2,4-Dinitroaniline, 98% 2,4-二硝基苯胺

CAS 97-02-9 MFCD00007151

化学结构图

97-02-9
SMILES: Nc1ccc([N+](=O)[O-])cc1[N+](=O)[O-]

化学属性

Mol. FormulaC6H5N3O4
Mol. Weight183
Melting Point176-178
Density1.61
Flash Point224°(435°F)
TSCAYes
Solubility0.06 G/L (20 ºC)
Stability对光敏感

别名和识别编码

Chemical Name2,4-Dinitroaniline, 98%
MDL NumberMFCD00007151
CAS Number97-02-9
Synonym 2,4-Dinitroaniline {LY} 2,4-Dinitroaniline 2,4-Dinitrobenzamine 2,4-Dinitrobenzenamine 2,4-dinitro-Benzenamine 2,4-dinitro-anilin 2,4-dinitro-aniline 2,4-dinitro-benzenamin 2,4-dinitrophenylamine 2,4-二硝基苯胺 2,4-二硝基苯胺, 99% (DRY WT.), CONT. UP TO 15% WATER 2,4-二硝苯胺 2,4-硝基苯胺 2.4-二硝基苯胺 2,4-DINITROANILINE 4-二硝基苯,间二硝基苯胺 Benzenamine, 2,4-dinitro- DNA NCI-C60753 dinitro-2,4aniline {} {LY} 2,4-Dinitroaniline {} {} {LY} 2,4-Dinitroaniline {} {} {} {LY} 2,4-Dinitroaniline {} {} {} {} {LY} 2,4-Dinitroaniline {} {} {} {} {} {Chemicalbook {} {} {} {} {} {uni_hamburg} 2,4-Dinitroanilin {} {} {} {} {} {} {Chemicalbook} 2,4-Dinitroaminobenzene {} {} {} {} {} {} {} {uni_hamburg} 2,4-Dinitro {} {} {} {} {} {} {} {} {Chemicalbook} 2,4-DINITROANILI
PubChem Substance ID87569112
EC Number202-553-5
Beilstein Registry Number982999
Merck Number3270
Reaxys-RN982999
Chemical Name Translation2,4-二硝基苯胺
Wiswesser Line NotationWNR BZ ENW
LabNetwork Molecule IDLN00195996
Canonical SMILESNC1=CC=C([N+]([O-])=O)C=C1[N+]([O-])=O
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分类

  • {SNA} Alphabetical Index of Analytical Standards, Chemical Class, Alpha Sort, Amines, Analytical Standards, Analytical/Chromatography, Aromatics, Chromatography, D, DID - DIN, Environmental Standards, Nitro Compounds,
  • {SNA} Alpha Sort, Alphabe

产品应用

  • 用作偶氮染料中间体，腐蚀抑制剂，分析试剂。检验酚和某些不饱和烃，有机合成。

相关文献及参考

  • Short: II/27C Title: Diamagnetic Susceptibility and Magnetic Anisotropy of Organic Compounds Author: Kumar, Mahendra; Gupta, Rajni Editor: Gupta, Radha Raman Source: Landolt-Börnstein, New Series Volume: II/27C Year: 2008 Keyword: diamagnetic susceptibility; magnetic anisotropy; organic compounds ISBN: 978-3-540-44734-4 (print) ISBN: 978-3-540-44736-8 (online) Internet Resource: doi:10.1007/978-3-540-44736-8 RefComment: VIII, 204 p., Hardcover RefComment: Written for: Scientists and researchers in the fields of physics, chemistry, materials science RefComment: Supplement and Revised Editon to II/16 Abstract: The volume II/27 has been divided into three subvolumes according to the classes of compounds: Subvolume A: Diamagnetic susceptibility and magnetic anisotropy of inorganic and organometallic compounds; Subvolume B: Diamagnetic susceptibility of organic compounds (Part 1); Subvolume C: Diamagnetic susceptibility and magnetic anisotropy of organic compounds (Part 2). The data presented in this volume are based on the literature survey of the chemical abstracts up to 2005.
  • Short: III/35E Title: Nuclear Magnetic Resonance (NMR) Data: Chemical Shifts for Oxygen-17 Author: Duddeck, H.; Toth, G.; Simon, A. Editor: Gupta, R.R.; Lechner, M.D. Source: Landolt-Börnstein, New Series Volume: III/35E Year: 2002 Keyword: Alipathic and Aromatic hydrocarbons; Coupling constant j; Nuclear Magnetic Resonance; chemical shifts δ ISBN: 3-540-42501-2 ISBN: 978-3-540-42501-4 Internet Resource: DOI:10.1007/b92953 RefComment: VII, 230 pages. With CD-ROM., Hardcover Abstract: This volume provides a comprehensive and evaluated compilation of nuclear magnetic resonance data. Chemical shifts and coupling constants of boron-11 and phosphorus-31 (subvol. A), fluorine-19 and nitrogen-15 (subvol. B), hydrogen-1 (subvol. C), carbon-13 (subvol. D), and oxygen-17 (subvol. E) compounds are tabulated together with the gross- and structure formulas and the most readily a

