1-Propanethiol 1-丙硫醇

CAS 107-03-9 MFCD00004900

化学结构图

107-03-9
SMILES: CCCS

化学属性

Mol. FormulaC3H8S
Mol. Weight76
Refractive index1.4360 to 1.4390
Boiling Point67-68
Density0.84
Melting Point-113
Flash Point-20°C(lit.)
TSCAYes
Vapor Density2.54 (vs air)
Vapor Pressure122 mmHg ( 20 °C)
Solubility微溶于水，溶于乙醇、乙醚等。

别名和识别编码

Chemical Name1-Propanethiol
Synonym 1-丙基硫醇/正丙硫醇 propanethiol(non-specificname) 1-Propan-1-thiol PROPYL MERCAPTAN NPM™ 丙硫醇 正丙基硫醇 硫氢丙烷 propane-1-thiol 3-mercaptopropanol mercaptanpropyliquenormal MERCAPTAN C3 正丙硫醇 n-propylmercapatan Propyl mercaptan n-Propyl mercaptan 丙基硫醇 1-丙硫醇 丙硫醇 正丙基硫醇 N-PROPYL MERCAPTAN 硫代丙醇 1-Propanthiol 1-丙三醇 丙硫醇 propylmercaptan(non-specificname) 1-Propanethoil n-thiopropylalcohol 丙基硫醇,1-丙硫醇,硫代丙醇,1-巯基丙烷,正丙硫醇 1-巯基丙烷 Propanethiol 1-propanethiol n-Propylthiol Propane-1-thiol 1-propane-thiol 1-propylmercaptan 1-PP 丙硫醇 正丙基硫醇 1-丙硫醇 NPM(TM) 1-Mercaptopropane n-Propanethiol n-Propylmercaptan N-propyl mercaptan 1-Propylthiol Propylmercaptan 1-Propyl mercaptan n-propylthiol 1-PROPANETHIOL 硫代正丙醇 FEMA 3521 Propylthiol n-Thiopropylalcohol propyl mercaptan n-C3H7SH
CAS Number107-03-9
PubChem Substance ID87574673
EC Number203-455-5
Beilstein Registry Number1696860
MDL NumberMFCD00004900
Reaxys-RN1696860
Chemical Name Translation1-丙硫醇
Wiswesser Line NotationSH3
LabNetwork Molecule IDLN00163783
InChIInChI=1S/C3H8S/c1-2-3-4/h4H,2-3H2,1H3
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分类

  • Alkyl Thiols, Allium cepa (Onion), Allium sativum (Garlic), Materials Science, Micro/NanoElectronics, Nutrition Research, Phytochemicals by Plant (Food/Spice/Herb), Self Assembly & Contact Printing, Self-Assembly Materials, Thiols
  • {SNA} Alphabetical Listings, Flavors and Fragrances, Halal Certified Products, Kosher Certified Products, O-P, O-Z
  • {SNA} Alkyl Thiols, Allium cepa (Onion), Allium sativum (Garlic), Materials Science, Micro/NanoElectronics, Phytochemicals by Plant (Food/Spice/Herb), Self Assembly & Contact Printing, Self-Assembly Materials, Thiols,
  • {S

