4-Bromo-1,2-difluorobenzene 4-溴-1,2-二氟苯

CAS 348-61-8 MFCD00000304

化学结构图

348-61-8
SMILES: Fc1ccc(Br)cc1F

化学属性

Mol. FormulaC6H3BrF2
Mol. Weight192.99
Boiling Point150-151 °C at 760 mmHg
Density1.707
Refractive index1.5040 to 1.5060
Flash Point33°C(lit.)
TSCANo
Melting Point-4 °C
Appearance 无色透明液体。沸点150-151℃,闪点33℃,折光率1.4990,比重 1.707。
Solubilityinsoluble
pH:A

别名和识别编码

Chemical Name1-Bromo-3,4-difluorobenzene
CAS Number348-61-8
Alfabeta NameBROMODIFLUOROBENZENE 134---,
MDL NumberMFCD00000304
Synonym 1-Bromo-3,4-difluorobenzene {LY} 1-Bromo-3,4-difluorobenzene {} {LY} 1-Bromo-3,4-difluorobenzene {} {} {LY} 1-Bromo-3,4-difluorobenzene {} {} {} {LY} 1-Bromo-3,4-difluorobenzene {} {} {} {} {LY} 1-Bromo-3,4-difluorobenzene {} {} {} {} {} {LY} 1-Bromo-3,4-difluorobenzene {} {} {} {} {} {} {LY} 1-Bromo-3,4-difluorobenzene {} {} {} {} {} {} {} {LY} 1-Bromo-3,4-difluorobenzene {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {LY} 1-Bromo-3,4-difluorobenzene {} {} {} {} {} {} {} {} {} {LY} 1-Bromo-3,4-difluorobenzene {} {} {} {} {} {} {} {} {} {} {LY} 1-Bromo-3,4-difluorobenzene {} {} {} {} {} {} {} {} {} {} {} {LY} 1-Bromo-3,4-difluorobenzene {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 1-Bromo-3,4-difluorobenzene {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 1-Bromo-3,4-difluorobenzene {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 1-Bromo-3,4-difluorobenzene {} {} {} {} {} {} {} {} {} {} {}
EC Number206-481-5
Beilstein Registry Number1934811
PubChem Substance ID67675
Chemical Name Translation4-溴-1,2-二氟苯
Reaxys-RN1934811
InChIKeyYMQPKONILWWJQG-UHFFFAOYSA-N
LabNetwork Molecule IDLN00008503
InChIInChI=1S/C6H3BrF2/c7-4-1-2-5(8)6(9)3-4/h1-3H
Canonical SMILESFC1=CC=C(Br)C=C1F
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分类

  • {SNA} Aryl, Aryl Fluorinated Building Blocks, Building Blocks, C6, Chemical Synthesis, Fluorinated Building Blocks, Halogenated Hydrocarbons, Organic Building Blocks, Organic Fluorinated Building Blocks, Other Fluorinated Organic Building Blocks

产品应用

  • 1-Bromo-3,4-difluorobenzene has been used in the preparation of 4-benzyl-2-(3,4-difluorophenyl)-2-hydroxy-morpholine.

