Ethylene Dimethacrylate 二甲基丙烯酸乙二醇酯

CAS 97-90-5 MFCD00008590

化学结构图

97-90-5
SMILES: C=C(C)C(=O)OCCOC(=O)C(=C)C

化学属性

Mol. FormulaC10H14O4
Mol. Weight198.22
Density1.051
Refractive index1.4530 to 1.4560
Vapor Density>;1 (vs air)
Boiling Point98-100 °C at 5 mmHg
Vapor Pressure<;0.1 mmHg ( 21.1 °C)
Flash Point118°C(lit.)
TSCAYes
Melting Point-40 °C
Solubility可溶

别名和识别编码

Chemical NameEthylene Dimethacrylate
CAS Number97-90-5
EC Number202-617-2
Beilstein Registry Number1776663
MDL NumberMFCD00008590
Synonym Ethylene glycol dimethacrylate {LY} Ethylene glycol dimethacrylate {} {LY} Ethylene glycol dimethacrylate {} {} {LY} Ethylene glycol dimethacrylate {} {} {} {LY} Ethylene glycol dimethacrylate {} {} {} {} {LY} Ethylene glycol dimethacrylate {} {} {} {} {} {LY} Ethylene glycol dimethacrylate {} {} {} {} {} {} {LY} Ethylene glycol dimethacrylate {} {} {} {} {} {} {} {LY} Ethylene glycol dimethacrylate {} {} {} {} {} {} {} {} {LY} Ethylene glycol dimethacrylate {} {} {} {} {} {} {} {} {} {LY} Ethylene glycol dimethacrylate {} {} {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {} {} {LY} Ethylene glycol dimethacrylate {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Ethylene glycol dimethacrylate {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Ethylene glycol dimethacrylate {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Ethylene glycol dimethacrylate {} {} {} {} {} {} {} {} {}
PubChem Substance ID87569408
Chemical Name Translation二甲基丙烯酸乙二醇酯
Reaxys-RN1776663
Wiswesser Line Notation1UY1&VO2OVY1&U1
LabNetwork Molecule IDLN00193057
InChIInChI=1S/C10H14O4/c1-7(2)9(11)13-5-6-14-10(12)8(3)4/h1,3,5-6H2,2,4H3
Canonical SMILESC=C(C)C(OCCOC(C(C)=C)=O)=O
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分类

  • {uni_hamburg} no charge; ester; 1fragment
  • {SNA} Biomaterials, Building Blocks, C10 to C11, Carbonyl Compounds, Chemical Synthesis, Crosslinking Agents, Esters, Homobifunctional PEGs, Materials Science, Methacrylate, Organic Building Blocks, Poly(ethylene glycol) and Poly(ethylene oxide), Polymer Science, Polymers
  • {SNA} Biomaterials, Building Blocks, C10 to C11, Carbonyl Compounds, Chemical Synthesis, Crosslinking Agents, Esters, Homobifunctional PEGs, Methacrylate, Organic Building Blocks, Poly(ethylene glycol) and Poly(ethylene oxide),

产品应用

  • 该品为交联剂,用于制取树脂、涂料和粘合剂等。

相关文献及参考

  • Short: IV/18B
  • Beilstein:2(3)1292
  • Short: EINECS

安全信息

Signal word Warning
GHS Symbol
WGK Germany1
Safety Statements
  • S24 Avoid contact with skin 避免皮肤接触;
  • S37 Wear suitable gloves 戴适当手套;
Risk Statements
  • R37 Irritating to respiratory system 刺激呼吸道
  • R43 May cause sensitisation by skin contact 皮肤接触会产生过敏反应
Precautionary statements
  • P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P271 Use only outdoors or in a well-ventilated area.? 只能在室外或通风良好的地方使用。
  • P272 Contaminated work clothing should not be allowed out of the workplace. 污染的工作服不得带出工作场所。
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P302+P352+P333+P313+P362+P364
  • P304+P340+P312
  • P312 Call a POISON CENTER or doctor/physician if you feel unwell. 如果你感觉不适,呼叫解毒中心或医生/医师。
  • P403+P233
  • P405 Store locked up. 上锁保管。
  • P501 Dispose of contents/container to..… 处理内容物/容器.....
Hazard statements
  • H317 May cause an allergic skin reaction 可能导致皮肤过敏
  • H335 May cause respiratory irritation 可能导致呼吸道刺激
  • H303 May be harmfully swallowed 吞食可能有害
Personal Protective Equipment Eyeshields, Faceshields, full-face respirator (US), Gloves, multi-purpose combination respirator cartridge (US), type ABEK (EN14387) respirator filter
RTECSOZ4400000
Hazard Codes 9
Packing GroupIII
UN Number 3334
Storage condition 2-8°C {LY} 2-8°C {} {LY} 2-8°C {} {} {LY} 2-8°C {} {} {} {LY} 2-8°C {} {} {} {} {LY} 2-8°C {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {
TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Rodent - mouse
DOSE/DURATION           : 2 gm/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   GTPZAB Gigiena Truda i Professional'nye Zabolevaniya.  Labor Hygiene and
   Occupational Diseases. (V/O Mezhdunarodnaya Kniga, 113095 Moscow, USSR)
   V.1-36, 1957-1992. For publisher information, see MTPEEI
   Volume(issue)/page/year: 24(4),58,1980

