Silver(I) oxide 氧化银

CAS 20667-12-3 MFCD00003404

化学结构图

20667-12-3
SMILES: [Ag]O[Ag]

化学属性

Mol. Formula2
Mol. Weight232
Density7.483
Solubility溶于酸、氨水、醇,微溶于水。
TSCAYes
Melting Point230° dec.
Appearance 棕褐色立方结晶或棕黑色重质粉末。 溶于酸、氨水、醇,微溶于水。
Stability对光敏感
RedoxOxidation

别名和识别编码

Chemical NameSilver(I) oxide
MDL NumberMFCD00003404
PubChem Substance ID24853593
CAS Number20667-12-3
EC Number243-957-1
Merck Number14,8521
Synonym SILVER(I) OXIDE, REAGENTPLUS, 99% disilveroxide Disilberoxid Disilver oxide SILVER(I) OXIDE, 99.99+% SILVER OXIDE Ag2O SILVER(I) OXIDE, NANOPOWDER, 99.9% 氧化银(I) 氧化银(I), 99+% (METALS BASIS) 氧化银 SILVER OXIDE EXTRA PURE SILVER(I) OXIDE: 99.9% (93% AG) 氧化二银 Silver oxide (Ag2O) SILVEROXIDE,POWDER,REAGENT Silber(I)-oxid ARGENTOUS OXIDE silver(1+)oxide SILVER(I) OXIDE (Ag2O) Silver(I)oxide,99+%(99.99%-Ag) Argentous oxide Silver(I) oxide Silver oxide, Ag2O silveroxide(ag2o) silver(i) oxide, electrical grade silver (I) oxide Silver oxide Disilver monoxide SILVER (I) OXIDE HIGH DENSITY triethoxy(chloromethyl)silane Silberoxid SILVER(I) OXIDE 氧化银(I), ELECTRICAL GRADE 氧化银(I), 99.99% (METALS BASIS) Silver(I) oxide, 99+% Silver Oxide
Beilstein Registry Number2384789
Chemical Name Translation氧化银
Wiswesser Line NotationAG2 O
LabNetwork Molecule IDLN00222430
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分类

  • {SNA} Catalysis and Inorganic Chemistry, Chemical Synthesis, Metal and Ceramic Science, Oxides, Silver, Silver Complexes, 材料科学
  • {SA} Materials Science, Metal and Ceramic Science, Oxides, Silver
  • {SNA} Catalysis and Inorganic Chemistry, Chemical Synthesis, Materials Science, Metal and Ceramic Science, Oxides, Silver, Silver Complexes
  • {SNA} Catalysis and Inorganic Chemistry, Chemical Synthesis, Metal and Ceramic Science, Oxides, Silver, Silver Catalysts, Silver Complexes, 材料科学

产品应用

  • 氧化银是氧化银电池的电极材料。它也是有机合成中的弱氧化剂和弱碱,可与1,3-二取代的咪唑盐及苯并咪唑盐反应生成氮杂环卡宾,可替代不稳定的配体环辛二烯或乙腈作卡宾转移试剂,合成过渡金属卡宾配合物。此外,氧化银可在低温和水汽存在下将有机溴化物和氯化物转化为醇类,把苯甲基卤化物转化成苯甲基醚,与碘甲烷连用为甲基化试剂,用于糖类甲基化分析和霍夫曼消去反应中,以及将醛氧化为羧酸。也作为表面催化剂,用于烯的环氧化反应中。

相关文献及参考

  • For use in the preparation of mevalonolactone 13C, see: Org. Synth. Coll., 7, 386 (1990).
  • Merck:14,8521
  • For use as a mild base in the Suzuki coupling of boronic acids with sensitive halides, see: Org. Synth., 75, 69 (1997); for reaction scheme, see 4-Methoxybenzeneboronic acid, A14462.
  • Short: III/27g
  • Promotes the oxidative coupling of silyl enol ethers to give 1,4-diketones: J. Am. Chem. Soc., 97, 649 (1975).
  • Reagent for conversion of quaternary methiodides to their hydroxides, prior to Hofmann elimination. For the conversion of the methiodide of N,N-dimethylcyclooctylamine to cis- and trans-cyclooctene, see: Org. Synth. Coll., 5, 315 (1973). Review: Org. React., 11, 317 (1960).

安全信息

WGK Germany3
GHS Symbol
Precautionary statements
Signal word
Hazard statements
  • H410 Verytoxictoaquaticlifewithlonglastingeffects 对水生生物毒性非常大并具有长期影响。
  • H318 Causes serious eye damage 严重伤害眼睛
  • H271 May cause fire or explosion; strong oxidizer 可能会引起火宅或爆炸;强氧化剂。
  • H315 Causes skin irritation 会刺激皮肤
  • H335 May cause respiratory irritation 可能导致呼吸道刺激
  • H272 May intensify fire; oxidizer 可能加剧火势;氧化剂。
  • H319 Causes serious eye irritation 严重刺激眼睛
Hazard Codes O,Xi,C O,Xi O,Xi,N
RTECSVW4900000
Personal Protective Equipment dust mask type N95 (US), Eyeshields, Gloves
Safety Statements
  • S60 This material and its container must be disposed of as hazardous waste 该物质及其容器必须作为危险废物处置;
  • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后,立即用大量水冲洗并征求医生意见;
  • S57 Use appropriate containment to avoid environmental contamination 使用适当容器避免环境污染;
  • S39 Wear eye/face protection 戴眼睛/面孔保护装置;
  • S17 Keep away from combustible material 远离可燃物料;
  • S36/37/39 Wear suitable protective clothing, gloves and eye/face protection 穿戴适当的防护服、手套和眼睛/面保护;
  • S45 In case of accident or if you feel unwell seek medical advice immediately (show the label where possible) 发生事故时或感觉不适时,立即求医(可能时出示标签);
  • S61 Avoid release to the environment. Refer to special instructions/safety data sheet 避免释放到环境中,参考特别指示/安全收据说明书;
UN Number UN1479
Risk Statements
  • R9 Explosive when mixed with combustible material 与易燃物混合会爆炸
  • R50/53
  • R41 Risk of serious damage to eyes 有严重损伤眼睛的危险
  • R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
  • R8 Contact with combustible material may cause fire 遇到易燃物会导致起火
Storage condition 密封避光保存 Light Sensitive Store at RT.
Packing GroupII
Hazard Class5.1
Warnings 危化品目录(2015)
TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Rodent - rat
DOSE/DURATION           : 2820 mg/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   AIHAAP American Industrial Hygiene Association Journal.  (AIHA, 475 Wolf
   Ledges Pkwy., Akron, OH 44311)  V.19-    1958-  Volume(issue)/page/year:
   30,470,1969