安全信息

Warnings IRRITANT
Packing GroupIII
UN Number 1993
Risk Statements
  • R10 Flammable 易燃
  • R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
Safety Statements
  • S16 Keep away from sources of ignition - No smoking 远离火源,禁止吸烟;
  • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后,立即用大量水冲洗并征求医生意见;
  • S36/37/39 Wear suitable protective clothing, gloves and eye/face protection 穿戴适当的防护服、手套和眼睛/面保护;
GHS Symbol
WGK Germany2
Hazard statements
  • H226 Flammable liquid and vapour 易燃液体和蒸气
  • H302 Harmful if swallowed 吞食有害
  • H315 Causes skin irritation 会刺激皮肤
  • H317 May cause an allergic skin reaction 可能导致皮肤过敏
  • H319 Causes serious eye irritation 严重刺激眼睛
  • H332 Harmful if inhaled 吸入有害
  • H335 May cause respiratory irritation 可能导致呼吸道刺激
  • H411 Toxictoaquaticlifewithlonglastingeffects 对水生生物有毒性并具有长期影响。
Personal Protective Equipment Eyeshields, Faceshields, full-face respirator (US), Gloves, multi-purpose combination respirator cartridge (US), type ABEK (EN14387) respirator filter
Precautionary statements
  • P210 Keep away from heat/sparks/open flames/hot surfaces. — No smoking. 远离热源/火花/明火/热的表面。——禁止吸烟。
  • P233 Keep container tightly closed. ?保持容器密闭。
  • P240 Ground/bond container and receiving equipment. 与地面接触/连接集装箱和接受设备。
  • P241 Use explosion-proof electrical/ventilating/lighting/…/equipment. 使用防爆电气/通风/照明/ .../设备。
  • P241+P242+P243
  • P242 Use only non-sparking tools. 只能使用无火花工具。
  • P243 Take precautionary measures against static discharge. 采取预防措施,防止静电放电。
  • P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
  • P264+P265
  • P270 Do not eat, drink or smoke when using this product. 使用本产品时不要吃东西,喝水或吸烟。
  • P271 Use only outdoors or in a well-ventilated area.? 只能在室外或通风良好的地方使用。
  • P272 Contaminated work clothing should not be allowed out of the workplace. 污染的工作服不得带出工作场所。
  • P273 Avoid release to the environment. 避免释放到环境中。
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P301+P317
  • P302+P352
  • P302+P352+P332+P313+P362+P364
  • P303+P361+P353
  • P304+P340
  • P305+P351+P338
  • P305+P351+P338+P337+P313
  • P317
  • P319
  • P321 Specific treatment (see … on this label). 具体治疗(见本标签上的)。
  • P330 Rinse mouth. 漱口
  • P332+P313
  • P332+P317
  • P333+P313
  • P333+P317
  • P337+P313
  • P337+P317
  • P362 Take off contaminated clothing and wash before reuse. 脱掉污染的衣服,清洗后方可重新使用
  • P362+P364
  • P370+P378
  • P391 Collect spillage. Hazardous to the aquatic environment 收集对水环境有危害的泄漏物。
  • P403+P233
  • P403+P235
  • P405 Store locked up. 上锁保管。
  • P501 Dispose of contents/container to..… 处理内容物/容器.....
Signal word Warning
Hazard Codes 3
Hazard Class3
Storage condition Store at room temperature {LY} Store at room temperature {} {LY} Store at room temperature {} {} {LY} Store at room temperature {} {} {} {LY} Store at room temperature {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {}

其他信息

  • Sigma Aldrich:348-61-8(sigmaaldrich)
  • 用途二:医药、农药、液晶材料中间体。
  • Alfa Aesar:4-溴-1,2-二氟苯,98+% 4-Bromo-1,2-difluorobenzene, 98+%(348-61-8)
  • MOL 文件:348-61-8.mol
  • 用途一:用作医药、液晶材料中间体
  • TCI Shanghai:3,4-二氟溴苯 1-Bromo-3,4-difluorobenzene,>;97.0%(GC)(348-61-8)
  • Acros Organics:3,4-二氟溴苯 1-Bromo-3,4-difluorobenzene, 98%(348-61-8)
  • 图谱信息:3,4-二氟溴苯(348-61-8)核磁图( 1 HNMR) 3,4-二氟溴苯(348-61-8)红外图谱(IR1) 3,4-二氟溴苯(348-61-8)质谱(MS) 3,4-二氟溴苯(348-61-8)核磁图( 13 CNMR)
  • 上游原料:氢溴酸 --> 溴化亚铜
  • 3,4-二氟溴苯价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2014/06/02 B1523 1-溴-3,4-二氟苯 1-Bromo-3,4-difluorobenzene 25G 1250元 2014/06/02 B1523 1-溴-3,4-二氟苯 1-Bromo-3,4-difluorobenzene 250G 6020元 2010/06/21 233190100 3,4-二氟溴苯 1-Bromo-3,4-difluorobenzene 98% 10 GR 790元
  • MSDS 信息:1-Bromo-3,4-difluorobenzene(348-61-8).msds
  • Hazard Note:Flammable

系列性分类


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