2,3-Diaminomaleonitrile 二氨基马来腈

CAS 1187-42-4 MFCD00001870

化学结构图

1187-42-4
SMILES: N#C/C(N)=C(/N)C#N

化学属性

Mol. FormulaC4H4N4
Mol. Weight108.10
Melting Point178-179°C
Density1.360
TSCAYes
Solubility5 G/L (25 ºC)
Boiling Point192.71 °C at 760 mmHg

别名和识别编码

Chemical Name2,3-Diaminomaleonitrile
Synonym Diaminomaleonitrile {LY} Diaminomaleonitrile {} {LY} Diaminomaleonitrile {} {} {LY} Diaminomaleonitrile {} {} {} {LY} Diaminomaleonitrile {} {} {} {} {LY} Diaminomaleonitrile {} {} {} {} {} {LY} Diaminomaleonitrile {} {} {} {} {} {} {} {} {} {} {} {} {LY} Diaminomaleonitrile {} {} {} {} {} {} {} {LY} Diaminomaleonitrile {} {} {} {} {} {} {} {} {LY} Diaminomaleonitrile {} {} {} {} {} {} {} {} {} {LY} Diaminomaleonitrile {} {} {} {} {} {} {} {} {} {} {LY} Diaminomaleonitrile {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Diaminomaleonitrile {} {} {} {} {} {} {} {} {} {} {} {} {LY} Diaminomaleonitrile {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Diaminomaleonitrile {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Diaminomaleonitrile {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Diaminomaleonitrile {} {} {} {} {}
Beilstein Registry Number878333
PubChem Substance ID2723951
CAS Number1187-42-4
EC Number214-697-6
MDL NumberMFCD00001870
Reaxys-RN878333
Alfabeta NameDIAMINOBUTENEDINITRILE 232---,
Chemical Name Translation二氨基马来腈
InChIKeyDPZSNGJNFHWQDC-ARJAWSKDSA-N
LabNetwork Molecule IDLN00185457
InChIInChI=1S/C4H4N4/c5-1-3(7)4(8)2-6/h7-8H2/b4-3-
Canonical SMILESN/C(C#N)=C(N)/C#N.[(Z)]
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分类

  • Building Blocks, C1 to C5, Chemical Synthesis, Cyanides/Nitriles, Nitrogen Compounds, Organic Building Blocks
  • {uni_hamburg} no charge; 1fragment
  • {SNA} Building Blocks, C1 to C5, Chemical Synthesis, Cyanides/Nitriles, Nitrogen Compounds, Organic Building Blocks

相关文献及参考

  • The tetramer of HCN. Useful precursor of various heterocycles, e.g. imidazoles: Synthesis, 767 (1988); J. Org. Chem., 39, 2341 (1974), pyrazines: J. Org. Chem., 39, 2341 (1974); 44, 827, 4871 (1979); J. Heterocycl. Chem., 11, 79 (1974); Heterocycles, 16, 1449 (1981), pteridines: J. Heterocycl. Chem., 23, 1299 (1986). For extension to synthesis of nucleosides, see: J. Org. Chem., 50, 747 (1985). For a review, with particular reference to its utility in heterocyclic synthesis, see: Tetrahedron, 59, 2749 (2003).
  • Short: EINECS
  • Short: III/5a

