4-Methylcyclohexanone 4-甲基环己酮

CAS 589-92-4 MFCD00001643

化学结构图

589-92-4
SMILES: CC1CCC(=O)CC1

化学属性

Mol. FormulaC7H12O
Mol. Weight112.17
Refractive index1.4420 to 1.4480
Boiling Point170°C at 760 mmHg
Density0.914
Flash Point48°C
TSCAYes
Melting Point-41°C
Appearance 无色液体,有丙酮味。熔点-40.6℃,沸点170℃,相对密度 20/4℃ 0.914,折光率1.4451,75℃时遇硝酸可爆炸。闪点48℃。溶于醇、醚,不溶于水。

别名和识别编码

Chemical Name4-methylcyclohexan-1-one
Synonym 4-Methylcyclohexanone {LY} 4-Methylcyclohexanone {} {LY} 4-Methylcyclohexanone {} {} {LY} 4-Methylcyclohexanone {} {} {} {LY} 4-Methylcyclohexanone {} {} {} {} {LY} 4-Methylcyclohexanone {} {} {} {} {} {LY} 4-Methylcyclohexanone {} {} {} {} {} {} {} {} {} {} {} {} {LY} 4-Methylcyclohexanone {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 4-Methylcyclohexanone {} {} {} {} {} {} {} {} {LY} 4-Methylcyclohexanone {} {} {} {} {} {} {} {} {} {LY} 4-Methylcyclohexanone {} {} {} {} {} {} {} {} {} {} {LY} 4-Methylcyclohexanone {} {} {} {} {} {} {} {} {} {} {} {LY} 4-Methylcyclohexanone {} {} {} {} {} {} {} {} {} {} {} {} {LY} 4-Methylcyclohexanone {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 4-Methylcyclohexanone {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 4-Methylcyclohexanone {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 4-Methylcyclohexanone {} {} {} {} {} {} {} {} {} {} {}
CAS Number589-92-4
PubChem Substance ID11525
EC Number209-665-3
Beilstein Registry Number506746
MDL NumberMFCD00001643
Reaxys-RN506746
Chemical Name Translation4-甲基环己酮
LabNetwork Molecule IDLN00335098
InChIInChI=1S/C7H12O/c1-6-2-4-7(8)5-3-6/h6H,2-5H2,1H3
Canonical SMILESO=C1CCC(C)CC1
信息真实价格透明    资金保障    专业采购外包团队在线服务   
信息真实价格透明    资金保障    专业采购外包团队在线服务   
品牌质保精细包装    现货库存    一流品牌服务   

分类

  • {SNA} Alphabetical Listings, Flavors and Fragrances, M-N
  • Building Blocks, C7 to C8, Carbonyl Compounds, Chemical Synthesis, Ketones, Organic Building Blocks
  • {uni_hamburg} no charge; carbocycle; alicycle; 6RingOnly; 6ring; ketone; 1fragment
  • {SNA} Building Blocks, C7 to C8, Carbonyl Compounds, Chemical Synthesis, Ketones, Organic Building Blocks

