1-Hexadecylamine 十六胺

CAS 143-27-1 MFCD00008158

化学结构图

143-27-1
SMILES: CCCCCCCCCCCCCCCCN

化学属性

Mol. FormulaC16H35N
Mol. Weight241.46
Density0.813
Boiling Point330 °C at 760 mmHg
Vapor Pressure<;1 mmHg ( 20 °C)
Melting Point43-45 °C
Refractive index1.4496
Flash Point140°(284°F)
TSCAYes
Solubility不溶
Appearance 白色片状结晶。熔点46.77℃,沸点332.5℃,187(2.0kPa)177.9℃(1.33kPa),162-165℃(0.69kPa),相对密度0.8129(20/4℃),折光率1.4496,闪点140℃。溶于乙醇、乙醚、丙酮、苯和氯仿,不溶于水。可吸收二氯化碳。

别名和识别编码

Chemical Name1-Hexadecylamine
Synonym Cetylamine {LY} Cetylamine {} {LY} Cetylamine {} {} {LY} Cetylamine {} {} {} {LY} Cetylamine {} {} {} {} {LY} Cetylamine {} {} {} {} {} {LY} Cetylamine {} {} {} {} {} {} {LY} Cetylamine {} {} {} {} {} {} {} {LY} Cetylamine {} {} {} {} {} {} {} {} {LY} Cetylamine {} {} {} {} {} {} {} {} {} {LY} Cetylamine {} {} {} {} {} {} {} {} {} {} {LY} Cetylamine {} {} {} {} {} {} {} {} {} {} {} {LY} Cetylamine {} {} {} {} {} {} {} {} {} {} {} {} {LY} Cetylamine {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Cetylamine {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Cetylamine {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Cetylamine {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Cetylamine {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Cetylamine
CAS Number143-27-1
EC Number205-596-8
Beilstein Registry Number4,202
MDL NumberMFCD00008158
PubChem Substance ID8926
Chemical Name Translation十六胺
Reaxys-RN1634065
Wiswesser Line NotationZ16
LabNetwork Molecule IDLN00223429
InChIInChI=1S/C16H35N/c1-2-3-4-5-6-7-8-9-10-11-12-13-14-15-16-17/h2-17H2,1H3
Canonical SMILESCCCCCCCCCCCCCCCCN
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分类

  • {SNA} Amines, Building Blocks, C15 to C19, Chemical Synthesis, Nitrogen Compounds, Organic Building Blocks
  • {uni_hamburg} no charge; 1fragment

产品应用

  • 用于制取树脂;杀虫剂和高级洗涤剂。

相关文献及参考

  • Short: IV/20C
  • Short: IV/6
  • Short: IV/8I
  • Short: III/38B
  • Beilstein:4,202

安全信息

Signal word Danger
GHS Symbol
WGK Germany3
Safety Statements
  • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后,立即用大量水冲洗并征求医生意见;
  • S36/37/39 Wear suitable protective clothing, gloves and eye/face protection 穿戴适当的防护服、手套和眼睛/面保护;
  • S45 In case of accident or if you feel unwell seek medical advice immediately (show the label where possible) 发生事故时或感觉不适时,立即求医(可能时出示标签);
Risk Statements
  • R34 Causes burns 会导致灼伤
Precautionary statements
  • P260 Do not breathe dust/fume/gas/mist/vapours/spray. 不要吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
  • P270 Do not eat, drink or smoke when using this product. 使用本产品时不要吃东西,喝水或吸烟。
  • P273 Avoid release to the environment. 避免释放到环境中。
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P301+P310
  • P301+P312
  • P301+P330+P331
  • P301+P330+P331+P310
  • P303+P361+P353
  • P303+P361+P353+P310+P363
  • P304+P340
  • P304+P340+P310
  • P305+P351+P338
  • P305+P351+P338+P310
  • P310 Immediately call a POISON CENTER or doctor/physician. 立即呼救解毒中心或医生/医师。
  • P314 Get medical advice/attention if you feel unwell. 获取医疗咨询/就医,如果你觉得不舒服
  • P321 Specific treatment (see … on this label). 具体治疗(见本标签上的)。
  • P330 Rinse mouth. 漱口
  • P331 Do NOT induce vomiting.. 不要催吐。
  • P363 Wash contaminated clothing before reuse. 被污染的衣服洗净后方可重新使用。
  • P391 Collect spillage. Hazardous to the aquatic environment 收集对水环境有危害的泄漏物。
  • P405 Store locked up. 上锁保管。
  • P501 Dispose of contents/container to..… 处理内容物/容器.....
Hazard statements
  • H302 Harmful if swallowed 吞食有害
  • H304 May be fatal if swallowed and enters airways 吞食和进入呼吸道可能致命
  • H314 Causes severe skin burns and eye damage 导致严重的皮肤灼伤和眼睛损伤
  • H318 Causes serious eye damage 严重伤害眼睛
  • H373 May causes damage to organs through prolonged or repeated exposure 长期或频繁接触可能会损伤器官
  • H400 Verytoxictoaquaticlife 对水生生物毒性非常大。
  • H410 Verytoxictoaquaticlifewithlonglastingeffects 对水生生物毒性非常大并具有长期影响。
Personal Protective Equipment Eyeshields, Faceshields, full-face particle respirator type N100 (US), Gloves, respirator cartridge type N100 (US), type P1 (EN143) respirator filter, type P3 (EN 143) respirator cartridges
RTECSML9100000
Packing GroupII
UN Number 3259
Hazard Codes C
Hazard Class8
TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Intraperitoneal
SPECIES OBSERVED        : Rodent - mouse
DOSE/DURATION           : 200 mg/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   NTIS** National Technical Information Service.  (Springfield, VA 22161)
   Formerly U.S. Clearinghouse for Scientific & Technical Information.
   Volume(issue)/page/year: AD691-490

