3-Nitrophthalic Acid 3-硝基邻苯二甲酸

CAS 603-11-2 MFCD00007138

化学结构图

603-11-2
SMILES: O=C(O)c1cccc([N+](=O)[O-])c1C(=O)O

化学属性

Mol. FormulaC8H5NO6
Mol. Weight211.13
Melting Point210°C
Density1.671
TSCAYes
Solubility20 G/L (25 ºC)
Appearance 淡黄色结晶。熔点213-216℃（分解）。溶于热水、甲醇、乙醇，微溶于醚，不溶于氯仿、四氯化碳、二硫化碳、苯。
Boiling Point441.3°C at 760 mmHg

别名和识别编码

Chemical Name3-Nitrophthalic Acid
CAS Number603-11-2
Synonym 3-Nitrophthalic acid {LY} 3-Nitrophthalic acid {} {LY} 3-Nitrophthalic acid {} {} {LY} 3-Nitrophthalic acid {} {} {} {LY} 3-Nitrophthalic acid {} {} {} {} {LY} 3-Nitrophthalic acid {} {} {} {} {} {LY} 3-Nitrophthalic acid {} {} {} {} {} {} {LY} 3-Nitrophthalic acid {} {} {} {} {} {} {} {LY} 3-Nitrophthalic acid {} {} {} {} {} {} {} {} {LY} 3-Nitrophthalic acid {} {} {} {} {} {} {} {} {} {LY} 3-Nitrophthalic acid {} {} {} {} {} {} {} {} {} {} {LY} 3-Nitrophthalic acid {} {} {} {} {} {} {} {} {} {} {} {LY} 3-Nitrophthalic acid {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 3-Nitrophthalic acid {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 3-Nitrophthalic acid {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 3-Nitrophthalic acid {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 3-Nitrophthalic acid {} {} {}
Beilstein Registry Number9,823
PubChem Substance ID69043
EC Number210-030-8
MDL NumberMFCD00007138
Reaxys-RN2054269
Chemical Name Translation3-硝基邻苯二甲酸
InChIKeyKFIRODWJCYBBHY-UHFFFAOYSA-N
LabNetwork Molecule IDLN00224558
InChIInChI=1S/C8H5NO6/c10-7(11)4-2-1-3-5(9(14)15)6(4)8(12)13/h1-3H,(H,10,11)(H,12,13)
Canonical SMILESO=C(C1=CC=CC([N+]([O-])=O)=C1C(O)=O)O
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分类

  • Building Blocks, C8, Carbonyl Compounds, Carboxylic Acids, Chemical Synthesis, Organic Building Blocks
  • {SNA} Building Blocks, C8, Carbonyl Compounds, Carboxylic Acids, Chemical Synthesis, Organic Building Blocks

产品应用

  • 用作有机合成中间体，可用于合成医药、染料、农作物保护剂等。

相关文献及参考

  • Beilstein:9,823

安全信息

Precautionary statements
  • P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
  • P271 Use only outdoors or in a well-ventilated area.? 只能在室外或通风良好的地方使用。
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P302+P350
  • P302+P352
  • P302+P352+P332+P313+P362+P364
  • P304+P340
  • P305+P351+P338
  • P305+P351+P338+P337+P313
  • P310 Immediately call a POISON CENTER or doctor/physician. 立即呼救解毒中心或医生/医师。
  • P312 Call a POISON CENTER or doctor/physician if you feel unwell. 如果你感觉不适，呼叫解毒中心或医生/医师。
  • P321 Specific treatment (see … on this label). 具体治疗（见本标签上的）。
  • P332+P313
  • P337+P313
  • P362 Take off contaminated clothing and wash before reuse. 脱掉污染的衣服，清洗后方可重新使用
  • P403+P233
  • P405 Store locked up. 上锁保管。
  • P501 Dispose of contents/container to..… 处理内容物/容器.....
WGK Germany3
GHS Symbol
Signal word
Hazard statements
  • H315 Causes skin irritation 会刺激皮肤
  • H318 Causes serious eye damage 严重伤害眼睛
  • H335 May cause respiratory irritation 可能导致呼吸道刺激
Hazard Codes Xi
Personal Protective Equipment dust mask type N95 (US), Eyeshields, Gloves
Safety Statements
  • S37/39 Wear suitable gloves and eye/face protection 穿戴适当的手套和眼睛/面保护；
  • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后，立即用大量水冲洗并征求医生意见；
  • S36/39 Wear suitable protective clothing and eye/face protection 穿戴适当的防护服和眼睛/面保护；
  • S37 Wear suitable gloves 戴适当手套；
  • S36/37/39 Wear suitable protective clothing, gloves and eye/face protection 穿戴适当的防护服、手套和眼睛/面保护；
Risk Statements
  • R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
  • R41 Risk of serious damage to eyes 有严重损伤眼睛的危险
Storage condition 2-8°C {LY} 2-8°C {} {LY} 2-8°C {} {} {LY} 2-8°C {} {} {} {LY} 2-8°C {} {} {} {} {LY} 2-8°C {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {

