Bromocyclohexane 溴代环己烷

CAS 108-85-0 MFCD00003819

化学结构图

108-85-0
SMILES: Brc1ccccc1

化学属性

Mol. FormulaC6H11Br
Mol. Weight163.06
Density1.324
Refractive index1.4940 to 1.4980
Flash Point63°C
TSCAYes
Boiling Point161.1°C at 760 mmHg
Melting Point-57°C
Solubility不溶于水,溶于乙醇、乙醚。
Stability对光敏感

别名和识别编码

Chemical NameBromocyclohexane
CAS Number108-85-0
EC Number203-622-2
Beilstein Registry Number5,24
MDL NumberMFCD00003819
Synonym Bromocyclohexane {LY} Bromocyclohexane {} {LY} Bromocyclohexane {} {} {LY} Bromocyclohexane {} {} {} {LY} Bromocyclohexane {} {} {} {} {LY} Bromocyclohexane {} {} {} {} {} {LY} Bromocyclohexane {} {} {} {} {} {} {LY} Bromocyclohexane {} {} {} {} {} {} {} {LY} Bromocyclohexane {} {} {} {} {} {} {} {} {LY} Bromocyclohexane {} {} {} {} {} {} {} {} {} {LY} Bromocyclohexane {} {} {} {} {} {} {} {} {} {} {LY} Bromocyclohexane {} {} {} {} {} {} {} {} {} {} {} {LY} Bromocyclohexane {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {} {} {} {} {LY} Bromocyclohexane {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Bromocyclohexane {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Bromocyclohexane {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Bromocyclohexane {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {
Merck Number2730
PubChem Substance ID7960
Reaxys-RN1098373
Chemical Name Translation溴代环己烷
LabNetwork Molecule IDLN00223725
InChIInChI=1S/C6H11Br/c7-6-4-2-1-3-5-6/h6H,1-5H2
Canonical SMILESBrC1CCCCC1
信息真实价格透明    资金保障    专业采购外包团队在线服务   
信息真实价格透明    资金保障    专业采购外包团队在线服务   
品牌质保精细包装    现货库存    一流品牌服务   

分类

  • {uni_hamburg} no charge; carbocycle; alicycle; 6RingOnly; 6ring; 1fragment
  • {SNA} Alkyl, Building Blocks, Chemical Synthesis, Halogenated Hydrocarbons, Organic Building Blocks

产品应用

  • 有机合成中间体。

相关文献及参考

  • Short: II/19c
  • Merck:14,2730
  • Short: II/19b
  • Merck:14,2730 Beilstein:5,24

安全信息

Signal word Warning
GHS Symbol
WGK Germany3
Safety Statements
  • S37/39 Wear suitable gloves and eye/face protection 穿戴适当的手套和眼睛/面保护;
  • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后,立即用大量水冲洗并征求医生意见;
  • S23 Do not breathe gas/fumes/vapour/spray (appropriate wording to be specified by the manufacturer) 不要吸入气体/烟雾/蒸汽/喷雾;
  • S24/25 Avoid contact with skin and eyes 避免皮肤和眼睛接触;
  • S36/37/39 Wear suitable protective clothing, gloves and eye/face protection 穿戴适当的防护服、手套和眼睛/面保护;
  • S37 Wear suitable gloves 戴适当手套;
Risk Statements
  • R52 Harmful to aquatic organisms 对水生生物有害
  • R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
  • R18 In use, may form flammable/explosive vapour-air mixture 使用时可能生成易燃易爆的蒸汽-空气混合物
  • R20 Harmful by inhalation 吸入有害
Precautionary statements
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P501 Dispose of contents/container to..… 处理内容物/容器.....
  • P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P305+P351+P338
  • P210 Keep away from heat/sparks/open flames/hot surfaces. — No smoking. 远离热源/火花/明火/热的表面。——禁止吸烟。
  • P403+P235
RTECSGU7171700
Storage condition Store at room temperature {LY} Store at room temperature {} {LY} Store at room temperature {} {} {LY} Store at room temperature {} {} {} {LY} Store at room temperature {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {}
Personal Protective Equipment Eyeshields, full-face respirator (US), Gloves, multi-purpose combination respirator cartridge (US), type ABEK (EN14387) respirator filter
Hazard Codes Xn
Hazard statements
  • H227 Combustible liquid 可燃液体

其他信息

  • MOL 文件:108-85-0.mol
  • 上游原料:氢溴酸 --> 环己醇
  • 外观性质:无色至微黄色液体, 有刺激性气味。
  • 用途二:用于有机合成
  • 溴代环己烷价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2011/08/23 K1681001 溴代环己烷》99.0% 250ml 650元 2011/04/16 B0581 溴代环己烷 Bromocyclohexane 25G 146元 2011/04/16 B0581 溴代环己烷 Bromocyclohexane 500G 785元
  • F:8
  • Acros Organics:溴代环己烷 Cyclohexyl bromide, 99%(108-85-0)
  • 下游产品:2-二环己膦基-2'-(N,N-二甲胺)-联苯 --> 二氯[1,1'-双(耳叔丁基膦)二茂铁钯(II) ]PALLADIUM(II) --> 2-(二环己基膦基)联苯 --> 1,1'-双(二叔丁基膦)二茂铁 --> 二氯二(三环己基瞵)钯 --> 1-环己基哌嗪 --> 三环己基膦
  • Sigma Aldrich:108-85-0(sigmaaldrich)
  • 方法一:由环乙醇与溴氢酸反应而得:将环乙醇与48%氢溴酸加热回流6h。在反应混合物中加入少量水,分出下层的有机相,用无水氯化钙干燥。蒸馏,收集163-165℃馏分即为成品。产率74%。 用途:有机合成中间体。 #EndEditable "Content"
  • Alfa Aesar:溴代环己烷,99% Bromocyclohexane, 99%(108-85-0)
  • 敏感性:Air & Light Sensitive
  • 用途一:用作有机合成中间体
  • 用途三:有机合成中间体。 #EndEditable "Content"
  • TCI Shanghai:1-溴环己烷 Bromocyclohexane,>;98.0%(GC)(108-85-0)
  • 与乙醇、乙醚、丙酮、苯和四氯化碳混溶,不溶于水。有刺激性气味。
  • 存储注意事项:光敏感
  • 海关编码:29035990
  • 图谱信息:溴代环己烷(108-85-0)质谱(MS) 溴代环己烷(108-85-0)核磁图( 13 CNMR) 溴代环己烷(108-85-0)Raman光谱 溴代环己烷(108-85-0)核磁图( 1 HNMR) 溴代环己烷(108-85-0)红外图谱(IR1)
  • MSDS 信息:环己基溴(108-85-0).msds

系列性分类


相关产品推荐