1,3,5-Triazine 1,3,5-三嗪

CAS 290-87-9 MFCD00006044

化学结构图

290-87-9
SMILES: C1NCNCN1

化学属性

Mol. FormulaC3H3N3
Mol. Weight81.08
Melting Point77-83°C
Density1.380
TSCANo
Boiling Point114°C at 760 mmHg
Flash Point114°C
Solubilitymethanol: 0.1 g/mL, clear

别名和识别编码

Chemical Name1,3,5-Triazine
Synonym 1,3,5-Triazine {LY} 1,3,5-Triazine {} {LY} 1,3,5-Triazine {} {} {LY} 1,3,5-Triazine {} {} {} {LY} 1,3,5-Triazine {} {} {} {} {LY} 1,3,5-Triazine {} {} {} {} {} {LY} 1,3,5-Triazine {} {} {} {} {} {} {LY} 1,3,5-Triazine {} {} {} {} {} {} {} {LY} 1,3,5-Triazine {} {} {} {} {} {} {} {} {LY} 1,3,5-Triazine {} {} {} {} {} {} {} {} {} {LY} 1,3,5-Triazine {} {} {} {} {} {} {} {} {} {} {LY} 1,3,5-Triazine {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 1,3,5-Triazine {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 1,3,5-Triazine {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 1,3,5-Triazine {} {} {} {} {} {} {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 1,3,5-Triazine {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 1,3,5-Triazine {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {
MDL NumberMFCD00006044
CAS Number290-87-9
PubChem Substance ID9262
Beilstein Registry Number104790
EC Number206-028-1
Reaxys-RN104790
Merck Number9602
Chemical Name Translation1,3,5-三嗪
LabNetwork Molecule IDLN00194078
InChIInChI=1S/C3H3N3/c1-4-2-6-3-5-1/h1-3H
Canonical SMILESN1=CN=CN=C1
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分类

  • {SNA} Boger Tetrazines and Triazines, Building Blocks, Chemical Synthesis, Heterocyclic Building Blocks, Triazines
  • {SNA} Building Blocks, Chemical Synthesis, Heterocyclic Building Blocks, Triazines
  • {uni_hamburg} no charge; nitrogen heterocycle; aromatic; 6RingOnly; 6ring; 1fragment

相关文献及参考

  • Short: II/19c
  • Formylating agent: useful replacement for HCN in the Gattermann reaction for the synthesis of aromatic aldehydes: J. Am. Chem. Soc., 76, 290 (1954); Angew. Chem. Int. Ed., 6, 940 (1969); Arch. Pharm., 302, 828 (1969); 304, 362 (1971); with reactive substrates, formylation can be accomplished without a catalyst.
  • Also reacts with nucleophiles, e.g. amines, which has been utilized in a quinazoline synthesis: J. Chem. Soc. (C), 1282 (1969):
  • Short: II/19a

安全信息

WGK Germany3
GHS Symbol
Precautionary statements
  • P201 Obtain special instructions before use. 使用前获取专门指示。
  • P202 Do not handle until all safety precautions have been read and understood. 已阅读并理解所有的安全预防措施之前,切勿操作。
  • P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
  • P270 Do not eat, drink or smoke when using this product. 使用本产品时不要吃东西,喝水或吸烟。
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P301+P312+P330
  • P302+P352+P332+P313+P362+P364
  • P305+P351+P338
  • P332+P313
  • P362 Take off contaminated clothing and wash before reuse. 脱掉污染的衣服,清洗后方可重新使用
  • P405 Store locked up. 上锁保管。
  • P501 Dispose of contents/container to..… 处理内容物/容器.....
Hazard statements
  • H315 Causes skin irritation 会刺激皮肤
  • H318 Causes serious eye damage 严重伤害眼睛
  • H302 Harmful if swallowed 吞食有害
  • H335 May cause respiratory irritation 可能导致呼吸道刺激
RTECSXY2957000
Signal word Danger
Personal Protective Equipment dust mask type N95 (US), Eyeshields, Gloves
Safety Statements
  • S22 Do not breathe dust 不要吸入粉尘;
  • S24/25 Avoid contact with skin and eyes 避免皮肤和眼睛接触;
  • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后,立即用大量水冲洗并征求医生意见;
  • S36/37/39 Wear suitable protective clothing, gloves and eye/face protection 穿戴适当的防护服、手套和眼睛/面保护;
  • S39 Wear eye/face protection 戴眼睛/面孔保护装置;
  • S60 This material and its container must be disposed of as hazardous waste 该物质及其容器必须作为危险废物处置;
Risk Statements
  • R22 Harmful if swallowed 吞咽有害
  • R37/38 Irritating to respiratory system and skin 对呼吸系统和皮肤有刺激性
  • R41 Risk of serious damage to eyes 有严重损伤眼睛的危险
Storage condition Store at room temperature {LY} Store at room temperature {} {LY} Store at room temperature {} {} {LY} Store at room temperature {} {} {} {LY} Store at room temperature {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {}
Hazard Codes Xn
Packing GroupII
Hazard Class6.1
UN Number UN2928
TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Bird - quail
DOSE/DURATION           : 237 mg/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   EESADV Ecotoxicology and Environmental Safety.  (Academic Press, Inc., 1 E.
   First St., Duluth, MN 55802)  V.1-    1977-  Volume(issue)/page/year:
   6,149,1982

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Bird - wild bird species
DOSE/DURATION           : 100 mg/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   AECTCV Archives of Environmental Contamination and Toxicology.
   (Springer-Verlag New York, Inc., Service Center, 44 Hartz Way, Secaucus, NJ
   070944)  V.1-    1973-  Volume(issue)/page/year: 12,355,1983

其他信息

  • TCI Shanghai:1,3,5-三嗪 1,3,5-Triazine,>;95.0%(GC)(N)(290-87-9)
  • 图谱信息:1,3,5-三嗪(290-87-9)Raman光谱 1,3,5-三嗪(290-87-9)核磁图( 1 HNMR) 1,3,5-三嗪(290-87-9)红外图谱(IR1) 1,3,5-三嗪(290-87-9)质谱(MS) 1,3,5-三嗪(290-87-9)核磁图( 13 CNMR)
  • 下游产品:3-(4-甲氧基-6-甲基-1,3,5-三嗪-2-基)-1-(2-甲氧基甲酰基苯基)磺酰脲 --> 苯磺隆 --> 2-氨基-4-甲基-6-甲氧基-1,3,5-三嗪 --> 醚黄隆 --> 4-氨基嘧啶-5-羧酰胺 --> 特丁净
  • MOL 文件:290-87-9.mol
  • Sigma Aldrich:290-87-9(sigmaaldrich)
  • Alfa Aesar:1,3,5-三嗪,97% 1,3,5-Triazine, 97%(290-87-9)
  • 1,3,5-三嗪价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2014/06/02 T0339 1,3,5-三嗪 1,3,5-Triazine 5G 1180元 2014/06/02 T0339 1,3,5-三嗪 1,3,5-Triazine 25G 2920元 2014/06/02 T0339 1,3,5-三嗪 1,3,5-Triazine 1G 386元
  • 敏感性:Moisture Sensitive

系列性分类


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