TYPE OF TEST            : TDLo - Lowest published toxic dose
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Rodent - mouse
DOSE                    : 40 mg/kg
SEX/DURATION            : female 9 day(s) after conception
TOXIC EFFECTS :
   Reproductive - Fertility - post-implantation mortality (e.g. dead and/or
   resorbed implants per total number of implants)
   Reproductive - Specific Developmental Abnormalities - other developmental
   abnormalities
REFERENCE :
   DZZEA7 Deutsche Zahnaerztliche Zeitschrift.  (Carl Hanser Verlag, Postfach
   860420, D-8000 Munich 86, Fed. Rep. Ger.)  V.1-    1946-
   Volume(issue)/page/year: 32,861,1977

TYPE OF TEST            : TDLo - Lowest published toxic dose
ROUTE OF EXPOSURE       : Intraperitoneal
SPECIES OBSERVED        : Rodent - mouse
DOSE                    : 10 mg/kg
SEX/DURATION            : female 9 day(s) after conception
TOXIC EFFECTS :
   Reproductive - Fertility - post-implantation mortality (e.g. dead and/or
   resorbed implants per total number of implants)
   Reproductive - Specific Developmental Abnormalities - other developmental
   abnormalities
REFERENCE :
   DZZEA7 Deutsche Zahnaerztliche Zeitschrift.  (Carl Hanser Verlag, Postfach
   860420, D-8000 Munich 86, Fed. Rep. Ger.)  V.1-    1946-
   Volume(issue)/page/year: 32,861,1977

Storage condition 2-8°C, protect from light {LY} 2-8°C, protect from light {} {LY} 2-8°C, protect from light {} {} {LY} 2-8°C, protect from light {} {} {} {LY} 2-8°C, protect from light {} {} {} {} {LY} 2-8°C, protect from light {} {} {} {} {} {LY} 2-8°C, protect from light {} {} {} {} {} {} {LY} 2-8°C, protect from light {} {} {} {} {} {} {} {LY} 2-8°C, protect from light {} {} {} {} {} {} {} {} {LY} 2-8°C, protect from light {} {} {} {} {} {} {} {} {} {LY} 2-8°C, protect from light {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, protect from light {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, protect from light {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, protect from light {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, protect from light {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, protect from light {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, protect from light {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {}

其他信息

  • 上游原料:稀盐酸 --> 氧化钠
  • F:34
  • MSDS 信息:1-Hexadecylamine(143-27-1).msds
  • 十六胺价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2011/08/23 LB2245901 正十六胺, 95% 25g 197元 2011/04/16 H0074 十六胺 Hexadecylamine 25G 146元 2011/04/16 H0074 十六胺 Hexadecylamine 500G 451元
  • TCI Shanghai:十六胺 Hexadecylamine,>;90.0%(GC)(143-27-1)
  • Sigma Aldrich:143-27-1(sigmaaldrich)
  • 下游产品:3-磺丙基十六烷基二甲基铵
  • 用途一:用于纤维助剂、化肥抗结块剂、浮选剂等
  • 海关编码:29211980
  • 图谱信息:十六胺(143-27-1)核磁图( 1 HNMR) 十六胺(143-27-1)质谱(MS) 十六胺(143-27-1)红外图谱(IR1) 十六胺(143-27-1)红外图谱(IR2) 十六胺(143-27-1)核磁图( 13 CNMR) 十六胺(143-27-1)红外图谱(IR3)
  • Acros Organics:十六胺 1-Hexadecylamine, 90%(143-27-1)
  • 方法一:由棕榈脯经还原而得。将3份棕榈脯溶于30份无水乙醇中,慢慢加入金属钠4份进行还原。反应放热,使反应物呈液体状态。当加入的金属钠只能部分溶解时,可加热至60℃,并逐渐升温至120℃,始终使金属钠不全部消失。反应完全后趁热倾入水中,加入稍过量的盐酸,将生成的十六胺盐酸盐结晶滤出,用少量稀盐酸洗涤后压干。将此盐酸用20%氯氧化钠碱化,减压蒸馏,得十六胺。
  • MOL 文件:143-27-1.mol
  • 蒸气压:<;1 mm Hg ( 20 °C)
  • 溶于乙醇;乙醚;丙酮;苯和氯仿,不溶于水。可吸收二氯化碳。 不溶于水,溶于乙醇和乙醚中。与盐酸生成十六胺盐酸盐。
  • Alfa Aesar:1-十六胺,tech.90%,remaindermainly1-Octadecylamine 1-Hexadecylamine, tech. 90%, remainder mainly 1-octadecylamine(143-27-1)
  • 用途三:用于制取树脂;杀虫剂和高级洗涤剂。
  • 用途二:用于制取树脂、杀虫剂和高级洗涤剂。

系列性分类


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