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Rodent - rat
DOSE/DURATION           : 3300 mg/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   GTPZAB Gigiena Truda i Professional'nye Zabolevaniya.  Labor Hygiene and
   Occupational Diseases. (V/O Mezhdunarodnaya Kniga, 113095 Moscow, USSR)
   V.1-36, 1957-1992. For publisher information, see MTPEEI
   Volume(issue)/page/year: 24(4),58,1980

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Intraperitoneal
SPECIES OBSERVED        : Rodent - rat
DOSE/DURATION           : 2800 mg/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   AMPMAR Archives des Maladies Professionnelles de Medecine du Travail et de
   Securite Sociale.  (SPPIF, B.P.22, F-41353 Vineuil, France)  V.7-    1946-
   Volume(issue)/page/year: 36,58,1975

TYPE OF TEST            : Mutation in mammalian somatic cells
TEST SYSTEM             : Rodent - mouse Lymphocyte
DOSE/DURATION           : 5820 umol/L
REFERENCE :
   EMMUEG Environmental and Molecular Mutagenesis.  (Alan R. Liss, Inc., 41 E.
   11th St., New York, NY 10003)  V.10-    1987-  Volume(issue)/page/year:
   17,264,1991

其他信息

  • 海关编码:29161490
  • 图谱信息:乙二醇二甲基丙烯酸酯(97-90-5)核磁图( 1 HNMR) 乙二醇二甲基丙烯酸酯(97-90-5)红外图谱(IR1) 乙二醇二甲基丙烯酸酯(97-90-5)核磁图( 13 CNMR) 乙二醇二甲基丙烯酸酯(97-90-5)Raman光谱 乙二醇二甲基丙烯酸酯(97-90-5)质谱(MS)
  • 毒性分级:中毒
  • TCI Shanghai:乙二醇二甲基丙烯酸酯(含稳定剂氢醌) Ethylene Glycol Dimethacrylate (stabilized with HQ),>;97.0%(GC)(97-90-5)
  • MOL 文件:97-90-5.mol
  • 微溶于水。
  • MSDS 信息:双甲基丙烯酸乙二醇酯(97-90-5).msds
  • 类别:有毒物品
  • 方法一:由乙二醇与甲基丙烯酸在硫酸催化下直接酯化,所得粗品经减压精馏后成品。
  • Alfa Aesar:二甲基丙烯酸乙二醇酯,98%,含100ppmMEHQ做稳定剂 Ethylene glycol dimethacrylate, 98%, stab. with 100ppm 4-methoxyphenol(97-90-5)
  • F:8-19
  • 急性毒性:口服-大鼠 LD50: 3300 毫克/公斤; 口服-小鼠 LD50: 2000 毫克/公斤
  • Acros Organics:二甲基丙烯酸乙二醇酯 Ethylene dimethacrylate, stabilized, 98%(97-90-5)
  • 储运特性:库房通风低温干燥
  • 蒸气密度:>;1 (vs air)
  • 灭火剂:干粉,泡沫,砂土,二氧化碳, 雾状水
  • 可燃性危险特性:可燃; 受热分解刺激烟雾
  • 乙二醇二甲基丙烯酸酯价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2011/08/23 A33568102 乙二醇二甲基丙烯酸酯 100ml 544元 2011/08/23 K0380801 乙二醇二甲基丙烯酸酯(+4℃) 100ml 427元 2011/04/16 E0102 乙二醇二甲基丙烯酸酯(含稳定剂HQ) Ethylene Glycol Dimethacrylate (stabilized with HQ) 25ML 183元
  • Sigma Aldrich:97-90-5(sigmaaldrich)
  • 用途一:该品为交联剂,用于制取树脂、涂料和粘合剂等。
  • 外观性质:无色液体。
  • 上游原料:2-甲基丙烯酸
  • 蒸气压:<;0.1 mm Hg ( 21.1 °C)

系列性分类


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