate {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Cadmium carbonate {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Cadmium carbonate {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {
CAS Number513-78-0
PubChem Substance ID10564
EC Number208-168-9
MDL NumberMFCD00010918
Merck Number14,1616
Chemical Name Translation碳酸镉
InChIInChI=1S/CH2O3.Cd/c2-1(3)4;/h(H2,2,3,4);/q;+2/p-2
Canonical SMILES[Cd]C(O[O])=O
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分类

  • {SNA} Cadmium, Cadmium Salts, Catalysis and Inorganic Chemistry,
  • {SNA} Cadmium, Cadmium Salts, Catalysis and Inorganic Chemistry, Cd, Chemical Synthesis, Essential Chemicals, Metal and Ceramic Science, Research Essentials, Salts, Ultra-High Purity Materials, 材料科学
  • {SNA}
  • {SNA} Cadmium, Cadmium Salts, Catalysis and Inorganic Chemistry, Cd, Chemical Synthesis, Essential Chemicals, Materials Science, Metal and Ceramic Science, Research Essentials, Salts, Ultra-High Purity Materials
  • {Chemicalbook} 无机化工产品: 无机盐: Cd硝酸盐
  • {uni_hamburg} no charge; carbonate; 2fragments; ionic

产品应用

  • 硫的测定。稀土光学玻璃制造，电镀上色。催化剂、增塑剂和稳定剂。制造涤纶的中间体和绝缘材料，还可用作生产镉盐的原料。

相关文献及参考

  • Short: III/7c3
  • Merck: 14,1616
  • Short: III/29a

安全信息

GHS Symbol
WGK Germany3
Hazard Codes Xn;N T+,N Xn,N
Hazard statements
  • H302 Harmful if swallowed 吞食有害
  • H302+H312
  • H302+H312+H332
  • H312 Harmful in contact with skin 皮肤接触有害
  • H330 Fatal if inhaled 吸入致命
  • H332 Harmful if inhaled 吸入有害
  • H341 Suspected of causing genetic defects 怀疑导致遗传性缺陷
  • H350 May cause cancer 可能致癌
  • H361 Suspected of damaging fertility or the unborn child 怀疑对生育能力或未出生婴儿造成伤害
  • H372 Causes damage to organs through prolonged or repeated exposure 长期或频繁接触会损伤器官
  • H400 Verytoxictoaquaticlife 对水生生物毒性非常大。
  • H410 Verytoxictoaquaticlifewithlonglastingeffects 对水生生物毒性非常大并具有长期影响。
Personal Protective Equipment Eyeshields, Gloves, type N95 (US), type P1 (EN143) respirator filter dust mask type N95 (US), Eyeshields, Faceshields, Gloves
Precautionary statements
  • P201 Obtain special instructions before use. 使用前获取专门指示。
  • P202 Do not handle until all safety precautions have been read and understood. 已阅读并理解所有的安全预防措施之前，切勿操作。
  • P203
  • P260 Do not breathe dust/fume/gas/mist/vapours/spray. 不要吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
  • P270 Do not eat, drink or smoke when using this product. 使用本产品时不要吃东西，喝水或吸烟。
  • P271 Use only outdoors or in a well-ventilated area.? 只能在室外或通风良好的地方使用。
  • P273 Avoid release to the environment. 避免释放到环境中。
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P281 Use personal protective equipment as required. 使用所需的个人防护装备。
  • P284 Wear respiratory protection.? 佩戴呼吸保护装置。
  • P301+P310
  • P301+P312
  • P301+P316
  • P301+P317
  • P302+P352
  • P304+P312
  • P304+P340
  • P304+P340+P310
  • P307+P311
  • P308+P313
  • P308+P316
  • P310 Immediately call a POISON CENTER or doctor/physician. 立即呼救解毒中心或医生/医师。
