9-Fluorenemethanol, 99% 9-芴甲醇

CAS 24324-17-2 MFCD00001139

化学结构图

24324-17-2
SMILES: OCC1c2ccccc2-c2ccccc21

化学属性

Mol. FormulaC14H12O
Mol. Weight196.25
Melting Point105-107°C
TSCAYes
Density1.422
Boiling Point363.9°C at 760 mmHg

别名和识别编码

Chemical Name9-Fluorenemethanol, 99%
CAS Number24324-17-2
Alfabeta NameFLUORENEMETHANOL 9-
MDL NumberMFCD00001139
Synonym 9-Fluorenylmethanol {LY} 9-Fluorenylmethanol {} {LY} 9-Fluorenylmethanol {} {} {LY} 9-Fluorenylmethanol {} {} {} {LY} 9-Fluorenylmethanol {} {} {} {} {LY} 9-Fluorenylmethanol {} {} {} {} {} {LY} 9-Fluorenylmethanol {} {} {} {} {} {} {LY} 9-Fluorenylmethanol {} {} {} {} {} {} {} {LY} 9-Fluorenylmethanol {} {} {} {} {} {} {} {} {LY} 9-Fluorenylmethanol {} {} {} {} {} {} {} {} {} {LY} 9-Fluorenylmethanol {} {} {} {} {} {} {} {} {} {} {LY} 9-Fluorenylmethanol {} {} {} {} {} {} {} {} {} {} {} {LY} 9-Fluorenylmethanol {} {} {} {} {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {} {} {} {} {LY} 9-Fluorenylmethanol {} {} {} {} {} {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 9-Fluorenylmethanol {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 9-Fluorenylmethanol {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 9-Fluorenylmethanol {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 9-Fluorenylmethanol {} {} {} {} {} {} {} {} {} {} {} {} {} {}
PubChem Substance ID87569980
Beilstein Registry Number6(3)3507
EC Number246-167-5
Reaxys-RN2330017
Chemical Name Translation9-芴甲醇
InChIKeyXXSCONYSQQLHTH-UHFFFAOYSA-N
LabNetwork Molecule IDLN00173075
Canonical SMILESC1=CC=CC3=C1C2=CC=CC=C2C3CO
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分类

  • {SNA} Alcohols, Building Blocks, C11 to C30+, Chemical Synthesis, Organic Building Blocks, Oxygen Compounds
  • {SA} Alcohols, Building Blocks, C11 to C30+, Chemical Synthesis, Organic Building Blocks, Oxygen Compounds

产品应用

  • 在合成脱氧核糖核苷酸时磷酸酯的保护基团;羧基保护基团。

相关文献及参考

  • Reagent for protection of carboxyl groups as their 9-fluorenylmethyl (Fm) esters, which improve solubility of the molecule in organic solvents. Fm esters can be formed, e.g. by the DCC-DMAP method: Tetrahedron Lett., 24, 281 (1983), or by imidazole-catalyzed transesterification of active esters of N-protected amino acids: Int. J. Pept. Prot. Res., 21, 196 (1983). Cleavage is by hydrogenolysis. See Appendix 6.
  • Can also be used to protect phosphate groups in oligonucleotide synthesis: J. Chem. Soc., Chem. Commun., 803 (1973).
  • Beilstein:6(3)3507

安全信息

Warnings IRRITANT
WGK Germany3
Personal Protective Equipment Eyeshields, Gloves, type N95 (US), type P1 (EN143) respirator filter
Signal word Warning
GHS Symbol
Safety Statements
  • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后,立即用大量水冲洗并征求医生意见;
  • S36/37/39 Wear suitable protective clothing, gloves and eye/face protection 穿戴适当的防护服、手套和眼睛/面保护;
  • S24/25 Avoid contact with skin and eyes 避免皮肤和眼睛接触;
Risk Statements
  • R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
Precautionary statements
  • P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P305+P351+P338
Storage condition 2-8°C {LY} 2-8°C Store at room temperature {} {LY} 2-8°C {} {} {LY} 2-8°C {} {} {} {LY} 2-8°C {} {} {} {} {LY} 2-8°C {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°

系列性分类


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