Adipic Dihydrazide 己二酸二酰肼

CAS 1071-93-8 MFCD00007614

化学结构图

1071-93-8
SMILES: NNC(=O)CCCCC(=O)NN

化学属性

Mol. FormulaC6H14N4O2
Mol. Weight174.20
Melting Point180-182°C
TSCAYes
Density1.186
Solubility可溶
Flash Point150°C
Appearance 己二酸二酰肼(1071-93-8)为白色结晶。熔点180-182℃。无色透明，无可视不溶物。
Stability对空气敏感
Boiling Point519.3°C at 760 mmHg

别名和识别编码

Chemical NameAdipic Dihydrazide
CAS Number1071-93-8
Alfabeta NameADIPICACIDDIHYDRAZIDE
MDL NumberMFCD00007614
Beilstein Registry Number973863
PubChem Substance ID66117
EC Number213-999-5
Reaxys-RN973863
Synonym Adipic acid dihydrazide {LY} Adipic acid dihydrazide {} {LY} Adipic acid dihydrazide {} {} {LY} Adipic acid dihydrazide {} {} {} {LY} Adipic acid dihydrazide {} {} {} {} {LY} Adipic acid dihydrazide {} {} {} {} {} {LY} Adipic acid dihydrazide {} {} {} {} {} {} {LY} Adipic acid dihydrazide {} {} {} {} {} {} {} {LY} Adipic acid dihydrazide {} {} {} {} {} {} {} {} {LY} Adipic acid dihydrazide {} {} {} {} {} {} {} {} {} {LY} Adipic acid dihydrazide {} {} {} {} {} {} {} {} {} {} {LY} Adipic acid dihydrazide {} {} {} {} {} {} {} {} {} {} {} {LY} Adipic acid dihydrazide {} {} {} {} {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {} {} {} {} {LY} Adipic acid dihydrazide {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Adipic acid dihydrazide {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Adipic acid dihydrazide {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Adipic acid dihydrazide {} {} {} {} {} {} {} {} {} {} {} {} {} {} {
Chemical Name Translation己二酸二酰肼
LabNetwork Molecule IDLN00159787
InChIInChI=1S/C6H14N4O2/c7-9-5(11)3-1-2-4-6(12)10-8/h1-4,7-8H2,(H,9,11)(H,10,12)
Canonical SMILESO=C(NN)CCCCC(NN)=O
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分类

  • {SNA} Aldehyde Reactive Fluorophores and Labels, Chemical Biology,
  • {SNA} Aldehyde Reactive Fluorophores and Labels, Chemical Biology, Chemical Synthesis, Conjugation Chemistry: Azides, Alkynes and Other Reagents, Crosslinkers, Crosslinking, Homobifunctional Cross-Linking Reagents, Linkers and Crosslinkers, Protein Modification, 分子生物学, 蛋白质组学, 蛋白质结构分析
  • {SNA} Chemical Biology, Chemical Synthesis, Crosslinkers, Crosslinking, Homobifunctional Cross-Linking Reagents, Linkers and Crosslinkers, Other Reactivities, Protein Modification, 分子生物学, 蛋白质组学,
  • {SNA} Aldehyde Reactive Fluorophores and Labels,
  • {SNA} Chemica

产品应用

  • 同双功能交联试剂，专用于醛，生成相对稳定的腙链接。特别是，用于连接糖蛋白，如抗体。

相关文献及参考

  • 2. Anal. Biochem. 275 , 231, (1999) 摘要
  • Beilstein: 2,IV,1977
  • Beil. 2 ,IV,1977