  • P312 Call a POISON CENTER or doctor/physician if you feel unwell. 如果你感觉不适，呼叫解毒中心或医生/医师。
  • P314 Get medical advice/attention if you feel unwell. 获取医疗咨询/就医，如果你觉得不舒服
  • P316
  • P317
  • P318
  • P319
  • P320 Specific treatment is urgent (see … on this label). 紧急具体治疗（见本标签上的）。
  • P321 Specific treatment (see … on this label). 具体治疗（见本标签上的）。
  • P322 Specific measures (see …on this label). 具体治疗（见本标签上的）。
  • P330 Rinse mouth. 漱口
  • P362+P364
  • P363 Wash contaminated clothing before reuse. 被污染的衣服洗净后方可重新使用。
  • P391 Collect spillage. Hazardous to the aquatic environment 收集对水环境有危害的泄漏物。
  • P403+P233
  • P405 Store locked up. 上锁保管。
  • P501 Dispose of contents/container to..… 处理内容物/容器.....
Signal word Danger Warning
Safety Statements
  • S45 In case of accident or if you feel unwell seek medical advice immediately (show the label where possible) 发生事故时或感觉不适时，立即求医（可能时出示标签）；
  • S53 Avoid exposure - obtain special instructions before use 避免接触，使用前获得特别指示说明；
  • S60 This material and its container must be disposed of as hazardous waste 该物质及其容器必须作为危险废物处置；
  • S61 Avoid release to the environment. Refer to special instructions/safety data sheet 避免释放到环境中，参考特别指示/安全收据说明书；
  • S28 After contact with skin, wash immediately with plenty of ... (to be specified by the manufacturer) 皮肤接触后，立即用大量…（由生产厂家指定）冲洗；
  • S36/37 Wear suitable protective clothing and gloves 穿戴适当的防护服和手套；
UN Number UN 3077 9/PG 3 3077 UN2570
Risk Statements
  • R26 Very toxic by inhalation 吸入极毒
  • R21 Harmful in contact with skin 与皮肤接触有害
  • R22 Harmful if swallowed 吞咽有害
  • R45 May cause cancer 可能致癌
  • R50/53
  • R62 Possible risk of impaired fertility 有削弱生殖能力的危险
  • R63 Possible risk of harm to the unborn child 可能危害未出生婴儿
  • R48 Danger of serious damage to health by prolonged exposure 长期接触有严重损害健康的危险
  • R68 Possible risk of irreversible effects 可能有不可挽回的作用的危险
  • R20/21/22 Harmful by inhalation, in contact with skin and if swallowed 吸入、皮肤接触和不慎吞咽有害
Packing GroupIII
Hazard Class6.1
RTECSFF9320000
Storage condition Store at room temperature, keep dry and cool {LY} Store at room temperature, keep dry and cool {} {LY} Store at room temperature, keep dry and cool {} {} {LY} Store at room temperature, keep dry and cool {} {} {} {LY} Store at room temperature, keep dry and cool {} {} {} {} {LY} Store at room temperature, keep dry and cool {} {} {} {} {} {LY} Store at room temperature, keep dry and cool {} {} {} {} {} {} {LY} Store at room temperature, keep dry and cool {} {} {} {} {} {} {} {LY} Store at room temperature, keep dry and cool {} {} {} {} {} {} {} {} {LY} Store at room temperature, keep dry and cool {} {} {} {} {} {} {} {} {} {LY} Store at room temperature, keep dry and cool {} {} {} {} {} {} {} {} {} {} {LY} Store at room temperature, keep dry and cool {} {} {} {} {} {} {} {} {} {} {} {LY} Store at room temperature, keep dry and cool {} {} {} {} {} {} {} {} {} {} {} {} {LY} Store at room temperature, keep dry and cool {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Store

