1,4,8,11-Tetraazacyclotetradecane 1,4,8,11-四氮杂环十四烷
CAS 295-37-4 MFCD00005105
化学结构图
SMILES: C1CNCCNCCCNCCNC1
化学属性
| Mol. Formula | C10H24N4 |
|---|---|
| Mol. Weight | 200 |
| Density | 1.422 |
| Melting Point | 185-188 |
| TSCA | No |
| Stability | 对湿度敏感 |
别名和识别编码
| Chemical Name | 1,4,8,11-Tetraazacyclotetradecane |
|---|---|
| CAS Number | 295-37-4 |
| Synonym | 1,1',1''-(1,4,8,11-Tetraazacyclotetradecane-1,4,8-triyl)tris[2,2,2-trifluoro-ethanone 1,4,8,11-TETRAAZACYCLOTETRADECANE(CYCLAM) 1,4,8,11-TETRAAZACYCLOTETRADECANE, 98+% 1,4,8,11-Tetraazacyclotetradecane 98% 1,4,8,11-四叠氮环十四烷 1,4,8,11-四氮杂环十四烷 1,4,8,11-四氮环十四烷 1,4,8,11-四氮环十四烷, 98+% 1,4,8-Tris(trifluoroacetyl)-1,4,8,11-tetraazacyclo 1,4,8-Tris(trifluoroacetyl)-1,4,8,11-tetraazacyclotetradecane CYCLAM Cyclam Cyclam, 98+% Cyclam=1,4,8,11-Tetraazacyclotetradecane JM 1498 jm1498 |
| EC Number | 206-039-1 |
| Beilstein Registry Number | 111811 |
| MDL Number | MFCD00005105 |
| PubChem Substance ID | 64964 |
| Alfabeta Name | TETRAAZACYCLOTETRADECANE 14811-,,, |
| Reaxys-RN | 111811 |
| Chemical Name Translation | 1,4,8,11-四氮杂环十四烷 |
| InChIKey | MDAXKAUIABOHTD-UHFFFAOYSA-N |
| LabNetwork Molecule ID | LN00184756 |
| InChI | InChI=1S/C10H24N4/c1-3-11-7-9-13-5-2-6-14-10-8-12-4-1/h11-14H,1-10H2 |
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分类
- {SNA} ATRP, ATRP Ligands, Chelation/Complexation Compounds, Chemical Synthesis, Crown Ethers, Materials Science, Polymer Science, Reagents for Controlled Radical Polymerization, Reagents for Polymerization, Synthetic Reagents
- {SNA} ATRP, ATRP Ligands, Chelation/Complexation Compounds, Chemical Synthesis, Crown Ethers, Polymer Science, Reagents for Controlled Radical Polymerization, Reagents for Polymerization, Synthetic Reagents, 材料科学
- Heterocycles
- Pharmaceuticals
- Intermediates & Fine Chemicals
- {uni_hamburg} no charge; nitrogen heterocycle; alicycle; large ring; 14ring; 1fragment
产品应用
- Reagent used in the preparation of Plerixafor derivatives.
相关文献及参考
- The Ni(II) complex catalyzes the novel electrochemical reaction of epoxides with carbon dioxide to give good yields of cyclic carbonates: J. Chem. Soc., Chem. Commun., 43 (1995). A similar system catalyzes the electrochemical intramolecular reductive cyclization of a series of o-halogenated aryl alkenes: Tetrahedron Lett., 36, 4429 (1995):
- For use in synthesis of molecules with electroactive cavities, see (Ferrocenylmethyl)trimethylammonium iodide, 39399.
- Nitrogen analogue of the crown ethers (see Appendix 2), forming stable complexes with metal ions: Inorg. Chem., 4,1102, 1109 (1965); Can. J. Chem., 48, 1481 (1970). For examples
- Short: III/35B
- Short: IV/20C
- Complex with iron(II) triflate is an effective epoxidation catalyst: J. Am. Chem. Soc., 113, 7052 (1991).
