4-Fluoroiodobenzene 对氟碘苯

CAS 352-34-1 MFCD00001052

化学结构图

352-34-1
SMILES: Fc1ccc(I)cc1

化学属性

Mol. FormulaC6H4FI
Mol. Weight222.00
Boiling Point182-184°C at 760 mmHg
Melting Point-20 °C
TSCAT
Density1.925
Refractive index1.5820 to 1.5840
Flash Point68°C
Stability对光敏感

别名和识别编码

Chemical Name4-Fluoroiodobenzene
CAS Number352-34-1
Alfabeta NameFLUOROIODOBENZENE 14---
MDL NumberMFCD00001052
Synonym 4-Iodofluorobenzene {LY} 4-Iodofluorobenzene {} {LY} 4-Iodofluorobenzene {} {} {LY} 4-Iodofluorobenzene {} {} {} {LY} 4-Iodofluorobenzene {} {} {} {} {LY} 4-Iodofluorobenzene {} {} {} {} {} {LY} 4-Iodofluorobenzene {} {} {} {} {} {} {LY} 4-Iodofluorobenzene {} {} {} {} {} {} {} {LY} 4-Iodofluorobenzene {} {} {} {} {} {} {} {} {LY} 4-Iodofluorobenzene {} {} {} {} {} {} {} {} {} {LY} 4-Iodofluorobenzene {} {} {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {} {} {LY} 4-Iodofluorobenzene {} {} {} {} {} {} {} {} {} {} {} {LY} 4-Iodofluorobenzene {} {} {} {} {} {} {} {} {} {} {} {} {LY} 4-Iodofluorobenzene {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 4-Iodofluorobenzene {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 4-Iodofluorobenzene {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 4-Iodofluorobenzene {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 4-Iodofluorobenzene {} {} {} {} {} {} {} {} {} {} {} {} {} {}
EC Number206-522-7
Beilstein Registry Number1853970
PubChem Substance ID87570016
Chemical Name Translation对氟碘苯
Reaxys-RN1853970
InChIKeyKGNQDBQYEBMPFZ-UHFFFAOYSA-N
LabNetwork Molecule IDLN00008528
InChIInChI=1S/C6H4FI/c7-5-1-3-6(8)4-2-5/h1-4H
Canonical SMILESIC1=CC=C(F)C=C1
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分类

  • {SNA} Aryl, Aryl Fluorinated Building Blocks, Building Blocks, C6, Chemical Synthesis, Fluorinated Building Blocks, Halogenated Hydrocarbons, Organic Building Blocks, Organic Fluorinated Building Blocks, Other Fluorinated Organic Building Blocks
  • {uni_hamburg} no charge; carbocycle; aromatic; 6RingOnly; 6ring; 1fragment

相关文献及参考

  • Regioselective metallation can be accomplished with LDA ortho to the fluoro substituent: Tetrahedron Lett., 33, 7499 (1992). Subsequent carboxylation and F - displacement with an amine has been used to synthesize 5-iodoanthranilic acid derivatives: J. Med. Chem., 40, 717 (1997).
  • Short: III/20a
  • Short: III/31b
  • Short: III/20c
  • Beilstein:5,220

安全信息

Warnings IRRITANT
Signal word Warning
GHS Symbol
WGK Germany3
Safety Statements
  • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后,立即用大量水冲洗并征求医生意见;
  • S2637/39
  • S36 Wear suitable protective clothing 穿戴适当的防护服;
  • S36/37/39 Wear suitable protective clothing, gloves and eye/face protection 穿戴适当的防护服、手套和眼睛/面保护;
  • S37 Wear suitable gloves 戴适当手套;
  • S37/39 Wear suitable gloves and eye/face protection 穿戴适当的手套和眼睛/面保护;
  • S60 This material and its container must be disposed of as hazardous waste 该物质及其容器必须作为危险废物处置;
Risk Statements
  • R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
Precautionary statements
  • P210 Keep away from heat/sparks/open flames/hot surfaces. — No smoking. 远离热源/火花/明火/热的表面。——禁止吸烟。
  • P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P302+P352+P332+P313+P362+P364
  • P305+P351+P338
  • P305+P351+P338+P337+P313
  • P332+P313
  • P362 Take off contaminated clothing and wash before reuse. 脱掉污染的衣服,清洗后方可重新使用
  • P403+P235
  • P501 Dispose of contents/container to..… 处理内容物/容器.....
Hazard statements
  • H227 Combustible liquid 可燃液体
  • H315 Causes skin irritation 会刺激皮肤
  • H319 Causes serious eye irritation 严重刺激眼睛
  • H335 May cause respiratory irritation 可能导致呼吸道刺激
Personal Protective Equipment Eyeshields, full-face respirator (US), Gloves, multi-purpose combination respirator cartridge (US), type ABEK (EN14387) respirator filter
Storage condition 2-8°C, protect from light {LY} 2-8°C, protect from light Light Sensitive {} {LY} 2-8°C, protect from light {} {} {LY} 2-8°C, protect from light {} {} {} {LY} 2-8°C, protect from light {} {} {} {} {LY} 2-8°C, protect from light {} {} {} {} {} {LY} 2-8°C, protect from light {} {} {} {} {} {} {LY} 2-8°C, protect from light {} {} {} {} {} {} {} {LY} 2-8°C, protect from light {} {} {} {} {} {} {} {} {LY} 2-8°C, protect from light {} {} {} {} {} {} {} {} {} {LY} 2-8°C, protect from light {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, protect from light {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, protect from light {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, protect from light {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, protect from light {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, protect from light {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, protect from light {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, protect fro
Hazard Codes Xi
UN Number UN2810

其他信息

  • Sigma Aldrich:352-34-1(sigmaaldrich)
  • 图谱信息:对氟碘苯(352-34-1)质谱(MS) 对氟碘苯(352-34-1)红外图谱(IR1) 对氟碘苯(352-34-1)核磁图( 1 HNMR) 对氟碘苯(352-34-1)核磁图( 13 CNMR)
  • Acros Organics:1-Fluoro-4-iodobenzene, 99%(352-34-1)
  • TSCA:T
  • 对氟碘苯价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2014/06/02 F0237 1-氟-4-碘苯(含稳定剂铜屑) 1-Fluoro-4-iodobenzene (stabilized with Copper chip) 25G 566元 2014/06/02 F0237 1-氟-4-碘苯(含稳定剂铜屑) 1-Fluoro-4-iodobenzene (stabilized with Copper chip) 5G 202元 2010/06/21 204500500 对氟碘苯 1-Fluoro-4-iodobenzene 99% 50 ML 2231元
  • Alfa Aesar:1-氟-4-碘苯,99% 1-Fluoro-4-iodobenzene, 99%(352-34-1)
  • Hazard Note:Irritant
  • MSDS 信息:4-Fluoroiodobenzene(352-34-1).msds
  • TCI Shanghai:4-氟碘苯(含稳定剂铜屑) 1-Fluoro-4-iodobenzene (stabilized with Copper chip),>;98.0%(GC)(352-34-1)
  • 下游产品:5-碘-2-氟苯甲醛
  • MOL 文件:352-34-1.mol
  • 敏感性:Light Sensitive

系列性分类


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