安全信息

GHS Symbol
WGK Germany2
Hazard statements
  • H301 Toxic if swallowed 吞食有毒
  • H330 Fatal if inhaled 吸入致命
  • H411 Toxictoaquaticlifewithlonglastingeffects 对水生生物有毒性并具有长期影响。
  • H310 Fatal in contact with skin 皮肤接触致命
  • H373 May causes damage to organs through prolonged or repeated exposure 长期或频繁接触可能会损伤器官
  • H300 Fatal if swallowed 吞食致命
Precautionary statements
  • P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
  • P391 Collect spillage. Hazardous to the aquatic environment 收集对水环境有危害的泄漏物。
  • P301+P316
  • P321 Specific treatment (see … on this label). 具体治疗（见本标签上的）。
  • P405 Store locked up. 上锁保管。
  • P262 Do not get in eyes, on skin, or on clothing. 不要接触眼睛，皮肤或衣服。
  • P270 Do not eat, drink or smoke when using this product. 使用本产品时不要吃东西，喝水或吸烟。
  • P501 Dispose of contents/container to..… 处理内容物/容器.....
  • P284 Wear respiratory protection.? 佩戴呼吸保护装置。
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P302+P352
  • P304+P340
  • P271 Use only outdoors or in a well-ventilated area.? 只能在室外或通风良好的地方使用。
  • P361+P364
  • P319
  • P273 Avoid release to the environment. 避免释放到环境中。
  • P260 Do not breathe dust/fume/gas/mist/vapours/spray. 不要吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P330 Rinse mouth. 漱口
  • P403+P233
  • P320 Specific treatment is urgent (see … on this label). 紧急具体治疗（见本标签上的）。
Signal word Danger
RTECSBX9100000
Personal Protective Equipment dust mask type N95 (US), Eyeshields, Faceshields, Gloves, type P2 (EN 143) respirator cartridges
Safety Statements
  • S61 Avoid release to the environment. Refer to special instructions/safety data sheet 避免释放到环境中，参考特别指示/安全收据说明书；
  • S45 In case of accident or if you feel unwell seek medical advice immediately (show the label where possible) 发生事故时或感觉不适时，立即求医（可能时出示标签）；
  • S28 After contact with skin, wash immediately with plenty of ... (to be specified by the manufacturer) 皮肤接触后，立即用大量…（由生产厂家指定）冲洗；
  • S36/37 Wear suitable protective clothing and gloves 穿戴适当的防护服和手套；
Packing GroupII
UN Number 1596
Risk Statements
  • R33 Danger of cumulative effects 有累积作用的危险
  • R51/53
  • R26/27/28 Very toxic by inhalation, in contact with skin and if swallowed 吸入，皮肤接触及吞食都有剧毒
Hazard Codes 6.1
Hazard Class6.1
Storage condition Store at room temperature {LY} Store at room temperature {} {LY} Store at room temperature {} {} {LY} Store at room temperature {} {} {} {LY} Store at room temperature {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {} {} {} {} {Chemicalbook} Flammables area 密封避光保存。 
TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Rodent - rat
DOSE/DURATION           : 285 mg/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   TSCAT* Office of Toxic Substances Report.  (U.S. Environmental Protection
   Agency, Office of Toxic Substances, 401 M St., SW, Washington, DC 20460)
   Volume(issue)/page/year: OTS 206512

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Rodent - guinea pig
DOSE/DURATION           : 1050 mg/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   GISAAA Gigiena i Sanitariya.  For English translation, see HYSAAV.  (V/O
   Mezhdunarodnaya Kniga, 113095 Moscow, USSR)  V.1-    1936-
   Volume(issue)/page/year: 47(10),15,1982