其他信息

  • 方法一:将苯酐加入浓硫酸中，搅拌下通入水蒸气加热至80℃，滴加发烟硝酸，反应温度维持100-110℃，加毕，在110℃以上加热2h，放置过夜后倾入水中，过滤。滤饼用水重结晶，得3-硝基邻苯二甲酸。收率约30%。
  • Acros Organics:3-硝基邻苯二甲酸 3-Nitrophthalic acid, 95%(603-11-2)
  • Alfa Aesar:3-硝基邻苯二甲酸,95% 3-Nitrophthalic acid, 95%(603-11-2)
  • 图谱信息:3-硝基邻苯二甲酸(603-11-2)Raman光谱 3-硝基邻苯二甲酸(603-11-2)红外图谱(IR1) 3-硝基邻苯二甲酸(603-11-2)核磁图( 1 HNMR) 3-硝基邻苯二甲酸(603-11-2)质谱(MS) 3-硝基邻苯二甲酸(603-11-2)红外图谱(IR2) 3-硝基邻苯二甲酸(603-11-2)核磁图( 13 CNMR)
  • 用途二:用作有机合成中间体，可用于合成医药、染料、农作物保护剂等
  • 用途一:用作感光材料及医药中间体
  • 下游产品:发光氨 --> 坎地沙坦 --> 2-氨基-6-硝基苯甲酸 --> 3-硝基邻苯二甲酸酐
  • 上游原料:硝酸
  • Sigma Aldrich:603-11-2(sigmaaldrich)
  • MSDS 信息:3-Nitro-1,2-benzenedicarboxylic acid(603-11-2).msds
  • Hazard Note:Irritant
  • TCI Shanghai:3-硝基邻苯二甲酸 3-Nitrophthalic Acid,>;98.0%(LC)(T)(603-11-2)
  • 溶解度:20 g/l 水(25 C)，1g/10ml 甲醇。
  • 3-硝基邻苯二甲酸价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2014/06/02 N0243 3-硝基邻苯二甲酸 3-Nitrophthalic Acid 500G 990元 2014/06/02 N0243 3-硝基邻苯二甲酸 3-Nitrophthalic Acid 25G 198元 2010/06/21 160165000 3-硝基邻苯二甲酸 3-Nitrophthalic acid 95% 500 GR 1743元
  • 用途三:用作有机合成中间体，可用于合成医药、染料、农作物保护剂等。
  • 检测方法:HPLC,NMR
  • MOL 文件:603-11-2.mol
  • 海关编码:29173980

系列性分类

  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Organic Building Blocks 有机砌块
  4. Carbonyl Compounds 羰基化合物
  5. Carboxylic Acids - Carbonyl Compounds
  6. C8 - Carboxylic Acids
  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Organic Building Blocks 有机砌块
  4. Carbonyl Compounds 羰基化合物
  5. Aromatic acids
  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Organic Building Blocks 有机砌块
  4. Carbonyl Compounds 羰基化合物
  5. Carboxylic Acids
  6. C7