Octadecylamine 十八胺

CAS 124-30-1 MFCD00008159

化学结构图

124-30-1
SMILES: CCCCCCCCCCCCCCCCCCN

化学属性

Mol. FormulaC18H39N
Mol. Weight269.52
Density0.86
Boiling Point232°C at 760 mmHg
Vapor Pressure10 mmHg ( 72 °C)
Melting Point50-52°C
Flash Point148°C
TSCAYes
Solubility难溶
Refractive index1.4522

别名和识别编码

Chemical NameOctadecylamine
Synonym Octadecan-1-amine,mixtures {LY} Octadecan-1-amine,mixtures {} {LY} Octadecan-1-amine,mixtures {} {} {LY} Octadecan-1-amine,mixtures {} {} {} {LY} Octadecan-1-amine,mixtures {} {} {} {} {LY} Octadecan-1-amine,mixtures {} {} {} {} {} {LY} Octadecan-1-amine,mixtures {} {} {} {} {} {} {LY} Octadecan-1-amine,mixtures {} {} {} {} {} {} {} {LY} Octadecan-1-amine,mixtures {} {} {} {} {} {} {} {} {LY} Octadecan-1-amine,mixtures {} {} {} {} {} {} {} {} {} {LY} Octadecan-1-amine,mixtures {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Octadecan-1-amine,mixtures {} {} {} {} {} {} {} {} {} {} {} {LY} Octadecan-1-amine,mixtures {} {} {} {} {} {} {} {} {} {} {} {} {LY} Octadecan-1-amine,mixtures {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Octadecan-1-amine,mixtures {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Octadecan-1-amine,mixtures {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {}
CAS Number124-30-1
EC Number204-695-3
Beilstein Registry Number636111
MDL NumberMFCD00008159
PubChem Substance ID15793
Reaxys-RN636111
Chemical Name Translation十八胺
Wiswesser Line NotationZ18
LabNetwork Molecule IDLN00193031
InChIInChI=1S/C18H39N/c1-2-3-4-5-6-7-8-9-10-11-12-13-14-15-16-17-18-19/h2-19H2,1H3
Canonical SMILESCCCCCCCCCCCCCCCCCCN
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分类

  • {SNA} Amines, Building Blocks, C15 to C19, Chemical Synthesis, Nitrogen Compounds, Organic Building Blocks
  • {uni_hamburg} no charge; 1fragment

产品应用

  • 有机合成。缓蚀剂。乳化剂。杀菌剂。

相关文献及参考

  • Short: LC
  • Short: III/38B
  • Short: IV/20C
  • Short: EINECS
  • Short: IV/6
  • Beilstein:4(4)825

