(Bromomethyl)cyclopropane 溴甲基环丙烷

CAS 7051-34-5 MFCD00001306

化学结构图

7051-34-5
SMILES: BrCC1CC1

化学属性

Mol. FormulaC4H7Br
Mol. Weight135.00
Boiling Point105-107°C at 760 mmHg
Density1.392
Refractive indexn20/D 1.457(lit.)
Flash Point41°C
TSCANo
Appearance 无色透明、易燃液体,无异味。密度1.433g/ml,沸点102-108℃,折射率1.4385。溶解于乙醇,醚,丙酮,苯。
Danger-Level乙类
Melting Point87-90 °C

别名和识别编码

Chemical NameCyclopropylmethyl Bromide
CAS Number7051-34-5
Alfabeta NameCYCLOPROPYLMETHYLBROMIDE
MDL NumberMFCD00001306
Synonym Cyclopropylmethyl bromide {LY} Cyclopropylmethyl bromide {} {LY} Cyclopropylmethyl bromide {} {} {LY} Cyclopropylmethyl bromide {} {} {} {LY} Cyclopropylmethyl bromide {} {} {} {} {LY} Cyclopropylmethyl bromide {} {} {} {} {} {LY} Cyclopropylmethyl bromide {} {} {} {} {} {} { {} {} {} {} {} {} {LY} Cyclopropylmethyl bromide {} {} {} {} {} {} {} {LY} Cyclopropylmethyl bromide {} {} {} {} {} {} {} {} {LY} Cyclopropylmethyl bromide {} {} {} {} {} {} {} {} {} {LY} Cyclopropylmethyl bromide {} {} {} {} {} {} {} {} {} {} {LY} Cyclopropylmethyl bromide {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Cyclopropylmethyl bromide {} {} {} {} {} {} {} {} {} {} {} {} {LY} Cyclopropylmethyl bromide {} {} {} {} {} {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Cyclopropylmethyl bromide {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Cyclopropylmethyl bromide {} {} {} {} {} {} {} {} {} {} {
EC Number230-331-8
Beilstein Registry Number605296
PubChem Substance ID81503
Chemical Name Translation溴甲基环丙烷
InChIKeyAEILLAXRDHDKDY-UHFFFAOYSA-N
LabNetwork Molecule IDLN00008111
InChIInChI=1S/C4H7Br/c5-3-4-1-2-4/h4H,1-3H2
Canonical SMILESBrCC1CC1
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分类

  • {uni_hamburg} no charge; carbocycle; alicycle; 3ring; 1fragment
  • {SNA} Alkyl, Building Blocks, Chemical Synthesis, Halogenated Hydrocarbons, Organic Building Blocks
  • Miscellaneous Reagents

产品应用

  • 用于有机合成中构建环丙烷甲基基团(cyclopropylmethyl- group)

相关文献及参考

  • Short: II/25C
  • Short: EINECS
  • O-Alkylation of phenols (KO-t-Bu/DMF) has been used as a means of protection. The cyclopropylmethyl ethers are stable to reducing agents (metal hydride, H2, Birch), but selectively cleaved by aqueous methanolic HCl: Chem. Pharm. Bull., 23, 2878 (1975).
  • Beilstein: 5,IV,14
  • Short: II/14a

