2,6-Difluorobenzyl Bromide 2,6-二氟溴苄

CAS 85118-00-9 MFCD00000329

化学结构图

85118-00-9
SMILES: FC1C=CC=C(F)C=1CBr

化学属性

Mol. FormulaC7H5BrF2
Mol. Weight207.02
Melting Point52-55°C
Density1.625
Flash Point>110°C
TSCANo
Boiling Point184.9±25.0 °C at 760 mmHg

别名和识别编码

Chemical Name2,6-Difluorobenzyl Bromide
CAS Number85118-00-9
Alfabeta NameDIFLUOROBENZYLBROMIDE 26-,
MDL NumberMFCD00000329
Synonym 2-(Bromomethyl)-1,3-difluorobenzene {LY} 2-(Bromomethyl)-1,3-difluorobenzene {} {LY} 2-(Bromomethyl)-1,3-difluorobenzene {} {} {LY} 2-(Bromomethyl)-1,3-difluorobenzene {} {} {} {LY} 2-(Bromomethyl)-1,3-difluorobenzene {} {} {} {} { {} {} {} {} {LY} 2-(Bromomethyl)-1,3-difluorobenzene {} {} {} {} {} {LY} 2-(Bromomethyl)-1,3-difluorobenzene {} {} {} {} {} {} {LY} 2-(Bromomethyl)-1,3-difluorobenzene {} {} {} {} {} {} {} {LY} 2-(Bromomethyl)-1,3-difluorobenzene {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {LY} 2-(Bromomethyl)-1,3-difluorobenzene {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-(Bromomethyl)-1,3-difluorobenzene {} {} {} {} {} {} {} {} {} {} {LY} 2-(Bromomethyl)-1,3-difluorobenzene {} {} {} {} {} {} {} {} {} {} {} {LY} 2-(Bromomethyl)-1,3-difluorobenzene {} {} {} {} {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-(Bromomethyl)-1,3-difluorobenzene {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-(Bromomethyl)-1,3-dif
PubChem Substance ID87568998
EC Number285-652-6
Beilstein Registry Number2083943
Reaxys-RN2083943
Chemical Name Translation2,6-二氟溴苄
LabNetwork Molecule IDLN00116695
Canonical SMILESFC1=C(CBr)C(F)=CC=C1
信息真实价格透明    资金保障    专业采购外包团队在线服务   
信息真实价格透明    资金保障    专业采购外包团队在线服务   
品牌质保精细包装    现货库存    一流品牌服务   

分类

  • {SNA} Aryl, Aryl Fluorinated Building Blocks, Building Blocks, C7, Chemical Synthesis, Fluorinated Building Blocks, Halogenated Hydrocarbons, Organic Building Blocks, Organic Fluorinated Building Blocks, Other Fluorinated Organic Building Blocks

相关文献及参考

  • Reagent for protection of alcohols as 2,6-difluorobenzyl ethers which can be formed in the presence of Ba(OH)2 in DMF: Helv. Chim. Acta, 79, 1159 (1996). Unlike benzyl ethers, these are stable during cationic reactions. They can be cleaved by dissolving metal reduction (Ca/NH3): Chimia, 329 (1991).

安全信息

Warnings LACHRYMATOR, CORROSIVE
GHS Symbol
WGK Germany3
Hazard statements
  • H290 May be corrosive to metals 可能腐蚀金属。
  • H314 Causes severe skin burns and eye damage 导致严重的皮肤灼伤和眼睛损伤
Personal Protective Equipment Eyeshields, Faceshields, full-face particle respirator type N100 (US), Gloves, respirator cartridge type N100 (US), type P1 (EN143) respirator filter, type P3 (EN 143) respirator cartridges
Precautionary statements
  • P304+P340+
  • P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
  • P501 Dispose of contents/container to..… 处理内容物/容器.....
  • P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P305+P351+P338
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P304+P340
  • P303+P361+P353
  • P310 Immediately call a POISON CENTER or doctor/physician. 立即呼救解毒中心或医生/医师。
  • P260 Do not breathe dust/fume/gas/mist/vapours/spray. 不要吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P305+P351+P338+P310
  • P301+P330+P331+P310
Signal word Danger
Safety Statements
  • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后,立即用大量水冲洗并征求医生意见;
  • S36/37/39 Wear suitable protective clothing, gloves and eye/face protection 穿戴适当的防护服、手套和眼睛/面保护;
  • S45 In case of accident or if you feel unwell seek medical advice immediately (show the label where possible) 发生事故时或感觉不适时,立即求医(可能时出示标签);
  • S60 This material and its container must be disposed of as hazardous waste 该物质及其容器必须作为危险废物处置;
  • S20 When using do not eat or drink 使用时,不得进食,饮水;
  • S25 Avoid contact with eyes 避免眼睛接触;
Packing GroupII
UN Number UN 3261 8/PG 2 UN1759
Risk Statements
  • R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
  • R34 Causes burns 会导致灼伤
Hazard Codes C
Hazard Class8
Storage condition 2-8°C {LY} 2-8°C {} {LY} 2-8°C {} {} {LY} 2-8°C {} {} {} {LY} 2-8°C {} {} {} {} {LY} 2-8°C {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {}

其他信息

  • MOL 文件:85118-00-9.mol
  • Acros Organics:alpha-溴-2,6-二氟甲苯 alpha-Bromo-2,6-difluorotoluene, 97%(85118-00-9)
  • Hazard Note:Corrosive/Lachrymatory
  • 2,6-二氟溴苄价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2011/04/16 D2576 2,6-二氟苄溴 2,6-Difluorobenzyl Bromide 5G 800元 2010/06/21 303570250 2,6-二氟溴苄 alpha-Bromo-2,6-difluorotoluene 97% 25 GR 2156元 2010/06/21 303570050 2,6-二氟溴苄 alpha-Bromo-2,6-difluorotoluene 97% 5 GR 612元
  • F:10-19-21
  • Alfa Aesar:2,6-二氟苄基溴,97+% 2,6-Difluorobenzyl bromide, 97+%(85118-00-9)
  • Sigma Aldrich:85118-00-9(sigmaaldrich)
  • TCI Shanghai:2,6-二氟苄溴 2,6-Difluorobenzyl Bromide,>;98.0%(GC)(85118-00-9)
  • 敏感性:Lachrymatory

系列性分类


相关产品推荐