安全信息

Precautionary statements
  • P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
  • P270 Do not eat, drink or smoke when using this product. 使用本产品时不要吃东西,喝水或吸烟。
  • P271 Use only outdoors or in a well-ventilated area.? 只能在室外或通风良好的地方使用。
  • P273 Avoid release to the environment. 避免释放到环境中。
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P301+P310
  • P301+P310+P330
  • P301+P312
  • P302+P352
  • P302+P352+P312+P361+P364
  • P304+P312
  • P304+P340
  • P305+P351+P338
  • P311 Call a POISON CENTER or doctor/physician. 呼叫解毒中心或医生/医师。
  • P312 Call a POISON CENTER or doctor/physician if you feel unwell. 如果你感觉不适,呼叫解毒中心或医生/医师。
  • P321 Specific treatment (see … on this label). 具体治疗(见本标签上的)。
  • P322 Specific measures (see …on this label). 具体治疗(见本标签上的)。
  • P330 Rinse mouth. 漱口
  • P332+P313
  • P363 Wash contaminated clothing before reuse. 被污染的衣服洗净后方可重新使用。
  • P403+P233
  • P405 Store locked up. 上锁保管。
  • P501 Dispose of contents/container to..… 处理内容物/容器.....
WGK Germany3
GHS Symbol
Signal word Warning
Hazard statements
  • H301 Toxic if swallowed 吞食有毒
  • H301+H311+H331
  • H302 Harmful if swallowed 吞食有害
  • H302+H312+H332
  • H312 Harmful in contact with skin 皮肤接触有害
  • H331 Toxic if inhaled 吸入中毒
  • H332 Harmful if inhaled 吸入有害
  • H412 Harmfutoaquaticlifewithlonglastingeffects 对水生生物有害并具有长期影响。
Hazard Codes 6.1 T Xn
Personal Protective Equipment dust mask type N95 (US), Eyeshields, Gloves
Safety Statements
  • S36 Wear suitable protective clothing 穿戴适当的防护服;
Risk Statements
  • R20/21/22 Harmful by inhalation, in contact with skin and if swallowed 吸入、皮肤接触和不慎吞咽有害
UN Number 2811 3439
Storage condition RT, protect from light {LY} RT, protect from light {} {LY} RT, protect from light {} {} {LY} RT, protect from light {} {} {} {LY} RT, protect from light {} {} {} {} {LY} RT, protect from light {} {} {} {} {} {LY} RT, protect from light {} {} {} {} {} {} {LY} RT, protect from light {} {} {} {} {} {} {} {LY} RT, protect from light {} {} {} {} {} {} {} {} {LY} RT, protect from light {} {} {} {} {} {} {} {} {} {LY} RT, protect from light {} {} {} {} {} {} {} {} {} {} {LY} RT, protect from light {} {} {} {} {} {} {} {} {} {} {} {LY} RT, protect from light {} {} {} {} {} {} {} {} {} {} {} {} {LY} RT, protect from light {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} RT, protect from light {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} RT, protect from light {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} RT, protect from light {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} RT, protect from light {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} RT, protect
Packing GroupIII
Warnings IRRITANT
Hazard Class6.1

其他信息

  • 图谱信息:2,3-二氨基-2-丁烯二腈(1187-42-4)质谱(MS) 2,3-二氨基-2-丁烯二腈(1187-42-4)红外图谱(IR1) 2,3-二氨基-2-丁烯二腈(1187-42-4)红外图谱(IR2)
  • Alfa Aesar:二氨基马来腈,98% Diaminomaleonitrile, 98%(1187-42-4)
  • Sigma Aldrich:1187-42-4(sigmaaldrich)
  • MOL 文件:1187-42-4.mol
  • 海关编码:29269095
  • 下游产品:1-甲基咪唑-5-甲酰氯盐酸盐 --> 1-甲基-4-咪唑甲酸 --> 4-(羟甲基)咪唑 --> 咪唑-4,5-二羧酸 --> 1-甲基-1H-咪唑-5-甲酸 --> 1-甲基-1氢-咪唑-5-异氰酸酯 --> 1-甲基-1H-咪唑-4,5-二羧酸 --> 1H-咪唑-4-甲酸 --> 1-甲基-1H-咪唑-4,5-二甲腈 --> 4,5-二氰基咪唑
  • 用途一:用作合成各种杂环化合物的起始原料,还可合成医药、农药、染料、颜料等中间体,还是聚酯用分散染料的原料
  • 2,3-二氨基-2-丁烯二腈价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2014/06/02 D1335 二氨基顺丁烯二腈 Diaminomaleonitrile 25G 345元 2014/06/02 D1335 二氨基顺丁烯二腈 Diaminomaleonitrile 500G 2590元 2010/06/21 172700250 2,3-二氨基-2-丁烯二腈 Diaminomaleonitrile 98% 25 GR 282元
  • Acros Organics:二氨基顺丁烯二腈 Diaminomaleonitrile, 98%(1187-42-4)
  • 敏感性:Light Sensitive
  • MSDS 信息:Diaminomaleonitrile(1187-42-4).msds
  • TCI Shanghai:2,3-二氨基顺丁烯二腈 Diaminomaleonitrile,>;98.0%(T)(1187-42-4)

系列性分类


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