- Short: EINECS
- Nitrogen analogue of the crown ethers (see Appendix 2), forming stable complexes with metal ions: Inorg. Chem., 4,1102, 1109 (1965); Can. J. Chem., 48, 1481 (1970). For examples of use as a versatile ligand in coordination chemistry, see: Acc. Chem. Res., 11, 392 (1978); J. Chem. Soc., Chem. Commun., 1322 (1986); 1075 (1987); 156 (1988); Inorg. Chem., 26, 908 (1987); J. Am. Chem. Soc., 110, 3679 (1988).
- Jacobson, O., et al.: Bioorg. Med. Chem., 17, 1486 (2009),
安全信息
GHS Symbol
- S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后，立即用大量水冲洗并征求医生意见；
- S36 Wear suitable protective clothing 穿戴适当的防护服；
- S36/37/39 Wear suitable protective clothing, gloves and eye/face protection 穿戴适当的防护服、手套和眼睛/面保护；
- S37 Wear suitable gloves 戴适当手套；
- R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
- P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
- P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
- P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
- P302+P352+P332+P313+P362+P364
- P305+P351+P338
- P305+P351+P338+P337+P313
- P362 Take off contaminated clothing and wash before reuse. 脱掉污染的衣服，清洗后方可重新使用
- H315 Causes skin irritation 会刺激皮肤
- H319 Causes serious eye irritation 严重刺激眼睛
- H335 May cause respiratory irritation 可能导致呼吸道刺激
TYPE OF TEST : LD50 - Lethal dose, 50 percent kill ROUTE OF EXPOSURE : Intraperitoneal SPECIES OBSERVED : Rodent - mouse DOSE/DURATION : 371 mg/kg TOXIC EFFECTS : Behavioral - convulsions or effect on seizure threshold Skin and Appendages - primary irritation (after topical exposure) REFERENCE : CMSHAF Chemosphere. (Pergamon Press Inc., Maxwell House, Fairview Park, Elmsford, NY 10523) V.1- 1972- Volume(issue)/page/year: 17,839,1988
其他信息
- MOL 文件:295-37-4.mol
- F:3-9-34
- Alfa Aesar:1,4,8,11-四氮环十四烷,98+% 1,4,8,11-Tetraazacyclotetradecane, 98+%(295-37-4)
- 敏感性:Air Sensitive
- 存储注意事项:湿度敏感
- Acros Organics:1,4,8,11-四氮杂环十四烷 1,4,8,11-Tetraazacyclotetradecane, 99+%(295-37-4)
- Sigma Aldrich:295-37-4(sigmaaldrich)
- 图谱信息:1,4,8,11-四氮杂环十四烷(295-37-4)质谱(MS) 1,4,8,11-四氮杂环十四烷(295-37-4)核磁图( 1 HNMR) 1,4,8,11-四氮杂环十四烷(295-37-4)核磁图( 13 CNMR)
- TCI Shanghai:1,4,8,11-四氮杂环十四烷 1,4,8,11-Tetraazacyclotetradecane,>;98.0%(T)(295-37-4)
- 1,4,8,11-四氮杂环十四烷价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2014/06/02 T1597 1,4,8,11-四氮杂环十四烷 1,4,8,11-Tetraazacyclotetradecane 5G 3230元 2014/06/02 T1597 1,4,8,11-四氮杂环十四烷 1,4,8,11-Tetraazacyclotetradecane 1G 941元 2010/06/21 269330050 1,4,8,11-四氮杂环十四烷 1,4,8,11-Tetraazacyclotetradecane 99+% 5 GR 2615元
- 1,4,8,11-四氮杂环十四烷价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2011/04/16 T1597 1,4,8,11-四氮杂环十四烷 1,4,8,11-Tetraazacyclotetradecane 5G 3520元 2011/04/16 T1597 1,4,8,11-四氮杂环十四烷 1,4,8,11-Tetraazacyclotetradecane 1G 1030元 2010/06/21 269330050 1,4,8,11-四氮杂环十四烷 1,4,8,11-Tetraazacyclotetradecane 99+% 5 GR 2615元
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