其他信息

  • 碳酸镉价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2011/08/23 20010228 碳酸镉 500g 140元 2010/06/21 212320050 碳酸镉 Cadmium carbonate 99.999% 5 GR 839元 2010/05/25 A15812 碳酸镉, 97% Cadmium carbonate, 97% 1kg 2338元
  • 方法一:硝酸镉法 镉锭与硝酸反应生成硝酸镉，然后与纯碱反应生成碳酸镉，再经水洗、干燥和粉碎，制得成品碳酸镉。其 8HNO3+3Cd→3Cd(NO3)2+2NO+4H2O Cd(NO3)2+Na2CO3→CdCO3+2NANO3 盐酸法将镉锭熔融，倾入水中激碎成粒，加盐酸溶解生成氯化镉，同时加入少量硝酸，在搅拌下加入氨水调PH5～6，然后加入少量双氧水除铁，过滤后与配制好的纯碱液反应至Ph9～10，用水漂洗至中性，再经过滤，在120℃下干燥，制得碳酸镉成品。其 Cd+2HCl→CdC12+H2↑ CdCl2+Na2CO3→CdCO3+2NaCl
  • 下游产品:镉黄 --> 镉红
  • Sigma Aldrich:513-78-0(sigmaaldrich)
  • 急性毒性:口服-大鼠 LD50: 438 毫克/公斤; 口服-小鼠 LD50: 310 毫克/公斤
  • 可燃性危险特性:热分解排出有毒含镉烟雾
  • 用途二:用于制造涤纶的中间体和绝缘材料。用作玻璃色素的助熔剂，有机反应的催化剂，塑料之增塑剂和稳定剂，以及用作生产镉盐的原料。
  • 用途一:用作制造涤纶的中间体、玻璃色素的助熔剂、有机反应的催化剂、塑料增塑剂、稳定剂以及生产镉盐的原料
  • Alfa Aesar:碳酸镉,Puratronic|r,99.998%(metalsbasis) Cadmium carbonate, Puratronic, 99.998% (metals basis)(513-78-0)
  • MOL 文件:513-78-0.mol
  • 类别:有毒物质
  • 图谱信息:碳酸镉(513-78-0)红外图谱(IR1)
  • 用途三:硫的测定。稀土光学玻璃制造，电镀上色。催化剂、增塑剂和稳定剂。制造涤纶的中间体和绝缘材料，还可用作生产镉盐的原料。
  • 参考质量标准:参考标准 指标名称 指标 浆状产品 粉状产品 碳酸镉(CdCO3)/%≥ 40 96 水分/%≤ 60 1 硝酸盐(NＯ3 - )/%≤ 无 - 细度(140目筛余物)/%≤ - 0.5
  • 在500℃以下即分解。溶于稀酸和浓铵盐溶液，几乎不溶于水。中等毒，半数致死量(大鼠，经口)88mg/kg。有致癌可能性。
  • 毒性分级:高毒
  • Acros Organics:碳酸镉 Cadmium carbonate, 99.999%(513-78-0)
  • 水中溶解度(g/100ml):每100毫升水中的溶解克数: 3.932×10-5/20℃
  • 储运特性:库房通风低温干燥; 与食品原料分开存放
  • 灭火剂:水, 干粉, 二氧化碳, 泡沫
  • 上游原料:氢氧化铵 --> 氯化镉 --> 镉锭
  • 毒性:剧毒。溶解度较小的镉化合物首先作用于呼吸器官及胃肠道，吸收作用表现为中枢神经系统及周围神经系统、内脏，主要是心脏、肾、肝、骨骼肌及骨组织的损害。氧化镉粉尘的急性中毒，可见上呼吸道及呼吸道深部黏膜的刺激症状，如口中有甜味、前额部疼痛、眩晕、无力、恶心、上腹部疼。慢性中毒症状是嗅觉降低、头痛、消瘦。 氧化镉粉尘的最高容许浓度为0.1mg/m 3 ，日平均浓度为0.03 mg/m 3 。 如发生中毒，应速将中毒者移至空气新鲜处，安静、保暖，有呼吸道刺激症状时应吸入温热的2%碳酸氢钠溶液，工作时应戴防毒口罩、防护眼镜，穿无缝工作服或连衫裤，戴橡皮手套及围裙，工作期间及工作后要漱口。
  • 职业标准:TWA 0.01 毫克(镉)/立方米

系列性分类

  1. Chemical Synthesis 化学合成
  2. Catalysis and Inorganic Chemistry 催化剂和无机化学
  3. Cadmium 镉
  1. Materials Science 材料科学
  2. Metal and Ceramic Science Products 金属和陶瓷科学
  3. Ultra-High Purity Materials - Metal and Ceramic Science
  1. Materials Science 材料科学
  2. Metal and Ceramic Science Products 金属和陶瓷科学
  3. Salts 金属盐
  4. Cadmium Salts - Salts
  1. Functional Group 官能团索引
  2. carbonic acid derivative

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