安全信息

Signal word Danger
GHS Symbol
WGK Germany3
Safety Statements
  • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后,立即用大量水冲洗并征求医生意见;
  • S28 After contact with skin, wash immediately with plenty of ... (to be specified by the manufacturer) 皮肤接触后,立即用大量…(由生产厂家指定)冲洗;
  • S36 Wear suitable protective clothing 穿戴适当的防护服;
  • S36/37/39 Wear suitable protective clothing, gloves and eye/face protection 穿戴适当的防护服、手套和眼睛/面保护;
  • S37/39 Wear suitable gloves and eye/face protection 穿戴适当的手套和眼睛/面保护;
Risk Statements
  • R22 Harmful if swallowed 吞咽有害
  • R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
  • R38 Irritating to skin 刺激皮肤
  • R41 Risk of serious damage to eyes 有严重损伤眼睛的危险
  • R48/22
  • R50/53
  • R65 Harmful: may cause lung damage if swallowed 若吞咽可能伤害肺部器官
Precautionary statements
  • P260 Do not breathe dust/fume/gas/mist/vapours/spray. 不要吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
  • P270 Do not eat, drink or smoke when using this product. 使用本产品时不要吃东西,喝水或吸烟。
  • P271 Use only outdoors or in a well-ventilated area.? 只能在室外或通风良好的地方使用。
  • P273 Avoid release to the environment. 避免释放到环境中。
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P301+P310
  • P301+P310+P331+P330
  • P301+P312
  • P301+P330+P331
  • P302+P350
  • P302+P352
  • P302+P352+P332+P313+P362+P364
  • P303+P361+P353
  • P304+P340
  • P304+P340+P312
  • P305+P351+P338
  • P305+P351+P338+P310
  • P310 Immediately call a POISON CENTER or doctor/physician. 立即呼救解毒中心或医生/医师。
  • P312 Call a POISON CENTER or doctor/physician if you feel unwell. 如果你感觉不适,呼叫解毒中心或医生/医师。
  • P314 Get medical advice/attention if you feel unwell. 获取医疗咨询/就医,如果你觉得不舒服
  • P321 Specific treatment (see … on this label). 具体治疗(见本标签上的)。
  • P330 Rinse mouth. 漱口
  • P331 Do NOT induce vomiting.. 不要催吐。
  • P332+P313
  • P337+P313
  • P362 Take off contaminated clothing and wash before reuse. 脱掉污染的衣服,清洗后方可重新使用
  • P363 Wash contaminated clothing before reuse. 被污染的衣服洗净后方可重新使用。
  • P391 Collect spillage. Hazardous to the aquatic environment 收集对水环境有危害的泄漏物。
  • P403+P233
  • P405 Store locked up. 上锁保管。
  • P501 Dispose of contents/container to..… 处理内容物/容器.....
Hazard statements
  • H302 Harmful if swallowed 吞食有害
  • H303 May be harmfully swallowed 吞食可能有害
  • H304 May be fatal if swallowed and enters airways 吞食和进入呼吸道可能致命
  • H314 Causes severe skin burns and eye damage 导致严重的皮肤灼伤和眼睛损伤
  • H315 Causes skin irritation 会刺激皮肤
  • H318 Causes serious eye damage 严重伤害眼睛
  • H319 Causes serious eye irritation 严重刺激眼睛
  • H335 May cause respiratory irritation 可能导致呼吸道刺激
  • H373 May causes damage to organs through prolonged or repeated exposure 长期或频繁接触可能会损伤器官
  • H400 Verytoxictoaquaticlife 对水生生物毒性非常大。
  • H410 Verytoxictoaquaticlifewithlonglastingeffects 对水生生物毒性非常大并具有长期影响。
Personal Protective Equipment dust mask type N95 (US), Eyeshields, Gloves
RTECSRG4150000
Hazard Codes Xi Xn,N
Packing GroupIII
Storage condition 2-8°C, protect from light {LY} 2-8°C, protect from light {} {LY} 2-8°C, protect from light {} {} {LY} 2-8°C, protect from light {} {} {} {LY} 2-8°C, protect from light {} {} {} {} {LY} 2-8°C, protect from light {} {} {} {} {} {LY} 2-8°C, protect from light {} {} {} {} {} {} {LY} 2-8°C, protect from light {} {} {} {} {} {} {} {LY} 2-8°C, protect from light {} {} {} {} {} {} {} {} {LY} 2-8°C, protect from light {} {} {} {} {} {} {} {} {} {LY} 2-8°C, protect from light {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, protect from light {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, protect from light {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, protect from light {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, protect from light {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, protect from light {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, protect from light {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {}
Hazard Class9
UN Number 3077 3259
TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Rodent - rat
DOSE/DURATION           : 2395 mg/kg
TOXIC EFFECTS :
   Behavioral - somnolence (general depressed activity)
REFERENCE :
   GISAAA Gigiena i Sanitariya.  For English translation, see HYSAAV.  (V/O
   Mezhdunarodnaya Kniga, 113095 Moscow, USSR)  V.1-    1936-
   Volume(issue)/page/year: 38(11),31,1973

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Intraperitoneal
SPECIES OBSERVED        : Rodent - mouse
DOSE/DURATION           : 250 mg/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   NTIS** National Technical Information Service.  (Springfield, VA 22161)
   Formerly U.S. Clearinghouse for Scientific & Technical Information.
   Volume(issue)/page/year: AD691-490

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Rodent - mouse
DOSE/DURATION           : 3 gm/kg
TOXIC EFFECTS :
   Behavioral - somnolence (general depressed activity)
REFERENCE :
   GISAAA Gigiena i Sanitariya.  For English translation, see HYSAAV.  (V/O
   Mezhdunarodnaya Kniga, 113095 Moscow, USSR)  V.1-    1936-
   Volume(issue)/page/year: 38(11),31,1973

