1-(Bromomethyl)-2-(trifluoromethyl)benzene 1-(bromomethyl)-2-(trifluoromethyl)benzene

CAS 395-44-8 MFCD00013558

化学结构图

395-44-8
SMILES: FC(F)(F)c1ccccc1CBr

化学属性

Mol. FormulaC8H6BrF3
Mol. Weight239.04
Boiling Point201.9°C at 760 mmHg
Melting Point34-35 °C
Refractive indexn20/D 1.494(lit.)
Density1.571
Flash Point83°C
TSCANo
Appearance 浅黄色液体

别名和识别编码

Chemical Name2-(Trifluoromethyl)benzyl Bromide
CAS Number395-44-8
Alfabeta NameTRIFLUOROMETHYLBENZYLBROMIDE 2()-
MDL NumberMFCD00013558
Synonym 1-(Bromomethyl)-2-(trifluoromethyl)benzene {LY} 1-(Bromomethyl)-2-(trifluoromethyl)benzene {} {LY} 1-(Bromomethyl)-2-(trifluoromethyl)benzene {} {} {LY} 1-(Bromomethyl)-2-(trifluoromethyl)benzene {} {} {} {LY} 1-(Bromomethyl)-2-(trifluoromethyl)benzene {} {} {} {} {LY} 1-(Bromomethyl)-2-(trifluoromethyl)benzene {} {} {} {} {} {LY} 1-(Bromomethyl)-2-(trifluoromethyl)benzene {} {} {} {} {} {} {LY} 1-(Bromomethyl)-2-(trifluoromethyl)benzene {} {} {} {} {} {} {} {LY} 1-(Bromomethyl)-2-(trifluoromethyl)benzene {} {} {} {} {} {} {} {} {LY} 1-(Bromomethyl)-2-(trifluoromethyl)benzene {} {} {} {} {} {} {} {} {} {LY} 1-(Bromomethyl)-2-(trifluoromethyl)benzene {} {} {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {} {} {LY} 1-(Bromomethyl)-2-(trifluoromethyl)benzene {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 1-(Bromomethyl)-2-(trifluoromethyl)benzene {} {} {} {} {} {} {} {} {} {} {} {} {LY} 1-(Bromomethyl)-2-(trifluoromethyl)benzene {} {} {} {}
PubChem Substance ID123057
EC Number206-901-7
Beilstein Registry Number2256977
Reaxys-RN2256977
Chemical Name Translation1-(bromomethyl)-2-(trifluoromethyl)benzene
InChIKeyTXVVVEUSVBLDED-UHFFFAOYSA-N
LabNetwork Molecule IDLN00008523
InChIInChI=1S/C8H6BrF3/c9-5-6-3-1-2-4-7(6)8(10,11)12/h1-4H,5H2
Canonical SMILESFC(C1=CC=CC=C1CBr)(F)F
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分类

  • {SNA} Aryl, Building Blocks, C8, Chemical Synthesis, Halogenated Hydrocarbons, Organic Building Blocks
  • Aryl, Building Blocks, C8, Chemical Synthesis, Halogenated Hydrocarbons, Organic Building Blocks

相关文献及参考

  • Has been used to protect a carbohydrate OH as its 2-(trifluoromethyl)benzyl ether (NaH/DMF). The group is stable to NBS bromination, but can be hydrogenolyzed quantitatively: Tetrahedron Lett., 38, 7833 (1997).

安全信息

Warnings IRRITANT, LACHRYMATOR, CORROSIVE
GHS Symbol
WGK Germany3
Hazard Codes C C,Xi
Hazard statements
  • H290 May be corrosive to metals 可能腐蚀金属。
  • H314 Causes severe skin burns and eye damage 导致严重的皮肤灼伤和眼睛损伤
Personal Protective Equipment Faceshields, full-face respirator (US), Gloves, Goggles, multi-purpose combination respirator cartridge (US), type ABEK (EN14387) respirator filter
Precautionary statements
  • P234 Keep only in original container. 只保留在原来的容器中。
  • P260 Do not breathe dust/fume/gas/mist/vapours/spray. 不要吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P301+P330+P331
  • P302+P361+P354
  • P303+P361+P353
  • P303+P361+P353+P310+P363
  • P304+P340
  • P304+P340+P310
  • P305+P351+P338
  • P305+P351+P338+P310
  • P305+P354+P338
  • P310 Immediately call a POISON CENTER or doctor/physician. 立即呼救解毒中心或医生/医师。
  • P316
  • P321 Specific treatment (see … on this label). 具体治疗(见本标签上的)。
  • P363 Wash contaminated clothing before reuse. 被污染的衣服洗净后方可重新使用。
  • P390 Absorb spillage to prevent material damage. 吸收溢出物,防止重大损害。
  • P405 Store locked up. 上锁保管。
  • P406 Store in corrosive resistant/… container with a resistant inner liner. 存放在耐腐蚀/具有耐性的内衬容器。
  • P501 Dispose of contents/container to..… 处理内容物/容器.....
Signal word
Safety Statements
Risk Statements
UN Number 3261
Packing GroupII
Hazard Class8
Storage condition 2-8°C {LY} 2-8°C {} {LY} 2-8°C {} {} {LY} 2-8°C {} {} {} {LY} 2-8°C {} {} {} {} {LY} 2-8°C {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {}

其他信息

  • Sigma Aldrich:395-44-8(sigmaaldrich)
  • Acros Organics:alpha'-溴-alpha,alpha,alpha-三氟邻二甲苯 alpha'-Bromo-alpha,alpha,alpha-trifluoro-o-xylene, 98%(395-44-8)
  • Hazard Note:Corrosive/Lachrymatory
  • Alfa Aesar:2-(三氟甲基)溴苄,96% 2-(Trifluoromethyl)benzyl bromide, 97+%(395-44-8)
  • MSDS 信息:2-(Trifluoromethyl)benzyl bromide(395-44-8).msds
  • MOL 文件:395-44-8.mol
  • 上游原料:四氢呋喃 --> 氢溴酸 --> 镁 --> 溴乙烷 --> 多聚甲醛 --> 邻氯三氟甲苯 --> 邻溴三氟甲苯
  • 2-(三氟甲基)苄溴价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2010/06/21 312970050 2-(三氟甲基)苄溴 alpha'-Bromo-alpha,alpha,alpha-trifluoro-o-xylene 98% 5 GR 695元 2010/05/25 B20634 2-(三氟甲基)溴苄, 96% 2-(Trifluoromethyl)benzyl bromide, 97+% 5g 700元 2010/05/25 B20634 2-(三氟甲基)溴苄, 96% 2-(Trifluoromethyl)benzyl bromide, 97+% 25g 3052元
  • 下游产品:2-(三氟甲基)苄磺酰氯
  • 敏感性:Lachrymatory

系列性分类


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