安全信息

Warnings IRRITANT, KEEP COLD, FLAMMABLE
Signal word Warning
GHS Symbol
WGK Germany3
Safety Statements
  • S16 Keep away from sources of ignition - No smoking 远离火源,禁止吸烟;
  • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后,立即用大量水冲洗并征求医生意见;
  • S36/37/39 Wear suitable protective clothing, gloves and eye/face protection 穿戴适当的防护服、手套和眼睛/面保护;
Risk Statements
  • R10 Flammable 易燃
  • R22 Harmful if swallowed 吞咽有害
  • R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
Precautionary statements
  • P210 Keep away from heat/sparks/open flames/hot surfaces. — No smoking. 远离热源/火花/明火/热的表面。——禁止吸烟。
  • P233 Keep container tightly closed. ?保持容器密闭。
  • P240 Ground/bond container and receiving equipment. 与地面接触/连接集装箱和接受设备。
  • P241 Use explosion-proof electrical/ventilating/lighting/…/equipment. 使用防爆电气/通风/照明/ .../设备。
  • P242 Use only non-sparking tools. 只能使用无火花工具。
  • P243 Take precautionary measures against static discharge. 采取预防措施,防止静电放电。
  • P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
  • P264+P265
  • P270 Do not eat, drink or smoke when using this product. 使用本产品时不要吃东西,喝水或吸烟。
  • P271 Use only outdoors or in a well-ventilated area.? 只能在室外或通风良好的地方使用。
  • P273 Avoid release to the environment. 避免释放到环境中。
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P301+P312
  • P301+P317
  • P302+P352
  • P303+P361+P353
  • P304+P340
  • P305+P351+P338
  • P312 Call a POISON CENTER or doctor/physician if you feel unwell. 如果你感觉不适,呼叫解毒中心或医生/医师。
  • P319
  • P321 Specific treatment (see … on this label). 具体治疗(见本标签上的)。
  • P330 Rinse mouth. 漱口
  • P332+P313
  • P332+P317
  • P337+P313
  • P337+P317
  • P362 Take off contaminated clothing and wash before reuse. 脱掉污染的衣服,清洗后方可重新使用
  • P362+P364
  • P370+P378
  • P403+P233
  • P403+P235
  • P405 Store locked up. 上锁保管。
  • P501 Dispose of contents/container to..… 处理内容物/容器.....
Packing GroupIII
UN Number 1993
Hazard statements
  • H225 Highly flammable liquid and vapour 高度易燃液体和蒸气
  • H226 Flammable liquid and vapour 易燃液体和蒸气
  • H302 Harmful if swallowed 吞食有害
  • H315 Causes skin irritation 会刺激皮肤
  • H319 Causes serious eye irritation 严重刺激眼睛
  • H335 May cause respiratory irritation 可能导致呼吸道刺激
  • H412 Harmfutoaquaticlifewithlonglastingeffects 对水生生物有害并具有长期影响。
Personal Protective Equipment Eyeshields, Faceshields, full-face respirator (US), Gloves, multi-purpose combination respirator cartridge (US), type ABEK (EN14387) respirator filter
Hazard Codes 3 Xn
Hazard Class3
Storage condition 2-8°C {LY} 2-8°C Store at room temperature {} {LY} 2-8°C {} {} {LY} 2-8°C {} {} {} {LY} 2-8°C {} {} {} {} {LY} 2-8°C {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°

其他信息

  • 无异味。溶解于乙醇,醚,丙酮和苯。
  • Alfa Aesar:溴甲基环丙烷,97% (Bromomethyl)cyclopropane, 97%(7051-34-5)
  • 检测方法:GC
  • 图谱信息:溴甲基环丙烷(7051-34-5)核磁图( 1 HNMR) 溴甲基环丙烷(7051-34-5)质谱(MS) 溴甲基环丙烷(7051-34-5)核磁图( 13 CNMR)
  • MOL 文件:7051-34-5.mol
  • 用途一:用作医药中间体
  • Acros Organics:环丙基溴甲烷/溴甲基环丙烷 (Bromomethyl)cyclopropane, 96%(7051-34-5)
  • Hazard Note:Irritant
  • Sigma Aldrich:7051-34-5(sigmaaldrich)
  • 海关编码:29035990
  • MSDS 信息:1-(Bromomethyl)cyclopropane(7051-34-5).msds
  • 上游原料:乙醚 --> 四氢呋喃 --> 氢化铝锂 --> 三溴化磷 --> 环丙甲酸
  • 用途二:用于有机合成中构建环丙烷甲基基团(cyclopropylmethyl- group)
  • 溴甲基环丙烷价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2011/08/23 xw010407 环丙基溴甲烷 10ml 289元 2010/06/21 RJF00467DA 溴甲基环丙烷 1-(bromomethyl)cyclopropane 1 GR 315元 2010/06/21 RJF00467EB 溴甲基环丙烷 1-(bromomethyl)cyclopropane 25 GR 4200元
  • 下游产品:环丙乙酸 --> 西托溴铵

系列性分类


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