N,N’-Dimethylethylenediamine N,N’-二甲基乙二胺
CAS 110-70-3 MFCD00008290
化学结构图
SMILES: CNCCNC
化学属性
| Mol. Formula | C4H12N2 |
|---|---|
| Mol. Weight | 88.15 |
| Refractive index | 1.4270 to 1.4310 |
| Boiling Point | 120°C at 760 mmHg |
| Density | 0.819 |
| Flash Point | 26°C |
| TSCA | Yes |
| Melting Point | 1.63 °C |
别名和识别编码
| Chemical Name | N,N’-Dimethylethylenediamine |
|---|---|
| CAS Number | 110-70-3 |
| Alfabeta Name | DIMETHYLETHYLENEDIAMINE NN-,' |
| MDL Number | MFCD00008290 |
| Synonym | N,N'-Dimethylethylenediamine {LY} N,N'-Dimethylethylenediamine {} {LY} N,N'-Dimethylethylenediamine {} {} {LY} N,N'-Dimethylethylenediamine {} {} {} {LY} N,N'-Dimethylethylenediamine {} {} {} {} {LY} N,N'-Dimethylethylenediamine {} {} {} {} {} {LY} N,N'-Dimethylethylenediamine {} {} {} {} {} {} {LY} N,N'-Dimethylethylenediamine {} {} {} {} {} {} {} {LY} N,N'-Dimethylethylenediamine {} {} {} {} {} {} {} {} {LY} N,N'-Dimethylethylenediamine {} {} {} {} {} {} {} {} {} {LY} N,N'-Dimethylethylenediamine {} {} {} {} {} {} {} {} {} {} {LY} N,N'-Dimethylethylenediamine {} {} {} {} {} {} {} {} {} {} {} {LY} N,N'-Dimethylethylenediamine {} {} {} {} {} {} {} {} {} {} {} {} {LY} N,N'-Dimethylethylenediamine {} {} {} {} {} {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} N,N'-Dimethylethylenediamine {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} N,N'-Dimethylethylenediamine {} {} {} {} {} {} {} {} {} {} {} {} {} |
| PubChem Substance ID | 8070 |
| EC Number | 203-793-3 |
| Beilstein Registry Number | 878142 |
| Reaxys-RN | 878142 |
| Chemical Name Translation | N,N’-二甲基乙二胺 |
| Wiswesser Line Notation | 1M2M1 |
| LabNetwork Molecule ID | LN00110554 |
| InChIKey | KVKFRMCSXWQSNT-UHFFFAOYSA-N |
| InChI | InChI=1S/C4H12N2/c1-5-3-4-6-2/h5-6H,3-4H2,1-2H3 |
| Canonical SMILES | CNCCNC |
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分类
- {uni_hamburg} no charge; 1fragment
- {SNA} Building Blocks, Chemical Reagents, Chemical Synthesis, Development Quantities for Research, Nitrogen Compounds, Organic Building Blocks, Polyamines
- Building Blocks, Chemical Synthesis, Nitrogen Compounds, Organic Building Blocks, Polyamines
- {SNA} Building Blocks, Chemical Synthesis, Nitrogen Compounds, Organic Building Blocks, Polyamines
相关文献及参考
- Reagent for protection of aldehyde groups as 2-substituted-1,3-dimethylimidazolidines, e.g. by azeotropic dehydration with benzene. The derivatives are stable to n-BuLi and LDA, and can be cleaved by acid hydrolysis, or in high yield by quaternization with MeI and mild hydrolysis: Tetrahedron, 41, 3803 (1985). With aromatic aldehydes, the imidazolidine derivatives are activated to ortho-lithiation, providing a route to o-substituted benzaldehydes: J. Org. Chem., 44, 2004 (1979).