产品应用

  • 甲环亚硝脲的中间体,亦可用作溶剂。

相关文献及参考

  • Short: II/27B
  • Beilstein:7,18
  • Short: II/19b

安全信息

GHS Symbol
WGK Germany3
Hazard statements
  • H226 Flammable liquid and vapour 易燃液体和蒸气
  • H302 Harmful if swallowed 吞食有害
  • H314 Causes severe skin burns and eye damage 导致严重的皮肤灼伤和眼睛损伤
  • H318 Causes serious eye damage 严重伤害眼睛
Personal Protective Equipment Eyeshields, Faceshields, full-face respirator (US), Gloves, multi-purpose combination respirator cartridge (US), type ABEK (EN14387) respirator filter
Hazard Codes 3
RTECSGW1750200
Signal word Warning
Safety Statements
  • S16 Keep away from sources of ignition - No smoking 远离火源,禁止吸烟;
  • S23 Do not breathe gas/fumes/vapour/spray (appropriate wording to be specified by the manufacturer) 不要吸入气体/烟雾/蒸汽/喷雾;
  • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后,立即用大量水冲洗并征求医生意见;
  • S36 Wear suitable protective clothing 穿戴适当的防护服;
  • S36/37 Wear suitable protective clothing and gloves 穿戴适当的防护服和手套;
  • S36/37/39 Wear suitable protective clothing, gloves and eye/face protection 穿戴适当的防护服、手套和眼睛/面保护;
Risk Statements
  • R10 Flammable 易燃
  • R20/21/22 Harmful by inhalation, in contact with skin and if swallowed 吸入、皮肤接触和不慎吞咽有害
  • R22 Harmful if swallowed 吞咽有害
  • R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
Precautionary statements
  • P210 Keep away from heat/sparks/open flames/hot surfaces. — No smoking. 远离热源/火花/明火/热的表面。——禁止吸烟。
  • P211 Do not spray on an open flame or other ignition source.? 不要喷洒在明火或其他点火源。
  • P233 Keep container tightly closed. ?保持容器密闭。
  • P240 Ground/bond container and receiving equipment. 与地面接触/连接集装箱和接受设备。
  • P241 Use explosion-proof electrical/ventilating/lighting/…/equipment. 使用防爆电气/通风/照明/ .../设备。
  • P242 Use only non-sparking tools. 只能使用无火花工具。
  • P243 Take precautionary measures against static discharge. 采取预防措施,防止静电放电。
  • P260 Do not breathe dust/fume/gas/mist/vapours/spray. 不要吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
  • P264+P265
  • P270 Do not eat, drink or smoke when using this product. 使用本产品时不要吃东西,喝水或吸烟。
  • P271 Use only outdoors or in a well-ventilated area.? 只能在室外或通风良好的地方使用。
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P281 Use personal protective equipment as required. 使用所需的个人防护装备。
  • P301+P310
  • P301+P316
  • P301+P317
  • P301+P330+P331
  • P302+P352
  • P302+P361+P354
  • P303+P361+P353
  • P304+P340
  • P305+P351+P338
  • P305+P351+P338+P337+P313
  • P305+P354+P338
  • P312 Call a POISON CENTER or doctor/physician if you feel unwell. 如果你感觉不适,呼叫解毒中心或医生/医师。
  • P316
  • P317
  • P319
  • P321 Specific treatment (see … on this label). 具体治疗(见本标签上的)。
  • P330 Rinse mouth. 漱口
  • P331 Do NOT induce vomiting.. 不要催吐。
  • P332+P313
  • P332+P317
  • P337+P313
  • P337+P317
  • P362 Take off contaminated clothing and wash before reuse. 脱掉污染的衣服,清洗后方可重新使用
  • P362+P364
  • P363 Wash contaminated clothing before reuse. 被污染的衣服洗净后方可重新使用。
  • P370+P378
  • P403+P233
  • P403+P235
  • P405 Store locked up. 上锁保管。
  • P501 Dispose of contents/container to..… 处理内容物/容器.....
UN Number 2297 UN 2297 3/PG 3
Packing GroupIII
Hazard Class3
Storage condition 2-8°C {LY} 2-8°C Flammables area {} {LY} 2-8°C {} {} {LY} 2-8°C {} {} {} {LY} 2-8°C {} {} {} {} {LY} 2-8°C {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°
TYPE OF TEST            : LDLo - Lowest published lethal dose
ROUTE OF EXPOSURE       : Intravenous
SPECIES OBSERVED        : Mammal - dog
DOSE/DURATION           : 370 mg/kg
TOXIC EFFECTS :
   Cardiac - change in rate
   Vascular - BP lowering not characterized in autonomic section
REFERENCE :
   COREAF Comptes Rendus Hebdomadaires des Seances, Academie des Sciences.
   (Paris, France)  V.1-261, 1835-1965.  For publisher information, see CRASEV.
    Volume(issue)/page/year: 236,633,1953

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Rodent - mouse
DOSE/DURATION           : 1600 mg/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   38MKAJ "Patty's Industrial Hygiene and Toxicology," 3rd rev. ed., Clayton,
   G.D., and F.E. Clayton, eds., New York, John Wiley & Sons, Inc., 1978-82.
   Vol. 3 originally pub. in 1979; pub. as 2nd rev. ed. in 1985.
   Volume(issue)/page/year: 2C,4783,1982

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Rodent - rat
DOSE/DURATION           : 800 mg/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   38MKAJ "Patty's Industrial Hygiene and Toxicology," 3rd rev. ed., Clayton,
   G.D., and F.E. Clayton, eds., New York, John Wiley & Sons, Inc., 1978-82.
   Vol. 3 originally pub. in 1979; pub. as 2nd rev. ed. in 1985.
   Volume(issue)/page/year: 2C,4783,1982

其他信息

  • 4-甲基环己酮价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2011/08/23 K6640002 4-甲基环己酮 100ml 1158元 2011/04/16 M0199 4-甲基环己酮 4-Methylcyclohexanone 500ML 2290元 2011/04/16 M0199 4-甲基环己酮 4-Methylcyclohexanone 25ML 275元
  • Sigma Aldrich:589-92-4(sigmaaldrich)
  • MSDS 信息:4-Methylcyclohexanone(589-92-4).msds
  • 有丙酮味,溶于醇、醚,不溶于水。
  • 海关编码:29142200
  • 方法一:由甲基环己醇氧化制得。
  • 用途二:甲环亚硝脲的中间体,亦可用作溶剂。
  • MOL 文件:589-92-4.mol
  • 用途一:甲环亚硝脲的中间体。亦可用作溶剂。
  • Hazard Note:Irritant
  • Acros Organics:4-甲基环己酮 4-Methylcyclohexanone, 98%(589-92-4)
  • TCI Shanghai:4-甲基环己酮 4-Methylcyclohexanone,>;98.0%(GC)(589-92-4)
  • 下游产品:2-氨基-6-甲基-4,5,6,7-四氢-1-苯并噻吩-3-腈 --> 2-氨基-6-甲基-4,5,6,7-四氢-苯并噻吩-3-甲酸乙酯 --> 2-氨基-6-甲基-4,5,6,7-四氢-1-苯并噻吩-3-甲酰胺
  • 图谱信息:4-甲基环己酮(589-92-4)质谱(MS) 4-甲基环己酮(589-92-4)核磁图( 1 HNMR) 4-甲基环己酮(589-92-4)核磁图( 13 CNMR) 4-甲基环己酮(589-92-4)Raman光谱 4-甲基环己酮(589-92-4)红外图谱(IR1)
  • Alfa Aesar:4-甲基环己酮,98+% 4-Methylcyclohexanone, 98+%(589-92-4)
  • FEMA:3948

系列性分类