Zirconium tetrachloride 氯化锆

CAS 10026-11-6 MFCD00011306

化学结构图

10026-11-6
SMILES: Cl[Zr](Cl)(Cl)Cl

化学属性

Mol. FormulaZrCl4
Mol. Weight233.04
Density2.8 g/mL at 25 °C(lit.)
TSCAYes
Melting Point437°C
Solubility溶于冷水、乙醇、乙醚，不溶于苯、四氯化碳、二硫化碳。
Vapor Pressure1 mmHg ( 190 °C)
Stability对湿度敏感
Boiling Point331°C

别名和识别编码

Chemical NameZirconium tetrachloride
Synonym 四氯化锆 Zirconium chloride (ZrCl4), (T-4)- Zirkoniumtetrachlorid Zirconium(IV) chloride Zirconium chloride zirconium (IV) chloride Zirconium tetrachloride Zirconium chloride (Zr2Cl8) Tetrachlorozirconium 四氯化锆 Zirkon(IV)-chlorid, wasserfrei 氯化锆(IV) Zirkon(IV)-chlorid wasserfrei Zirkontetrachlorid ZrCl4 Tetrachlorozirconium Zirconium(IV) chloride, anhydrous 氯化锆
CAS Number10026-11-6
PubChem Substance ID24852962
EC Number233-058-2
MDL NumberMFCD00011306
Merck Number14,10174
Beilstein Registry Number2384789
Chemical Name Translation氯化锆
LabNetwork Molecule IDLN00198098
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分类

  • {SNA} Catalysis and Inorganic Chemistry, Chemical Synthesis, Crystal Grade Inorganics, Materials Science, Metal and Ceramic Science, Salts, Zirconium, Zirconium Salts
  • {SNA} Catalysis and Inorganic Chemistry, Chemical Synthesis, Crystal Grade Inorganics, Essential Chemicals, Metal and Ceramic Science, Research Essentials, Salts, Zirconium, Zirconium Salts, 材料科学
  • {SNA} Catalysis and Inorganic Chemistry, Chemical Synthesis, Materials Science, Metal and Ceramic Science, Salts, Zirconium, Zirconium Salts
  • {uni_hamburg} no charge; 1fragment
  • {SNA} Catalysis an

产品应用

  • 用于制金属锆、颜料、纺织品防水剂、皮革鞣剂和分析试剂等。

相关文献及参考

  • For a brief feature on uses of this reagent in synthesis, see: Synlett, 1073 (2003).
  • Catalyzes the trans-hydrostannylation of acetylenes with Tri-n-butyl­tin hydride, A13298: J. Chem. Soc., Chem. Commun., 2405 (1995); J. Org. Chem., 61, 4568 (1996). Allylstannanes also add trans-selectively to acetylenes under similar conditions: J. Chem. Soc., Chem. Commun., 1513 (1996).
  • Highly efficient and reusable catalyst for acetylation of phenols, thiols, amines and alcohols under solvent-free conditions, claimed to be superior to metal triflates: Synlett, 627 (2004).
  • Short: II/25A
  • Lewis acid. Promotes the rearrangement of hydroxy sulfones to ketones: J. Chem. Soc., Chem. Commun., 2289 (1994).
  • Superior catalyst for the Fries rearrangement of aryl acetates, giving the least hindered ortho-acetyl phenol in high yields at ambient temperatures: Tetrahedron Lett., 37, 7659 (1996).
  • Merck:14,10174
  • In the presence of ZrCl4, chloromethyl ethers are formed under mild conditions from acid chlorides and trioxane or paraformaldehyde: Tetrahedron Lett., 43, 6317 (2002).

安全信息

GHS Symbol
WGK Germany3
Hazard Codes C
Hazard statements
  • H314 Causes severe skin burns and eye damage 导致严重的皮肤灼伤和眼睛损伤
  • H302 Harmful if swallowed 吞食有害
  • H290 May be corrosive to metals 可能腐蚀金属。
Personal Protective Equipment Eyeshields, Faceshields, full-face particle respirator type N100 (US), Gloves, respirator cartridge type N100 (US), type P1 (EN143) respirator filter, type P3 (EN 143) respirator cartridges
RTECSZH7175000
Precautionary statements
  • P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P305+P351+P338
  • P310 Immediately call a POISON CENTER or doctor/physician. 立即呼救解毒中心或医生/医师。
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
Signal word Danger Warning
Safety Statements
  • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后，立即用大量水冲洗并征求医生意见；
  • S30 Never add water to this product 切勿将水加入该产品中；
  • S20 When using do not eat or drink 使用时，不得进食，饮水；
  • S45 In case of accident or if you feel unwell seek medical advice immediately (show the label where possible) 发生事故时或感觉不适时，立即求医（可能时出示标签）；
  • S60 This material and its container must be disposed of as hazardous waste 该物质及其容器必须作为危险废物处置；
  • S36/37/39 Wear suitable protective clothing, gloves and eye/face protection 穿戴适当的防护服、手套和眼睛/面保护；
  • S8 Keep container dry 保持容器干燥；
UN Number UN2503 2503
Risk Statements
  • R37 Irritating to respiratory system 刺激呼吸道
  • R14 Reacts violently with water 遇水会猛烈反应
  • R22 Harmful if swallowed 吞咽有害
  • R34 Causes burns 会导致灼伤
  • R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
  • R35 Causes severe burns 会导致严重灼伤
Storage condition Moisture Sensitive 易吸潮，密封保存。 充氩气保存 充氩保存 Moisture Sensitive & Hygroscopic
Packing GroupIII
Warnings 危化品目录(2015)
Restrict 危险品

其他信息

  • 易潮解，溶于冷水、乙醇、乙醚，不溶于苯、四氯化碳、二硫化碳。和水反应，生成盐酸和氧化锆。

系列性分类

  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  1. Materials Science 材料科学
  2. Metal and Ceramic Science Products 金属和陶瓷科学
  3. Crystal Grade Inorganics 晶体级无机物
  4. Zirconium 锆
  1. Materials Science 材料科学
  2. Metal and Ceramic Science Products 金属和陶瓷科学
  3. Salts 金属盐
  4. Zirconium Salts 锆盐
  1. Chemical Synthesis 化学合成
  2. Catalysis and Inorganic Chemistry 催化剂和无机化学
  3. Zirconium 锆x
  1. Chemical Synthesis 化学合成
  2. Catalysis and Inorganic Chemistry 催化剂和无机化学
  3. Zirconium 锆x
  1. Chemical Synthesis 化学合成
  2. Catalysis and Inorganic Chemistry 催化剂和无机化学
  3. 医药合成催化剂