4-Bromoveratrole 4-溴黎芦醚
CAS 2859-78-1 MFCD00008381
化学结构图
SMILES: COc1ccc(Br)cc1OC
化学属性
| Mol. Formula | C8H9BrO2 |
|---|---|
| Mol. Weight | 217 |
| Boiling Point | 255-256 |
| TSCA | T |
| Density | 1.509 |
| Refractive index | 1.5710 to 1.5750 |
| Flash Point | 109°C(lit.) |
别名和识别编码
| Chemical Name | 4-Bromoveratrole |
|---|---|
| CAS Number | 2859-78-1 |
| Alfabeta Name | BROMODIMETHOXYBENZENE 134---, |
| MDL Number | MFCD00008381 |
| EC Number | 220-677-8 |
| Beilstein Registry Number | 2046884 |
| Synonym | 4-溴藜芦醚 4-溴-1,2-二甲氧基苯 3,4-DIMETHOXYBROMOBENZENE 4-Brmomveratrole 1-溴-3,4-二甲氧基苯 1-BROMO-3,4-DIMETHOXYBENZENE 4-Bromoveratrol 3,4-Dimethoxyphenyl bromide 4-BROMOCATECHOL DIMETHYL ETHER 1-BROMO-3,4-DIMETHOXYBENZENE / 4-BROMOVERATROLE Bromoveratrole 4-Bromo-2-methoxyanisole 4-溴黎芦醚 4-BROMO-1,2-DIMETHOXYBENZENE 4-溴-1,2-邻苯二甲醚 4-Bromoveratrole98% 3,4-二甲氧基溴苯,97% 1,2-Dimethoxy-5-bromobenzene 4-溴黎芦醚(4-溴-1,2-二甲氧基苯) 3,4-Dimethoxy-1-bromobenzene 4-Bromo-1,2-dimethoxybenzene 3,4-二甲氧基溴苯 1-Bromo-3,4-dimetoxybenzene 4-Bromo-1,2-dimethoxybenzene~3,4-Dimethoxybromobenzene 4-bromo-1,2-dimethoxy-benzen 4-BROMOVERATROLE p-Bromoveratrole |
| PubChem Substance ID | 76114 |
| Chemical Name Translation | 4-溴黎芦醚 |
| Reaxys-RN | 2046884 |
| InChIKey | KBTMGSMZIKLAHN-UHFFFAOYSA-N |
| LabNetwork Molecule ID | LN00006143 |
| InChI | InChI=1S/C8H9BrO2/c1-10-7-4-3-6(9)5-8(7)11-2/h3-5H,1-2H3 |
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分类
- {SNA} Building Blocks, C8, Chemical Synthesis, Ethers, Organic Building Blocks, Oxygen Compounds
相关文献及参考
- Beilstein:6,784
- In the presence of sodamide, displacement by nucleophiles, e.g. anions of secondary amines or nitriles, occurs by an ortho-metallation-benzyne mechanism. The incoming nucleophile adds regioselectively such that the resulting anion is ortho-stabilized by methoxyl: J. Org. Chem., 48, 4397 (1983):
- The derived Grignard reagent has been used in the synthesis of the isoquinoline alkaloid (-)-mesembrine: J. Org. Chem., 60, 6785 (1995).
安全信息
GHS Symbol
- S24/25 Avoid contact with skin and eyes 避免皮肤和眼睛接触；
- R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
- P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
- P262 Do not get in eyes, on skin, or on clothing. 不要接触眼睛，皮肤或衣服。
- P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
- P271 Use only outdoors or in a well-ventilated area.? 只能在室外或通风良好的地方使用。
- P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
- P302+P352
- P304+P340
- P305+P351+P338
- P305+P351+P338+P337+P313
- P312 Call a POISON CENTER or doctor/physician if you feel unwell. 如果你感觉不适，呼叫解毒中心或医生/医师。
- P321 Specific treatment (see … on this label). 具体治疗（见本标签上的）。
- P332+P313
- P337+P313
- P362 Take off contaminated clothing and wash before reuse. 脱掉污染的衣服，清洗后方可重新使用
- P403+P233
- P405 Store locked up. 上锁保管。
- P501 Dispose of contents/container to..… 处理内容物/容器.....
- H315 Causes skin irritation 会刺激皮肤
- H319 Causes serious eye irritation 严重刺激眼睛
- H335 May cause respiratory irritation 可能导致呼吸道刺激
其他信息
- MOL 文件:2859-78-1.mol
- Sigma Aldrich:2859-78-1(sigmaaldrich)
- Alfa Aesar:3,4-二甲氧基溴苯,97% 4-Bromoveratrole, 97%(2859-78-1)
- TSCA:T
- MSDS 信息:4-Bromo-1,2-dimethoxybenzene(2859-78-1).msds
- 海关编码:29093038
- 图谱信息:4-溴黎芦醚(2859-78-1)Raman光谱 4-溴黎芦醚(2859-78-1)质谱(MS) 4-溴黎芦醚(2859-78-1)红外图谱(IR1) 4-溴黎芦醚(2859-78-1)核磁图( 13 CNMR) 4-溴黎芦醚(2859-78-1)核磁图( 1 HNMR)
- TCI Shanghai:4-溴藜芦醚 4-Bromoveratrole,>;95.0%(GC)(2859-78-1)
- 4-溴黎芦醚价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2014/06/02 B1021 4-溴藜芦醚 4-Bromo-1,2-dimethoxybenzene 25G 560元 2011/04/16 B1021 4-溴藜芦醚 4-Bromo-1,2-dimethoxybenzene 250G 3150元 2010/06/21 107541000 4-溴黎芦醚 4-Bromoveratrole 97% 100 GR 1673元
- Acros Organics:4-溴黎芦醚(4-溴-1,2-二甲氧基苯) 4-Bromoveratrole, 97%(2859-78-1)
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