- Short: EINECS
- Beilstein:4,250
- Short: III/38B
安全信息
GHS Symbol
- H226 Flammable liquid and vapour 易燃液体和蒸气
- H314 Causes severe skin burns and eye damage 导致严重的皮肤灼伤和眼睛损伤
- P210 Keep away from heat/sparks/open flames/hot surfaces. — No smoking. 远离热源/火花/明火/热的表面。——禁止吸烟。
- P233 Keep container tightly closed. ?保持容器密闭。
- P240 Ground/bond container and receiving equipment. 与地面接触/连接集装箱和接受设备。
- P241+P242+P243
- P260 Do not breathe dust/fume/gas/mist/vapours/spray. 不要吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
- P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
- P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
- P301+P330+P331+P310
- P303+P361+P353+P310+P363
- P304+P340
- P304+P340+P310
- P305+P351+P338
- P305+P351+P338+P310
- P310 Immediately call a POISON CENTER or doctor/physician. 立即呼救解毒中心或医生/医师。
- P314 Get medical advice/attention if you feel unwell. 获取医疗咨询/就医，如果你觉得不舒服
- P370+P378
- P403+P235
- P405 Store locked up. 上锁保管。
- P501 Dispose of contents/container to..… 处理内容物/容器.....
- R10 Flammable 易燃
- R34 Causes burns 会导致灼伤
- R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
- S16 Keep away from sources of ignition - No smoking 远离火源，禁止吸烟；
- S20 When using do not eat or drink 使用时，不得进食，饮水；
- S23 Do not breathe gas/fumes/vapour/spray (appropriate wording to be specified by the manufacturer) 不要吸入气体/烟雾/蒸汽/喷雾；
- S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后，立即用大量水冲洗并征求医生意见；
- S36/37/39 Wear suitable protective clothing, gloves and eye/face protection 穿戴适当的防护服、手套和眼睛/面保护；
- S45 In case of accident or if you feel unwell seek medical advice immediately (show the label where possible) 发生事故时或感觉不适时，立即求医（可能时出示标签）；
- S60 This material and its container must be disposed of as hazardous waste 该物质及其容器必须作为危险废物处置；
TYPE OF TEST : LD50 - Lethal dose, 50 percent kill ROUTE OF EXPOSURE : Intraperitoneal SPECIES OBSERVED : Rodent - mouse DOSE/DURATION : 200 mg/kg TOXIC EFFECTS : Details of toxic effects not reported other than lethal dose value REFERENCE : EJMCA5 European Journal of Medicinal Chemistry--Chimie Therapeutique. (Editions Scientifiques Elsevier, 29 rue Buffon, F-75005, Paris, France) V.9- 1974- Volume(issue)/page/year: 17,235,1982
其他信息
- 用途二:N,N'-二甲基乙二胺（110-70-3）用于生产头孢替安的中间体1-(2-二甲基氨基乙基)-5-巯基四唑。以甲基丙烯酸甲酯和N,N-二甲基乙二胺（110-70-3）为主要原料、二月桂酸二丁基锡为催化剂,合成了一种新型功能单体甲基丙烯酰胺乙基二甲基胺。同时也是合成萘酚萘磺酸酯的原料药。
- 检测方法:GC
- MOL 文件:110-70-3.mol
- 下游产品:2-甲酰基-呋喃-2-甲酸
- 图谱信息:N,N'-二甲基乙二胺(110-70-3)核磁图( 1 HNMR) N,N'-二甲基乙二胺(110-70-3)核磁图( 13 CNMR) N,N'-二甲基乙二胺(110-70-3)质谱(MS) N,N'-二甲基乙二胺(110-70-3)红外图谱(IR1)
- MSDS 信息:N,N'-Dimethyl-1,2-ethanediamine(110-70-3).msds
- TCI Shanghai:N,N'-二甲基乙二胺 N,N'-Dimethylethylenediamine,>;97.0%(GC)(T)(110-70-3)
- 微溶于水，溶于有机溶剂。
- Alfa Aesar:N,N'-二甲基乙二胺,95% N,N'-Dimethylethylenediamine, 95%(110-70-3)
- Acros Organics:N,N'-二甲基乙烯基二胺 N,N'-Dimethylethylenediamine, tech., 85%(110-70-3)
- N,N'-二甲基乙二胺价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2014/06/02 D0720 N,N'-二甲基乙二胺 N,N'-Dimethylethylenediamine 5ML 370元 2014/06/02 D0720 N,N'-二甲基乙二胺 N,N'-Dimethylethylenediamine 25ML 1130元 2010/06/21 116191000 N,N'-二甲基乙二胺 N,N'-Dimethylethylenediamine , tech., 85% 100 GR 2633元
- 存储注意事项:氮气保护
- 外观:无色透明液体
- 用途一:用于有机合成或用作医药中间体
- Sigma Aldrich:110-70-3(sigmaaldrich)
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