产品应用

  • 有机合成中间体。除草剂。

相关文献及参考

  • Short: II/25C
  • Beilstein:1,359
  • Short: II/14a

安全信息

GHS Symbol
WGK Germany3
Hazard statements
  • H225 Highly flammable liquid and vapour 高度易燃液体和蒸气
  • H302 Harmful if swallowed 吞食有害
  • H315 Causes skin irritation 会刺激皮肤
  • H318 Causes serious eye damage 严重伤害眼睛
  • H335 May cause respiratory irritation 可能导致呼吸道刺激
Personal Protective Equipment Eyeshields, Faceshields, full-face respirator (US), Gloves, multi-purpose combination respirator cartridge (US), type ABEK (EN14387) respirator filter
Hazard Codes 3
RTECSTZ7300000
Precautionary statements
  • P210 Keep away from heat/sparks/open flames/hot surfaces. — No smoking. 远离热源/火花/明火/热的表面。——禁止吸烟。
  • P233 Keep container tightly closed. ?保持容器密闭。
  • P240 Ground/bond container and receiving equipment. 与地面接触/连接集装箱和接受设备。
  • P241+P242+P243
  • P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
  • P270 Do not eat, drink or smoke when using this product. 使用本产品时不要吃东西，喝水或吸烟。
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P301+P312+P330
  • P302+P352+P332+P313+P362+P364
  • P303+P361+P353
  • P304+P312
  • P305+P351+P338
  • P305+P351+P338+P337+P313
  • P332+P313
  • P362 Take off contaminated clothing and wash before reuse. 脱掉污染的衣服，清洗后方可重新使用
  • P370+P378
  • P403+P235
  • P501 Dispose of contents/container to..… 处理内容物/容器.....
Signal word Danger
Safety Statements
  • S16 Keep away from sources of ignition - No smoking 远离火源，禁止吸烟；
  • S23 Do not breathe gas/fumes/vapour/spray (appropriate wording to be specified by the manufacturer) 不要吸入气体/烟雾/蒸汽/喷雾；
  • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后，立即用大量水冲洗并征求医生意见；
  • S36/37/39 Wear suitable protective clothing, gloves and eye/face protection 穿戴适当的防护服、手套和眼睛/面保护；
  • S39 Wear eye/face protection 戴眼睛/面孔保护装置；
  • S61 Avoid release to the environment. Refer to special instructions/safety data sheet 避免释放到环境中，参考特别指示/安全收据说明书；
  • S9 Keep container in a well-ventilated place 保持容器在通风良好的场所；
Risk Statements
  • R11 Highly flammable 非常易燃
  • R21/22 Harmful in contact with skin and if swallowed 皮肤接触和不慎吞咽有害
  • R22 Harmful if swallowed 吞咽有害
  • R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
  • R37/38 Irritating to respiratory system and skin 对呼吸系统和皮肤有刺激性
  • R41 Risk of serious damage to eyes 有严重损伤眼睛的危险
  • R50 Very toxic to aquatic organisms 对水生生物极毒
UN Number 2402 UN 2402 3/PG 2 UN2402
Storage condition Air Sensitive Flammables area 密封充氩保存。
Packing GroupII
Hazard Class3
Warnings 危化品目录(2015) 
TYPE OF TEST            : LC50 - Lethal concentration, 50 percent kill
ROUTE OF EXPOSURE       : Inhalation
SPECIES OBSERVED        : Rodent - rat
DOSE/DURATION           : 7300 ppm/4H
TOXIC EFFECTS :
   Lungs, Thorax, or Respiration - respiratory stimulation
   Behavioral - somnolence (general depressed activity)
   Sense Organs and Special Senses (Eye) - lacrimation
REFERENCE :
   AIHAAP American Industrial Hygiene Association Journal.  (AIHA, 475 Wolf
   Ledges Pkwy., Akron, OH 44311)  V.19-    1958-  Volume(issue)/page/year:
   19,171,1958

TYPE OF TEST            : LC50 - Lethal concentration, 50 percent kill
ROUTE OF EXPOSURE       : Inhalation
SPECIES OBSERVED        : Rodent - mouse
DOSE/DURATION           : 4010 ppm/4H
TOXIC EFFECTS :
   Lungs, Thorax, or Respiration - respiratory stimulation
   Behavioral - somnolence (general depressed activity)
   Sense Organs and Special Senses (Eye) - chromodacryorrhea
REFERENCE :
   AIHAAP American Industrial Hygiene Association Journal.  (AIHA, 475 Wolf
   Ledges Pkwy., Akron, OH 44311)  V.19-    1958-  Volume(issue)/page/year:
   19,171,1958

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Intraperitoneal
SPECIES OBSERVED        : Rodent - rat
DOSE/DURATION           : 515 mg/kg
TOXIC EFFECTS :
   Behavioral - somnolence (general depressed activity)
   Lungs, Thorax, or Respiration - respiratory depression
   Behavioral - coma
REFERENCE :
   AIHAAP American Industrial Hygiene Association Journal.  (AIHA, 475 Wolf
   Ledges Pkwy., Akron, OH 44311)  V.19-    1958-  Volume(issue)/page/year:
   19,171,1958

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Rodent - rat
DOSE/DURATION           : 1790 mg/kg
TOXIC EFFECTS :
   Behavioral - somnolence (general depressed activity)
   Lungs, Thorax, or Respiration - respiratory d