其他信息

  • 用途一:用于制彩色照片的成色剂,用作树脂、乳化剂、杀菌剂、表面活性剂的原料及纺织
  • Acros Organics:十八胺 Octadecylamine, tech., 90%(124-30-1)
  • {Che
  • 图谱信息:十八胺(124-30-1)质谱(MS) 十八胺(124-30-1)红外图谱(IR3) 十八胺(124-30-1)核磁图( 13 CNMR) 十八胺(124-30-1)红外图谱(IR1) 十八胺(124-30-1)红外图谱(IR2)
  • 外观:白色至浅黄色片状固体。
  • 硬脂胺:硬脂胺又名十八胺、1-氨基十八烷,是在工业上大量生产的脂肪族胺类化合物,常温下为白色结晶,分子量269.52。熔点52.8612。沸点23212(4.27千帕)。闪点149℃。相对密度0.8618。折射率1.4522。微溶于丙酮、煤油和甲醇,易溶于四氯化碳、氯仿、乙醇、异丙醇和甲苯,溶于醇、醚、苯,不溶于水。具碱性。能与盐酸生成加成物。毒性低于低级胺,大鼠口服500×10-6硬脂胺,连续两年,未呈现明显不良后果。对人体皮肤和粘膜有刺激性。用作有机合成中间体,用于生产十八烷季胺盐及多种助剂。例如阳离子润滑脂的稠化剂、矿物浮选剂、合成树脂、农药和沥青等的乳化剂、织物抗静电剂、湿润剂、防水剂、表面活性剂、杀菌剂、彩色照片的成色剂、炼油装置的缓蚀剂。由硬脂酸与氨反应生成十八腈,再经压力下催化加氢,进一步将烯胺还原制得。
  • 防护措施:本品属高级烷基胺,毒性比低级烷基胺小。根据长期喂养研究,在老鼠食物中喂0.0005的1-十八(烷)胺两年没有明显不利健康的后果,而以同样量喂狗十二个月则对胃肠系统粘液也无病理影响。本品对皮肤和粘膜有刺激性。勿与皮肤接触。防止设备泄漏,操作人员佩戴防护用具。
  • 产品分类:化肥,火工产品抗结快剂,矿物浮选剂,沥青乳化剂,纺织,润滑油助剂,表面活性剂的原料
  • 对二氧化碳敏感。易溶于氯仿,溶于乙醇、乙醚和苯,微溶于丙酮,不溶于水。
  • 方法一:由硬脂酸氨化、加氢而得。将硬脂酸和氨连续定量地送入液相反应塔内,于350℃下氨化生成十八烷腈。经水洗精制后加入高压釜内,于130℃、约3.5MPa压力下,在镍催化剂作用下加氢生成十八胺。加氢产物经沉淀除去催化剂即得成品。在实验室制备中,将十八烷腈和无水乙醇煮沸回流,投入金属钠反应。将反应混合物倾入稀盐酸内,冷却得到十八胺盐酸盐,再用20%氢氧化钠溶液处理,可得十八胺。收率85%。原料消耗定额:硬脂酸1165kg/t、液氨151kg/t、氢气211m3、镍催化剂6kg/t。
  • TCI Shanghai:硬脂胺 Stearylamine,>;80.0%(GC)(124-30-1)
  • 下游产品:氯化钾 --> 硫酸钾 --> 氯化镁 --> 氯化镁(六水合物) --> 十八烷基二甲基叔胺 --> 柔软剂HC --> 溶剂黄 98 --> 3-[N,N-二甲基,N-十八烷基]铵基,2-羟基丙磺酸盐 --> 季铵化聚酯 --> 抗静电剂SN --> 柔软剂D3 --> 柔软剂DMD --> 异氰酸十八酯 --> 十八烷基二甲基苄基氯化铵 --> 十八烷基三甲基溴化铵 --> 表面活性剂D16-1821
  • 制备匀染剂DC的原料:匀染剂DC的化学名称为十八烷基二甲基苄基氯化铵。常温下淡黄色稠粘状液体,可溶于水,0.1%水溶液pH值5.2~5.5,能耐硬水、无机盐和酸,但不耐碱。本品为阳离子型,对腈纶纤维有较强的亲和力,对阳离子染料染色有良好的匀染性。主要用作阳离子染料在各种腈纶纤维染色时匀染剂,并赋予良好的手感。用量
  • {Chemica
  • Alfa Aesar:1-十八胺,98% 1-Octadecylamine, 98%(124-30-1)
  • 制备匀染剂DC的原料:匀染剂DC的化学名称为十八烷基二甲基苄基氯化铵。常温下淡黄色稠粘状液体,可溶于水,0.1%水溶液pH值5.2~5.5,能耐硬水、无机盐和酸,但不耐碱。本品为阳离子型,对腈纶纤维有较强的亲和力,对阳离子染料染色有良好的匀染性。主要用作阳离子染料在各种腈纶纤维染色时匀染剂,并赋予良好的手感。用量一般浅色为2%~3% (织物重量),深色时0.8%~1.5%。 本品也可作醋酸纤维的柔软整理剂,亦可作消毒杀菌剂。由十八胺通过甲基化反应再与苄基氯反应而制得。

系列性分类


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