安全信息

Warnings IRRITANT
Personal Protective Equipment Eyeshields, Gloves, type N95 (US), type P1 (EN143) respirator filter
WGK Germany3
RTECSAV1400000
Signal word Warning
Precautionary statements
  • P201 Obtain special instructions before use. 使用前获取专门指示。
  • P202 Do not handle until all safety precautions have been read and understood. 已阅读并理解所有的安全预防措施之前，切勿操作。
  • P260 Do not breathe dust/fume/gas/mist/vapours/spray. 不要吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P262 Do not get in eyes, on skin, or on clothing. 不要接触眼睛，皮肤或衣服。
  • P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
  • P272 Contaminated work clothing should not be allowed out of the workplace. 污染的工作服不得带出工作场所。
  • P273 Avoid release to the environment. 避免释放到环境中。
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P281 Use personal protective equipment as required. 使用所需的个人防护装备。
  • P302+P350
  • P302+P352
  • P302+P352+P332+P313+P362+P364
  • P305+P351+P338
  • P305+P351+P338+P337+P313
  • P308+P313
  • P321 Specific treatment (see … on this label). 具体治疗（见本标签上的）。
  • P332+P313
  • P333+P313
  • P337+P313
  • P362 Take off contaminated clothing and wash before reuse. 脱掉污染的衣服，清洗后方可重新使用
  • P363 Wash contaminated clothing before reuse. 被污染的衣服洗净后方可重新使用。
  • P391 Collect spillage. Hazardous to the aquatic environment 收集对水环境有危害的泄漏物。
  • P405 Store locked up. 上锁保管。
  • P501 Dispose of contents/container to..… 处理内容物/容器.....
Hazard statements
  • H315 Causes skin irritation 会刺激皮肤
  • H317 May cause an allergic skin reaction 可能导致皮肤过敏
  • H411 Toxictoaquaticlifewithlonglastingeffects 对水生生物有毒性并具有长期影响。
Safety Statements
  • S22 Do not breathe dust 不要吸入粉尘；
  • S24/25 Avoid contact with skin and eyes 避免皮肤和眼睛接触；
  • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后，立即用大量水冲洗并征求医生意见；
  • S36/37/39 Wear suitable protective clothing, gloves and eye/face protection 穿戴适当的防护服、手套和眼睛/面保护；
  • S37 Wear suitable gloves 戴适当手套；
  • S60 This material and its container must be disposed of as hazardous waste 该物质及其容器必须作为危险废物处置；
Risk Statements
  • R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
GHS Symbol
Hazard Codes Xi
Storage condition Store at room temperature, keep dry and cool {LY} Store at room temperature, keep dry and cool {} {LY} Store at room temperature, keep dry and cool {} {} {LY} Store at room temperature, keep dry and cool {} {} {} {LY} Store at room temperature, keep dry and cool {} {} {} {} {LY} Store at room temperature, keep dry and cool {} {} {} {} {} {LY} Store at room temperature, keep dry and cool {} {} {} {} {} {} {LY} Store at room temperature, keep dry and cool {} {} {} {} {} {} {} {LY} Store at room temperature, keep dry and cool {} {} {} {} {} {} {} {} {LY} Store at room temperature, keep dry and cool {} {} {} {} {} {} {} {} {} {LY} Store at room temperature, keep dry and cool {} {} {} {} {} {} {} {} {} {} {LY} Store at room temperature, keep dry and cool {} {} {} {} {} {} {} {} {} {} {} {LY} Store at room temperature, keep dry and cool {} {} {} {} {} {} {} {} {} {} {} {} {LY} Store at room temperature, keep dry and cool {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Store

其他信息

  • 用途二:同双功能交联试剂，专用于醛，生成相对稳定的腙链接。特别是，用于连接糖蛋白，如抗体。
  • 己二酸二酰肼价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2014/06/02 A0170 己二酸二酰肼 Adipic Dihydrazide 250G 690元 2014/06/02 A0170 己二酸二酰肼 Adipic Dihydrazide 25G 180元 2010/06/21 203310250 己二酸二酰肼 Adipic dihydrazide 98% 25 GR 596元
  • Acros Organics:己二酰二肼 Adipic dihydrazide, 98%(1071-93-8)
  • TCI Shanghai:己二酸二酰肼 Adipic Dihydrazide,>;98.0%(T)(1071-93-8)
  • 急性毒性:非肠-大鼠 LDL0: 4000 毫克/公斤
  • 图谱信息:己二酸二酰肼(1071-93-8)核磁图( 1 HNMR) 己二酸二酰肼(1071-93-8)红外图谱(IR1) 己二酸二酰肼(1071-93-8)核磁图( 13 CNMR) 己二酸二酰肼(1071-93-8)质谱(MS) 己二酸二酰肼(1071-93-8)红外图谱(IR2)
  • 毒性分级:中毒
  • 用途一:主要用于环氧粉末涂料固化剂及涂料助剂，金属减活剂等其他高分子助剂及水处理剂
  • MSDS 信息:Hexanedioic acid dihydrazide(1071-93-8).msds
  • Hazard Note:Irritant
  • 储运特性:库房通风低温干燥; 与食品原料分开存放
  • 灭火剂:干粉、泡沫、砂土、二氧化碳, 雾状水
  • 海关编码:29280090
  • 溶于水，溶于乙酸，微溶于丙酮；不溶于乙醇、乙醚和苯
  • Alfa Aesar:己二酸二酰肼,97% Adipic dihydrazide, 97%(1071-93-8)
  • MOL 文件:1071-93-8.mol
  • 可燃性危险特性:可燃; 燃烧释放有毒氮氧化物烟雾
  • Sigma Aldrich:1071-93-8(sigmaaldrich)
  • 类别:有毒物品

系列性分类

  1. Chemical Synthesis 化学合成
  2. Chemical Biology 生物化学
  3. Peptide Chemistry 多肽化学
  4. Linkers - Peptide Chemistry
  5. Crosslinkers - Linkers and Crosslinkers
  1. Life Science 生命科学
  2. Proteomics 蛋白质组学
  3. Protein Structural Analysis - Proteomics
  4. Protein Modification - Protein Structural Analysis
  5. Crosslinking - Protein Modification
  6. Homobifunctional Cross-Linking Reagents - Crosslinking
  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Organic Building Blocks 有机砌块
  4. Carbonyl Compounds 羰基化合物
  5. Hydrazides - Carbonyl Compounds
  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Organic Building Blocks 有机砌块
  4. Carbonyl Compounds 羰基化合物
  5. Hydrazides - Carbonyl Compounds
  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Organic Building Blocks 有机砌块
  4. Nitrogen Compounds 氮化合物
  5. Hydrazines - Nitrogen Compounds
  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Organic Building Blocks 有机砌块
  4. Carbonyl Compounds 羰基化合物
  5. Esters
  6. C8 to C9
  1. Life Science 生命科学
  2. Biochemicals and Reagents
  3. Proteomics
  4. Protein Structural Analysis
  5. Protein Modification

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