6-Chloronicotinoyl Chloride 6-氯-3-吡啶甲酰氯
CAS 58757-38-3 MFCD00051775
化学结构图
SMILES: O=C(Cl)C1C=CC(Cl)=NC=1
化学属性
| Mol. Formula | C6 |
|---|---|
| Mol. Weight | 176 |
| Melting Point | 47.0 and le 51.0 deg-C |
| TSCA | No |
| Boiling Point | 84-85°/3mm |
| Density | 1.454 |
| Stability | 对湿度敏感 |
别名和识别编码
| Chemical Name | 6-Chloronicotinoyl Chloride |
|---|---|
| MDL Number | MFCD00051775 |
| PubChem Substance ID | 87566696 |
| CAS Number | 58757-38-3 |
| Reaxys-RN | 115927 |
| Synonym | 6-Chloropyridine-3-carbonyl chloride 6-氯烟酰氯 6-氯-3-羰酰氯 |
| Beilstein Registry Number | 115927 |
| Alfabeta Name | CHLORONICOTINOYLCHLORIDE 6- |
| Chemical Name Translation | 6-氯-3-吡啶甲酰氯 |
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分类
- {SNA} Building Blocks, C6, Chemical Synthesis, Halogenated Heterocycles, Heterocyclic Building Blocks, Pyridines
相关文献及参考
- Acylation of dimethyl malonate has been carried out using the combination of triethylamine and magnesium chloride (see Diethyl malonate, A15468, and Triethylamine, A12646, for discussion), followed by one-pot hydrolysis-decarboxylation of the acylmalonate derivative in wet DMSO, to give 5-acetyl-2-chloropyridine in good yield: Tetrahedron, 48, 9233 (1992).
- Acylation of dimethyl malonate has been carried out using the combination of triethylamine and magnesium chloride (see Diethyl malonate, A15468, and Triethylamine, A12646, for discussion), followed by one-pot hydrolysis-decarboxylation of the acylmalonate derivative in wet DMSO, to give 5-acetyl-2-chloropyridine in good yield: Tetrahedron, 48, 9233 (1992).
安全信息
GHS Symbol
- P501 Dispose of contents/container to..… 处理内容物/容器.....
- P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
- P260 Do not breathe dust/fume/gas/mist/vapours/spray. 不要吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
- P305+P351+P338+P310
- P310 Immediately call a POISON CENTER or doctor/physician. 立即呼救解毒中心或医生/医师。
- P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
- P301+P330+P331+P310
- P303+P361+P353
- P304+P340
- P304+P340+P310
- P390 Absorb spillage to prevent material damage. 吸收溢出物，防止重大损害。
- P305+P351+P338
- P301+P330+P331
- P303+P361+P353+P310+P363
- P405 Store locked up. 上锁保管。
- P234 Keep only in original container. 只保留在原来的容器中。
- P406 Store in corrosive resistant/… container with a resistant inner liner. 存放在耐腐蚀/具有耐性的内衬容器。
- P363 Wash contaminated clothing before reuse. 被污染的衣服洗净后方可重新使用。
- H290 May be corrosive to metals 可能腐蚀金属。
- H314 Causes severe skin burns and eye damage 导致严重的皮肤灼伤和眼睛损伤
- S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后，立即用大量水冲洗并征求医生意见；
- S36/37/39 Wear suitable protective clothing, gloves and eye/face protection 穿戴适当的防护服、手套和眼睛/面保护；
- S45 In case of accident or if you feel unwell seek medical advice immediately (show the label where possible) 发生事故时或感觉不适时，立即求医（可能时出示标签）；
- R34 Causes burns 会导致灼伤
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