TYPE OF TEST            : LDLo - Lowest published lethal dose
ROUTE OF EXPOSURE       : Intraperitoneal
SPECIES OBSERVED        : Rodent - rat
DOSE/DURATION           : 250 mg/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   NCNSA6 National Academy of Sciences, National Research Council,
   Chemical-Biological Coordination Center, Review.  (Washington, DC)
   Volume(issue)/page/year: 5,32,1953

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Rodent - mouse
DOSE/DURATION           : 370 mg/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   GTPZAB Gigiena Truda i Professional'nye Zabolevaniya.  Labor Hygiene and
   Occupational Diseases. (V/O Mezhdunarodnaya Kniga, 113095 Moscow, USSR)
   V.1-36, 1957-1992. For publisher information, see MTPEEI
   Volume(issue)/page/year: 25(8),50,1981

TYPE OF

TYPE OF TEST            : Unscheduled DNA synthesis
TEST SYSTEM             : Rodent - rat Liver
DOSE/DURATION           : 50 umol/L
REFERENCE :
   MUREAV Mutation Research.  (Elsevier Science Pub. B.V., POB 211, 1000 AE
   Amsterdam, Netherlands) V.1-    1964-  Volume(issue)/page/year: 221,263,1989

TYPE OF TEST            : Mutation in microorganisms
TEST SYSTEM             : Bacteria - Salmonella typhimurium
DOSE/DURATION           : 10 ug/plate
REFERENCE :
   ENMUDM Environmental Mutagenesis.  (New York, NY)  V.1-9, 1979-87.  For
   publisher information, see EMMUEG.  Volume(issue)/page/year: 5(Suppl
   1),3,1983

TYPE OF TEST            : Mutation in microorganisms
TEST SYSTEM             : Bacteria - Salmonella typhimurium
DOSE/DURATION           : 2 ug/plate
REFERENCE :
   MUREAV Mutation Research.  (Elsevier Science Pub. B.V., POB 211, 1000 AE
   Amsterdam, Netherlands) V.1-    1964-  Volume(issue)/page/year: 67,1,1979

TYPE OF TEST            : TCLo - Lowest published toxic concentration
ROUTE OF EXPOSURE       : Inhalation
SPECIES OBSERVED        : Rodent - rat
DOSE                    : 17 mg/m3/4H
SEX/DURATION            : female 1-7 day(s) after conception
TOXIC EFFECTS :
   Reproductive - Effects on Embryo or Fetus - fetal death
REFERENCE :
   GTPZAB Gigiena Truda i Professional'nye Zabolevaniya.  Labor Hygiene and
   Occupational Diseases. (V/O Mezhdunarodnaya Kniga, 113095 Moscow, USSR)
   V.1-36, 1957-1992. For publisher information, see MTPEEI
   Volume(issue)/page/year: 26(6),47,1982

TYPE OF TEST            : TCLo - Lowest published toxic concentration
ROUTE OF EXPOSURE       : Inhalation
SPECIES OBSERVED        : Rodent - rat
DOSE                    : 1100 ug/m3/4H
SEX/DURATION            : female 1-7 day(s) after conception
TOXIC EFFECTS :
   Reproductive - Effects on Embryo or Fetus - fetotoxicity (except death,
   e.g., stunted fetus)
REFERENCE :
   GTPZAB Gigiena Truda i Professional'nye Zabolevaniya.  Labor Hygiene and
   Occupational Diseases. (V/O Mezhdunarodnaya Kniga, 113095 Moscow, USSR)
   V.1-36, 1957-1992. For publisher information, see MTPEEI
   Volume(issue)/page/year: 26(6),47,1982

TYPE OF TEST            : TCLo - Lowest published toxic concentration
ROUTE OF EXPOSURE       : Inhalation
SPECIES OBSERVED        : Rodent - rat
DOSE                    : 17 mg/m3/4H
SEX/DURATION            : female 1-7 day(s) after conception
TOXIC EFFECTS :
   Reproductive - Fertility - pre-implantation mortality (e.g. reduction in
   number of implants per female; total number of implants per corpora lutea)
REFERENCE :
   GTPZAB Gigiena Truda i Professional'nye Zabolevaniya.  Labor Hygiene and
   Occupational Diseases. (V/O Mezhdunarodnaya Kniga, 113095 Moscow, USSR)
   V.1-36, 1957-1992. For publisher information, see MTPEEI
   Volume(issue)/page/year: 26(6),47,1982

