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• {SNA} Alkyl, Building Blocks, Chemical Synthesis, Halogenated Hydrocarbons, Organic Building Blocks
• {uni_hamburg} no charge; 1fragment

相关文献及参考

• Short: II/24B Title: Molecular Constants mostly from Microwave, Molecular Beam, and Sub-Doppler Laser Spectroscopy: Rotational, Centrifugal Distortion and Related Constants of Diamagnetic Asymmetric Top Molecules Author: Demaison, J.; Vogt, J.; Wlodarczak, G. Editor: Hüttner, W. Source: Landolt-Börnstein, New Series Volume: II/24B Year: 2000 Keyword: Diamagnetics Diatomics; Linear Symmetric Rotors; Molecular Constants; Molecules ISBN: 3-540-65345-7 ISBN: 978-3-540-65345-5 Internet Resource: DOI:10.1007/b58835 RefComment: VIII, 525 pages. Hardcover Abstract: Volume II/24 presents the spectroscopic data on diamagnetic and paramagnetic molecules as well as on molecular ions and radicals up to date considering the publications up to and partly including 1997. The spectroscopic information collected in this volume has been obtained principally from gas phase microwave measurements. Volume II/24 is a supplement to volumes II/4, II/6, II/14, and II/19 and is planned to appear in five subvolumes, the last of which will contain the substance index taking into account all molecules worked at since 1967 in the volumes mentioned and will provide cross references to and between all tables of these. The present subvolume II/24B contains an introduction and tables of rotational and centrifugal distortion constants of asymmetric-top molecules, i.e. data which roughly specifies the frequencies of the rotational transitions of these types of rotors.
• Short: II/24C Title: Molecular Constants mostly from Microwave, Molecular Beam, and Sub-Doppler Laser Spectroscopy: Dipole Moments, Quadrupole Coupling Constants, Hindered Rotation and Magnetic Interaction Constants of Diamagnetic Molecules Author: Demaison, J.; Hübner, H.; Hüttner, W.; Vogt, J.; Wlodarczak, G. Editor: Hüttner, W. Source: Landolt-Börnstein, New Series Volume: II/24C Year: 2002 Keyword: Atoms; Molecules and Cluster; Physical Chemistry; asZeeman effect parameters; electric dipole moments; hind

安全信息

GHS Symbol

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Intraperitoneal
SPECIES OBSERVED        : Rodent - rat
DOSE/DURATION           : 1241 mg/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   34ZIAG "Toxicology of Drugs and Chemicals," Deichmann, W.B., New York,
   Academic Press, Inc., 1969  Volume(issue)/page/year: -,756,1969

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Intraperitoneal
SPECIES OBSERVED        : Rodent - mouse
DOSE/DURATION           : 594 mg/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   34ZIAG "Toxicology of Drugs and Chemicals," Deichmann, W.B., New York,
   Academic Press, Inc., 1969  Volume(issue)/page/year: -,756,1969

TYPE OF TEST            : LC50 - Lethal concentration, 50 percent kill
ROUTE OF EXPOSURE       : Inhalation
SPECIES OBSERVED        : Rodent - rat
DOSE/DURATION           : 6700 mg/m3/4H
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   34ZIAG "Toxicology of Drugs and Chemicals," Deichmann, W.B., New York,
   Academic Press, Inc., 1969  Volume(issue)/page/year: -,756,1969

其他信息

• 海关编码:29033080
• 毒性分级:中毒
• Alfa Aesar:1-碘-2-甲基丙烷,98%,stab.withcopper 1-Iodo-2-methylpropane, 98%, stab. with copper(513-38-2)
• 蒸气密度:6 (vs air)
• 灭火剂:干粉、干砂、二氧化碳、泡沫、1211灭火剂
• 急性毒性:腹腔- 大鼠 LD50: 1241 毫克/ 公斤; 腹腔- 小鼠 LD50: 594 毫克/ 公斤
• 用途二:用作溶剂、分析试剂、有机合成原料。
• MSDS 信息:1-碘-2-甲基丙烷(513-38-2).msds
• 类别:易燃液体
• 用途一:用作有机溶剂，也用于有机合成
• 外观性质:无色或微黄色液体，见光变成棕色。
• Sigma Aldrich:513-38-2(sigmaaldrich)
• 蒸气压:20 mm Hg ( 20 °C)
• 上游原料:异丁醇
• Acros Organics:1-碘-2-甲基丙烷 1-Iodo-2-methylpropane, stabilized, 97%(513-38-2)
• 图谱信息:碘代异丁烷(513-38-2)核磁图( 13 CNMR) 碘代异丁烷(513-38-2)质谱(MS) 碘代异丁烷(513-38-2)红外图谱(IR2) 碘代异丁烷(513-38-2)红外图谱(IR1) 碘代异丁烷(513-38-2)核磁图( 1 HNMR)
• 敏感性:Light Sensitive
• F:8-10-23
• TCI Shanghai:1-碘-2-甲基丙烷(含稳定剂铜屑) 1-Iodo-2-methylpropane (stabilized with Copper chip),>;97.0%(GC)(513-38-2)
• 可燃性危险特性:遇明火、高温、氧化剂易燃; 遇热产生有毒碘化物气体
• 方法一:由异丁醇与三碘化磷反应而得。先将赤磷和异丁醇混合，在水浴上加热，慢慢加入碘，加完后继续反应4h，蒸馏粗品，再进行分馏，收集119-122℃馏分即为成品。
• 储运特性:库房通风低温干燥避光; 与氧化剂分开存放
• 碘代异丁烷价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2011/08/23 80025980 碘代异丁烷 25ml 141.9元 2011/04/16 I0322 1-碘-2-甲基丙烷(含稳定剂铜屑) 1-Iodo-2-methylpropane (stabilized with Copper chip) 250ML 2000元 2011/04/16 I0322 1-碘-2-甲基丙烷(含稳定剂铜屑) 1-Iodo-2-methylpropane (stabilized with Copper chip) 25ML 356元
• MOL 文件:513-38-2.mol