Restrict 危险品

其他信息

  • 上游原料:硫脲 --> 无水氯化钙 --> Α-球蛋白 --> 氢硫酸 --> 稀硫酸 --> 硫氢化钠 --> 甲醇溶液 --> 正丙基溴
  • 用途一:可作有机合成原料，亦是农药杀虫剂的中间体。
  • 所属类别一:食品添加剂: 食用香料（增香剂）: 天然等同香料和人造香
  • TCI Shanghai
  • 用途二:丙硫醇即正丙硫醇，又名硫代丙醇、1-巯基丙烷，在农药生产上可用于合成有机磷杀虫剂丙硫磷、硫丙磷，杀线虫剂及土壤杀虫剂灭线磷，除草剂克草敌的中间体，也用作其他有
  • 所属类别二:农药中间体: 杀虫剂中间体: 有机磷类杀虫剂
  • 食品添加剂最大允许使用量最大允许残留量标准:添加剂中文名称 允许使用该种添加剂的食品中文名称 添加剂功能 最大允许使用量（g/kg） 最大允许残留量（g/kg） 丙硫醇 食品 食品用香料 用于配制香精的各香料成分不得超过在GB 2760中的最大允许使用量和最大允许残留量
  • 外观性质:无色或淡黄色液体，有刺激气味。
  • Sigma Aldrich:107-03-9(sigmaaldrich)
  • MOL 文件:107-03-9.mol
  • FEMA:3521
  • 海关编码:29309070
  • 用途四:有机合成中间体。除草剂。
  • 丙硫醇价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2011/08/23 K8237001 正丙硫醇（*） 250ml 452元 2011/04/16 P0488 1-丙硫醇 1-Propanethiol 25ML 146元 2011/04/16 P0488 1-丙硫醇 1-Propanethiol 500ML 429元
  • 下游产品:阿苯达唑 --> 灭克磷 --> 硫丙磷 --> 2-硝基亚甲基-1,3-噻嗪烷-3-基甲醛 --> 灭草猛 --> S-丙基二硫代磷酰二氯 --> 硫线磷
  • F:13
  • 蒸气密度:2.54 (vs
  • 图谱信息:丙硫醇(107-03-9)红外图谱(IR1) 丙硫醇(107-03-9)质谱(MS) 丙硫醇(107-03-9)核磁图( 1 HNMR) 丙硫醇(107-03-9)核磁图( 13 CNMR)
  • MSDS 信息:正丙硫醇(107-03-9).msds
  • 用途三:用作农药和其他有机合成的中间体。
  • 方法二:1.由溴丙烷与硫脲反应而得。将硫脲与溴丙烷的甲醇溶液中回流3h，回收甲醇后，加入稀氢氧化钠溶液再回流6h。然后，慢慢滴加稀硫酸，随时蒸出丙硫醇，当稀硫酸加完后，再继续蒸馏，直至蒸不出油珠为止。收集的油层为粗品，用无水氯化钙干燥，然后精馏，收集沸点66.5-76.5℃馏分即得为成品。2.由卤代丙烷与硫氢化钠作用而得。3.丙醇与硫化氢于300-380℃通过催化反应也可得到丙基硫醇。
  • Acros Organics:1-丙硫醇 1-Propanethiol, 98%(107-03-9)
  • 有恶臭。溶于乙醇、乙醚、丙酮、苯和烃，不溶于水。易燃。
  • 使用限量:FEMA(mg/kg)：饮料、冷饮、布丁、果酱、明胶冻，1.0；糖果1.25；焙烤制品0.929；肉制品2.2；汤品3.0。 FDA，§172．515(2000)：适量为限
  • 参考质量标准:FAO/WHO，1999 折射率(n D 20 ) 1.438 相对密度(d 25 25 ) 0.842~0.847
  • 方法一:其制备方法是由溴丙烷与硫脲反应而得。 将硫脲与溴丙烷在甲醇溶液中回流3h，回收甲醇后，加入稀氢氧化钠溶液再回流6h。然后，慢慢滴加稀硫酸，随加随蒸出丙硫醇，当稀硫酸加完后，再继续蒸馏，直至蒸不出油珠为止。收集的油层为粗品，用无水氯化钙干燥，然后精馏，收集b.p.66.5～76.5℃馏分即为成品。 另外，丙醇与硫化氢于300～380℃通过催化反应也可得到丙硫醇。
  • 蒸气压:122 mm Hg ( 20 °C)

系列性分类

  1. Application Areas 应用领域分类
  2. Flavors and Fragrances 香精香料
  3. Kosher Certified Products - Flavors and Fragrances
  4. O-Z - Kosher Certified Products
  1. Application Areas 应用领域分类
  2. Flavors and Fragrances 香精香料
  3. Alphabetical Listings - Flavors and Fragrances
  4. O-P - Alphabetical Listings
  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Heterocyclic Building Blocks 杂环合成砌块
  4. Piperidines 哌啶
  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Organic Building Blocks 有机砌块
  4. Sulfur Compounds 硫化合物
  1. Chemical Synthesis 化学合成
  2. Synthetic Reagents 合成试剂
  3. Inorganic Salts - Synthetic Reagents
  4. Magnesium - Inorganic Salts
  1. Materials Science 材料科学
  2. Micro/NanoElectronics - Materials Science
  3. Self Assembly & Contact Printing - Micro/NanoElectronics
  4. Self-Assembly Materials - Self Assembly & Contact Printing
  5. Thiols - Self-Assembly Materials
  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Organic Building Blocks 有机砌块
  4. Sulfur Compounds 硫化合物
  5. Thiols/Mercaptans - Sulfur Compounds
  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Organic Building Blocks 有机砌块
  4. Sulfur Compounds 硫化合物
  5. Thiol/Mercaptan Salts - Sulfur Compounds
  1. Materials Science 材料科学
  2. Micro/NanoElectronics - Materials Science
  3. Self Assembly & Contact Printing - Micro/NanoElectronics
  4. Self-Assembly Materials - Self Assembly & Contact Printing
  5. Thiols - Self-Assembly Materials
  6. Alkyl Thiols - Thiols
  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Organic Building Blocks 有机砌块
  4. Sulfur Compounds 硫化合物
  5. Thiol/Mercaptan Salts
  1. Functional Group 官能团索引
  2. alkylthiol

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