Warnings 危险化学品

其他信息

  • 方法一:由2,4-二硝基氯苯加压氨解而得。在氨解反应锅内加入15kg拉开粉（1,2-二丁基萘-6-磺酸钠）、300kg2,4-二硝基氯苯、1350L氨水（含氨150kg），加热，在1h左右升温到80℃，停止加热。控制反应温度为108-110℃，压力为0.35-0.4MPa。保温反应4h后泄压。放出的氨气用水吸收回用。反应液冷却至35℃以下过滤，滤饼用冷水洗涤到接近中性，得成品。收率90-95%。
  • 上游原料:氨 --> 4-氯苯甲醛 --> 2,4-二硝基氯苯 --> 磺酸钠 --> 工业氨水 --> 丁基萘磺酸钠
  • 刺激数据:眼睛-兔子 500 毫克/24小时 轻度
  • 图谱信息:2,4-二硝基苯胺(97-02-9)核磁图( 1 HNMR) 2,4-二硝基苯胺(97-02-9)质谱(MS) 2,4-二硝基苯胺(97-02-9)红外图谱(IR1) 2,4-二硝基苯胺(97-02-9)核磁图( 13 CNMR) 2,4-二硝基苯胺(97-02-9)红外图谱(IR2)
  • 储运特性:库房通风低温干燥; 与氧化剂、食品添加剂、酸类分开存放
  • 类别:有毒物品
  • Alfa Aesar:2,4-二硝基苯胺,99%(drywt.),cont.upto15%water 2,4-Dinitroaniline, 99% (dry wt.), cont. up to 15% water(97-02-9)
  • 急性毒性:口服-大鼠 LD50: 285 毫克/公斤; 口服-小鼠 LD50: 370 毫克/公斤
  • 用途一:用于制造偶氮染料及分散染料，也可用作印刷油墨的调色剂和制取防腐剂等
  • TCI Shanghai:2,4-二硝基苯胺 2,4-Dinitroaniline,>;99.0%(GC)(97-02-9)
  • 灭火剂:雾状水、泡沫、二氧化碳、干粉、砂土。
  • 用途三:用作偶氮染料中间体，腐蚀抑制剂，分析试剂。检验酚和某些不饱和烃，有机合成。
  • MOL 文件:97-02-9.mol
  • 海关编码:29214210
  • 可燃性危险特性:明火可燃; 高热分解有毒氮氧化物烟雾;与氧化剂反应
  • 下游产品:分散兰 79 --> 2-溴-4,6-二硝基苯胺 --> 4-硝基邻苯二胺 --> 颜料橙 5 --> 硫化黄9 --> N-(2,4-二硝基苯基)乙酰胺
  • 与稀无机酸不能形成盐类。溶于乙醚等许多有机溶剂，微溶于乙醇、沸水，溶解度:0.06 g/l 水(20 C)，0.7% 乙醇 (21 C).溶于热盐酸，几乎不溶于冷水。中等毒，半数致死量(大鼠，经口)418mg/kg。有刺激性。 商品常含15%水润湿。
  • 毒性分级:高毒
  • MSDS 信息:2,4-二硝基苯胺(97-02-9).msds
  • Acros Organics:2，4-硝基苯胺 2,4-Dinitroaniline, 99%(97-02-9)
  • Sigma Aldrich:97-02-9(sigmaaldrich)
  • 2,4-二硝基苯胺价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2011/08/23 80054524 2，4-二硝基苯胺;1-氨基-2,4-二硝基苯 25g 18元 2011/08/23 80054560 2，4-二硝基苯胺;1-氨基-2,4-二硝基苯 25g 20元 2011/04/16 D0814 2,4-二硝基苯胺 2,4-Dinitroaniline 25G 124元
  • 职业标准:STEL 0.3 毫克/立方米
  • 外观性质:黄色针状结晶。
  • 用途二:该品是分散染料、中性染料、硫化染料、有机颜料的中间体。用于生产硫化深蓝3R、分散红B、分散紫2R等染料。也用于其他有机合成，生产农药二硝散等，以及用作印刷油墨的调色剂和制取防腐剂。

系列性分类

  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Organic Building Blocks 有机砌块
  4. Nitrogen Compounds 氮化合物
  5. Nitro Compounds 硝基化合物
  1. C6 - Amines
  1. C10 - Amines
  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Chemicals by Class 化学分类法
  4. Amines - Chemical Class
  5. Aromatics - Amines
  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Organic Building Blocks 有机砌块
  4. Nitrogen Compounds 氮化合物
  5. Amines 胺
  6. C11 to C38

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