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Intraperitoneal
SPECIES OBSERVED        : Rodent - mouse
DOSE/DURATION           : 37 mg/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   GTPZAB Gigiena Truda i Professional'nye Zabolevaniya.  Labor Hygiene and
   Occupational Diseases. (V/O Mezhdunarodnaya Kniga, 113095 Moscow, USSR)
   V.1-36, 1957-1992. For publisher information, see MTPEEI
   Volume(issue)/page/year: 27(12),33,1983

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Rodent - mouse
DOSE/DURATION           : 1027 mg/kg
TOXIC EFFECTS :
   Behavioral - tetany
   Lungs, Thorax, or Respiration - cyanosis
   Gastrointestinal - hypermotility, diarrhea
REFERENCE :
   GTPZAB Gigiena Truda i Professional'nye Zabolevaniya.  Labor Hygiene and
   Occupational Diseases. (V/O Mezhdunarodnaya Kniga, 113095 Moscow, USSR)
   V.1-36, 1957-1992. For publisher information, see MTPEEI
   Volume(issue)/page/year: 27(12),33,1983

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Intraperitoneal
SPECIES OBSERVED        : Rodent - rat
DOSE/DURATION           : 70 mg/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   GTPZAB Gigiena Truda i Professional'nye Zabolevaniya.  Labor Hygiene and
   Occupational Diseas

Restrict 危险品

其他信息

  • 类别:氧化剂
  • 可燃性危险特性:光照分解氧, 遇易氧化物易燃
  • 毒性分级:低毒
  • Sigma Aldrich:20667-12-3(sigmaaldrich)
  • 用途一:用于医疗及用作玻璃磨光剂、着色剂、净水剂
  • 用途四:主要用作化学合成催化剂。还用作防腐剂、电子器件材料、玻璃着色剂及研磨剂。
  • 上游原料:氢氧化钠 --> 硝酸 --> 磷酸 --> 硝酸银 --> 氢氧化钡(八水) --> 银 --> 硝酸银溶液
  • 用途三:用作氧化剂、分析试剂和防腐剂
  • 图谱信息:氧化银(20667-12-3)红外图谱(IR1)
  • 下游产品:(S)-(+)-alpha-甲氧基苯乙酸 --> 胆碱 --> 吡咯-2-羧酸 --> 反式-2-苯基环丙烷-羧酸 --> 1-甲基-4-(甲氨基)哌啶 --> 4-(2-噻吩)苯胺,97% --> 偶氮二甲酰胺 --> (S)-(-)-环氧丙基甲基醚 --> (R)-(-)-环氧丙基甲基醚
  • 爆炸物危险特性:与有机物、易氧化物混合易爆
  • MOL 文件:20667-12-3.mol
  • 300°C时会完全分解。氧化银是立体的共价聚合物,难溶于大多数溶剂中。它在水中可略微溶解,生成Ag(OH)2–离子及类似的水解产物,水中溶解度 0.0013 g/100 ml (20°C) 。溶于生成可溶性银盐的酸中,也可与氨水、碳酸铵、氰化钾和氰化钾溶液配合而溶解。
  • 灭火剂:水、砂土
  • 水中溶解度(g/100ml):每100毫升水中的溶解克数: 1.3×10-3/20℃
  • 用途二:用于制药和有机合成,用作玻璃的磨光剂、着色剂,电池极板,催化剂和净水剂
  • 职业标准:TLV-TWA 0.01 毫克(铝)/立方米; STEL 0.03 毫克(铝)/立方米
  • Alfa Aesar:氧化银(I),ElectricalGrade Silver(I) oxide, Electrical Grade(20667-12-3)
  • 储运特性:库房通风低温干燥; 与燃料、有机物、易氧化物、硫、磷分开存放
  • 氧化银价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2011/08/23 80114916 氧化银 100g 1645元 2011/08/23 80114926 氧化银 100g 535元 2010/06/21 205800500 氧化银 Silver(I) oxide 99+% 50 GR 1709元
  • 方法一:硝酸银法硝酸银溶液与氢氧化钠溶液反应,生成的氧化银经洗涤、分离、干燥制得成品。其反应式为: 2AgNO3+2NaOH→Ag2O+2NANO3+H2O
  • 敏感性:Light Sensitive
  • Acros Organics:氧化银 Silver(I) oxide, 99+%(20667-12-3)
  • MSDS 信息:Silver(I) oxide(20667-12-3).msds
  • F:8
  • 急性毒性:口服-大鼠 LD50:2820 毫克/公斤; 口服-小鼠 LD50:1027 毫克/公斤

系列性分类


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