Alpha,Alpha'-Dibromo-P-Xylene α,α′-二溴-对二甲苯

CAS 623-24-5 MFCD00000182

化学结构图

623-24-5
SMILES: BrCc1ccc(CBr)cc1

化学属性

Mol. FormulaC8H8Br2
Mol. Weight264
Boiling Point245
Melting Point143-145
Density2.012
TSCAYes
Solubility可溶, HYDROLYSES
Flash Point155-158°C/14mm
Refractive index1.614

别名和识别编码

Chemical NameAlpha,Alpha'-Dibromo-P-Xylene
CAS Number623-24-5
Synonym 1 1,4-BIS(BROMOMETHYL)BENZENE 1,4-Bis(bromomethyl)benzene, alpha,alpha'-Dibromo-p-xylene 1,4-Bis-(brommethyl)-benzol 1,4-Dibromomethylbenzene 1,4-bis(bromomethyl)-benzen 1,4-di(bromoethyl)benzene 4-Bromomethylbenzyl Bromide 4-二(溴甲基)苯,二溴对二甲苯 p-Xylene, α,α'-dibromo- p-dibromoxylene A,A'-Dibrom-p-xylol A,A'-DIBROMO-P-XYLENE ALPHA,ALPHA'-DIBROMO-P-XYLENE Benzene, 1,4-bis[bromomethyl]- LABOTEST-BB LT OMEGA,OMEGA'-DIBROMO-P-XYLENE P-XYLENE DIBROMIDE α'-二溴对二甲苯 α,α'-Dibrom-p-xylol α,α'-二溴对二甲苯 对二溴苄
PubChem Substance ID69335
EC Number210-781-1
Beilstein Registry Number1100019
MDL NumberMFCD00000182
Reaxys-RN1100019
Chemical Name Translationα,α′-二溴-对二甲苯
InChIKeyRBZMSGOBSOCYHR-UHFFFAOYSA-N
LabNetwork Molecule IDLN00116148
InChIInChI=1S/C8H8Br2/c9-5-7-1-2-8(6-10)4-3-7/h1-4H,5-6H2
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分类

  • {SNA} Aryl, Building Blocks, C8, Chemical Synthesis, Halogenated Hydrocarbons, Organic Building Blocks
  • {uni_hamburg} no charge; carbocycle; aromatic; 6RingOnly; 6ring; 1fragment
  • Aryl, Building Blocks, C8, Chemical Synthesis, Halogenated Hydrocarbons, Organic Building Blocks

相关文献及参考

  • Beilstein:5,385
  • Reductive coupling has been used in a relatively high-yielding route to [2,2]-p-cyclophanes: Chem. Lett., 13 (1989); J. Chem. Soc., Perkin 1, 2029 (1991). Used in template-directed synthesis of rigid cyclophane receptor: Synlett, 462 (1991). For use in rotaxane synthesis, see: Synlett, 8975 (1992).
  • Short: III/20b
  • Short: IV/1a

安全信息

GHS Symbol
WGK Germany3
Hazard statements
  • H290 May be corrosive to metals 可能腐蚀金属。
  • H315 Causes skin irritation 会刺激皮肤
  • H319 Causes serious eye irritation 严重刺激眼睛
  • H335 May cause respiratory irritation 可能导致呼吸道刺激
  • H314 Causes severe skin burns and eye damage 导致严重的皮肤灼伤和眼睛损伤
Personal Protective Equipment Eyeshields, Faceshields, full-face particle respirator type N100 (US), Gloves, respirator cartridge type N100 (US), type P1 (EN143) respirator filter, type P3 (EN 143) respirator cartridges
Hazard Codes 6.1 C
Precautionary statements
  • P260 Do not breathe dust/fume/gas/mist/vapours/spray. 不要吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P271 Use only outdoors or in a well-ventilated area.? 只能在室外或通风良好的地方使用。
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P284 Wear respiratory protection.? 佩戴呼吸保护装置。
  • P303+P361+P353
  • P304+P340+P310
  • P305+
  • P305+P351+P338
  • P305+P351+P338+P310
  • P310 Immediately call a POISON CENTER or doctor/physician. 立即呼救解毒中心或医生/医师。
  • P314 Get medical advice/attention if you feel unwell. 获取医疗咨询/就医,如果你觉得不舒服
  • P403+P233
  • P501 Dispose of contents/container to..… 处理内容物/容器.....
Signal word Danger
Safety Statements
  • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后,立即用大量水冲洗并征求医生意见;
  • S36/37/39 Wear suitable protective clothing, gloves and eye/face protection 穿戴适当的防护服、手套和眼睛/面保护;
  • S45 In case of accident or if you feel unwell seek medical advice immediately (show the label where possible) 发生事故时或感觉不适时,立即求医(可能时出示标签);
Risk Statements
  • R34 Causes burns 会导致灼伤
UN Number 2928 3448 UN 3448 6.1/PG 2
Packing GroupII
Hazard Class6.1/8

其他信息

  • TCI Shanghai:α、α-二溴对二甲苯 alpha,alpha'-Dibromo-p-xylene,>;98.0%(GC)(623-24-5)
  • 1,4-二(溴甲基)苯价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2014/06/02 D0216 α,α-二溴对二甲苯 alpha,alpha'-Dibromo-p-xylene 25G 605元 2010/06/21 112941000 1,4-二(溴甲基)苯 alpha,alpha'-Dibromo-p-xylene 97% 100 GR 3043元 2010/06/21 112940250 1,4-二(溴甲基)苯 alpha,alpha'-Dibromo-p-xylene 97% 25 GR 983元
  • F:8-19-21
  • Acros Organics:alpha,alpha-二溴对二甲苯 alpha,alpha'-Dibromo-p-xylene, 97%(623-24-5)
  • MSDS 信息:1,4-Bis(Bromomethyl)benzene(623-24-5).msds
  • Hazard Note:Corrosive/Lachrymatory
  • MOL 文件:623-24-5.mol
  • 外观性质:可溶于水并分解。密度: 2.012熔点: 142-147 °C沸点: 245 °C
  • Alfa Aesar:二溴对二甲苯,97% p-Xylylene dibromide, 97%(623-24-5)
  • 可溶于水并分解。
  • 上游原料:二氯甲烷 --> 四氯化碳 --> N-溴代丁二酰亚胺 --> 过氧化二苯甲酰 --> 三溴化磷 --> 对二甲苯 --> 对苯二甲醇
  • Sigma Aldrich:623-24-5(sigmaaldrich)
  • 图谱信息:1,4-二(溴甲基)苯(623-24-5)质谱(MS) 1,4-二(溴甲基)苯(623-24-5)红外图谱(IR2) 1,4-二(溴甲基)苯(623-24-5)Raman光谱 1,4-二(溴甲基)苯(623-24-5)红外图谱(IR1)
  • 敏感性:Lachrymatory

系列性分类


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