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• 试剂商城
• 直接询价

分类

• {SNA} Monomers, Polymer Science, Styrene and Functionalized Styrene Monomers, 材料科学
• {SNA} Additional Standards, Alpha Sort, Analytical Standards, Aromatics, Chemical Class, Chromatography, Environmental Standards,
• {SNA} Alpha Sort, Alphab
• {SNA} Alpha Sort, Alphabetical Index of Analytical Standard

产品应用

• 有机合成。聚合单体。

相关文献及参考

• Short: II/27B
• Beilstein:5,484
• In the presence of trichloroacetic acid, has been reported for the protection of 5-substituted tetrazoles as their N-cumyl derivatives. Deprotection was effected by catalytic transfer hydrogenolysis: J. Org. Chem., 64, 9301 (1999).
• Short: III/38A
• For asymmetric ene-reaction with methyl glyoxylate, catalyzed by a chiral binaphthyl (see (R)-(+)-1,1'-Bi(2-naphthol)­, L08305) Ti(O-i-Pr)4 complex to give methyl (2R)-3-hydroxy-4-phenyl-4-pentenoate, see: Org. Synth. Coll., 9, 596 (1998):

安全信息

GHS Symbol

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Rodent - rat
DOSE/DURATION           : 4900 mg/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   AMIHAB AMA Archives of Industrial Health.  (Chicago, IL)  V.11-21, 1955-60.
   For publisher information, see AEHLAU.  Volume(issue)/page/year: 14,387,1956

TYPE OF TEST            : TCLo - Lowest published toxic concentration
ROUTE OF EXPOSURE       : Inhalation
SPECIES OBSERVED        : Human
DOSE/DURATION           : 600 ppm
TOXIC EFFECTS :
   Sense Organs and Special Senses (Olfaction) - effect, not otherwise
   specified
   Sense Organs and Special Senses (Eye) - effect, not otherwise specified
REFERENCE :
   AMIHAB AMA Archives of Industrial Health.  (Chicago, IL)  V.11-21, 1955-60.
   For publisher information, see AEHLAU.  Volume(issue)/page/year: 14,387,1956

TYPE OF TEST            : LCLo - Lowest published lethal concentration
ROUTE OF EXPOSURE       : Inhalation
SPECIES OBSERVED        : Rodent - rat
DOSE/DURATION           : 3000 ppm
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   28ZRAQ "Toxicology and Biochemistry of Aromatic Hydrocarbons," Gerarde, H.,
   New York, Elsevier, 1960  Volume(issue)/page/year: -,131,1960

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Rodent - mouse
DOSE/DURATION           : 4500 mg/kg
TOXIC EFFECTS :
   Behavioral - convulsions or effect on seizure threshold
   Lungs, Thorax, or Respiration - cyanosis
   Nutritional and Gross Metabolic - body temperature decrease
REFERENCE :
   GISAAA Gigiena i Sanitariya.  For English translation, see HYSAAV.  (V/O
   Mezhdunarodnaya Kniga, 113095 Moscow, USSR)  V.1-    1936-
   Volume(issue)/page/year: 28(12),1

TYPE OF TEST            : Sister chromatid exchange
TEST SYSTEM             : Human Lymphocyte
DOSE/DURATION           : 330 umol/L
REFERENCE :
   MUREAV Mutation Research.  (Elsevier Science Pub. B.V., POB 211, 1000 AE
   Amsterdam, Netherlands) V.1-    1964-  Volume(issue)/page/year: 116,379,1983

其他信息

• 图谱信息:2-苯基-1-丙烯(98-83-9)核磁图( 1 HNMR) 2-苯基-1-丙烯(98-83-9)红外图谱(IR1) 2-苯基-1-丙烯(98-83-9)核磁图( 13 CNMR) 2-苯基-1-丙烯(98-83-9)质谱(MS) 2-苯基-1-丙烯(98-83-9)红外图谱(IR2) 2-苯基-1-丙烯(98-83-9)Raman光谱
• 储运特性:库房通风低温干燥; 与氧化剂分开储运
• 毒性分级:中毒
• 2-苯基-1-丙烯价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2011/08/23 81010726 α-甲基苯乙烯;异丙烯苯; α-甲基苏合香烯; 1-甲基-1-苯乙烯; 2-苯丙烯 100ml 21.1元 2011/04/16 M0429 α-甲基苯乙烯(含稳定剂TBC) alpha-Methylstyrene (stabilized with TBC) 25ML 109元 2011/04/16 M0429 α-甲基苯乙烯(含稳定剂TBC) alpha-Methylstyrene (stabilized with TBC) 500ML 218元
• Acros Organics:alpha-甲基苯乙烯 alpha-Methylstyrene, stabilized, 99%(98-83-9)
• 用途一:可用于生产涂料、增塑剂，也用作溶剂
• 用途三:有机合成。聚合单体。
• 方法一:在异丙苯法生产苯酚和丙酮时，副产α-甲基苯乙烯，年产万吨苯酚和丙酮的装置，约副产α-甲基苯乙烯500t。将异丙苯在催化剂存在下脱氢也可得到该品。但在工业中往往是将副产的α-甲基苯乙烯加氢转变为异丙苯。
• 职业标准:TWA 240 毫克/立方米; STEL 480
• 常规方法:本品易燃易爆，应采用铁桶包装，贮存于阴凉通风处，温度不得高于35℃。按易燃易爆有毒物品规定贮运。
• 爆炸物危险特性:其蒸气与空气混合可爆
• 可燃性危险特性:易燃; 火场释放辛辣刺激烟雾； 易聚合放热
• 急性毒性:口服-大鼠 LD50: 4900 毫克/公斤; 口服-小鼠 LD50: 4500 毫克/公斤
• 外观性质:无色液体, 具有刺激性臭味。
• 类别:易燃液体
• MSDS 信息:甲基苯乙烯(98-83-9).msds
• 溶于醚、苯、氯仿，不溶于水。受热或催化剂作用下易聚合。常加阻聚剂对叔丁基邻苯二酚0.005%-0.02%。在空气中爆炸极限0.7%-3.4%。
• 防护措施:本品毒性中等。应
• 上游原料:苯 --> 丙烯 --> 2-氨基-3-氯苯甲酸
• 下游产品:磷酸三苯酯 --> 高温匀染剂BOF --> 抗氧剂ZM-405
• TCI Shanghai:α-甲基苯乙烯(含稳定剂叔丁基邻苯二酚) alpha-Methylstyrene (stabilized with TBC),>;99.0%(GC)(98-83-9)
• 蒸气密度:4.1 (vs air)
• 刺激数据:皮肤-兔子 100% 中度; 眼睛-兔子 91 毫克 轻度
• Sigma Aldrich:98-83-9(sigmaaldrich)
• 用途二:本品用作聚合物单体，如丁甲苯橡胶和耐高温塑料。也可用以制取涂料、热熔胶、增塑剂以及合成麝香等。在日本，90%的α-甲基苯乙烯用作ABS树脂的改性剂，其余用作溶剂和有机合成的原料。
• Alfa Aesar:α－甲基苯乙烯,99%,stab.with10-20ppm4-tert-butylcatechol alpha-Methylstyrene, 99%, stab. with 10-20 ppm 4-tert-butylcatechol(98-83-9)
• 灭火剂:干粉, 二氧化碳, 泡沫
• 蒸气压:2.1 mm Hg ( 20 °C)