N,N-Dipropyl-1-Propanamine 三正丙胺

CAS 102-69-2 MFCD00009363

化学结构图

102-69-2
SMILES: CCCN(CCC)CCC

化学属性

Mol. FormulaC9 H21 N
Mol. Weight143.27
Autoignition Point356 °F
Refractive index1.4160 to 1.4180
Vapor Density4.9 (vs air)
Boiling Point
Vapor Pressure2.9 mmHg ( 20 °C)
Density0.753
Melting PointNo Data Available
Flash Point41°C(lit.)
TSCAYes
Solubility微溶于水,溶于乙醚,易溶于乙醇。
Stability对光敏感;对湿度敏感; 对二氧化碳敏感

别名和识别编码

Chemical NameN,N-Dipropyl-1-Propanamine
MDL NumberMFCD00009363
CAS Number102-69-2
Synonym (n-C3H7)3N 1-Propanamine, N,N-dipropyl- 1-Propanamine,N,N-dipropyl- N,N-Dipropyl-1-propanamine {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {}
PubChem Substance ID87576449
EC Number203-047-7
Beilstein Registry Number1098331
Reaxys-RN1098331
Chemical Name Translation三正丙胺
Wiswesser Line Notation3N3&3
LabNetwork Molecule IDLN01246944
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分类

  • {SNA} Amines, Building Blocks, C9, Chemical Synthesis, Nitrogen Compounds, Organic Building Blocks
  • {uni_hamburg} no charge; 1fragment

产品应用

  • 溶剂。有机合成原料,合成全氟化人造血浆和石油化工季铵分子筛催化剂。在激光技术上也有重要用途。

相关文献及参考

  • Short: III/47
  • Beilstein:4(2)623
  • Short: III/38B

安全信息

GHS Symbol
WGK Germany2
Hazard statements
  • H226 Flammable liquid and vapour 易燃液体和蒸气
  • H314 Causes severe skin burns and eye damage 导致严重的皮肤灼伤和眼睛损伤
  • H301+H311
  • H330 Fatal if inhaled 吸入致命
Personal Protective Equipment Faceshields, full-face respirator (US), Gloves, Goggles, multi-purpose combination respirator cartridge (US), type ABEK (EN14387) respirator filter
RTECSTX1575000
Precautionary statements
  • P210 Keep away from heat/sparks/open flames/hot surfaces. — No smoking. 远离热源/火花/明火/热的表面。——禁止吸烟。
  • P240 Ground/bond container and receiving equipment. 与地面接触/连接集装箱和接受设备。
  • P241+P242+P243
  • P260 Do not breathe dust/fume/gas/mist/vapours/spray. 不要吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
  • P270 Do not eat, drink or smoke when using this product. 使用本产品时不要吃东西,喝水或吸烟。
  • P273 Avoid release to the environment. 避免释放到环境中。
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P284 Wear respiratory protection.? 佩戴呼吸保护装置。
  • P301+P310
  • P301+P330+P331+P310
  • P303+P361+P353
  • P303+P361+P353+P310+P363
  • P304+P340+P310
  • P305+P351+P338
  • P305+P351+P338+P310
  • P310 Immediately call a POISON CENTER or doctor/physician. 立即呼救解毒中心或医生/医师。
  • P370+
  • P370+P378
  • P403+P235
  • P501 Dispose of contents/container to..… 处理内容物/容器.....
Signal word Danger
Packing GroupIII
UN Number 2260
Risk Statements
  • R10 Flammable 易燃
  • R21 Harmful in contact with skin 与皮肤接触有害
  • R23/25 Toxic by inhalation and if swallowed 吸入及吞食都有毒
  • R25 Toxic if swallowed 吞咽有毒
  • R34 Causes burns 会导致灼伤
  • R52/53
Safety Statements
  • S16 Keep away from sources of ignition - No smoking 远离火源,禁止吸烟;
  • S20 When using do not eat or drink 使用时,不得进食,饮水;
  • S23 Do not breathe gas/fumes/vapour/spray (appropriate wording to be specified by the manufacturer) 不要吸入气体/烟雾/蒸汽/喷雾;
  • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后,立即用大量水冲洗并征求医生意见;
  • S36/37/38
  • S36/37/39 Wear suitable protective clothing, gloves and eye/face protection 穿戴适当的防护服、手套和眼睛/面保护;
  • S45 In case of accident or if you feel unwell seek medical advice immediately (show the label where possible) 发生事故时或感觉不适时,立即求医(可能时出示标签);
  • S57 Use appropriate containment to avoid environmental contamination 使用适当容器避免环境污染;
  • S60 This material and its container must be disposed of as hazardous waste 该物质及其容器必须作为危险废物处置;
  • S61 Avoid release to the environment. Refer to special instructions/safety data sheet 避免释放到环境中,参考特别指示/安全收据说明书;
Hazard Codes 3 T T,C,Xn
Hazard Class3/8
Storage condition +4°C 4 4℃ Flammables area Hygroscopic 密封阴凉避光保存。
Warnings 危化品目录(2015) 危险化学品
TYPE OF TEST            : LC50 - Lethal concentration, 50 percent kill
ROUTE OF EXPOSURE       : Inhalation
SPECIES OBSERVED        : Mammal - species unspecified
DOSE/DURATION           : 5100 mg/m3
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   TPKVAL Toksikologiya Novykh Promyshlennykh Khimicheskikh Veshchestv.
   Toxicology of New Industrial Chemical Substances.  For English translation,
   see TNICS*.  (Izdatel'stvo Meditsina, Moscow, USSR)  No.1-    1961-
   Volume(issue)/page/year: 14,80,1975

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Administration onto the skin
SPECIES OBSERVED        : Rodent - rabbit
DOSE/DURATION           : 570 uL/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   AIHAAP American Industrial Hygiene Association Journal.  (AIHA, 475 Wolf
   Ledges Pkwy., Akron, OH 44311)  V.19-    1958-  Volume(issue)/page/year:
   30,470,1969

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Rodent - rat
DOSE/DURATION           : 96 mg/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   AIHAAP American Industrial Hygiene Association Journal.  (AIHA, 475 Wolf
   Ledges Pkwy., Akron, OH 44311)  V.19-    1958-  Volume(issue)/page/year:
   30,470,1969

TYPE OF TEST            : LC50 - Lethal concentration, 50 percent kill
ROUTE OF EXPOSURE       : Inhalation
SPECIES OBSERVED        : Rodent - rat
DOSE/DURATION           : 5100 mg/m3/4H
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   85GMAT "Toxicometric Parameters of Industrial Toxic Chemicals Under Single
   Exposure," Izmerov, N.F., et al., Moscow, Centre of International Projects,
   GKNT, 1982

其他信息

  • 上游原料:正丙胺 --> 二正丙胺
  • 图谱信息:三正丙胺(102-69-2)红外图谱(IR1) 三正丙胺(102-69-2)红外图谱(IR2) 三正丙胺(102-69-2)质谱(MS) 三正丙胺(102-69-2)核磁图( 13 CNMR)
  • TCI Shanghai:三正丙胺 Tripropylamine,>;98.0%(GC)(T)(102-69-2)
  • Alfa Aesar:三丙胺,98% Tri-n-propylamine, 98%(102-69-2)
  • 用途三:溶剂。有机合成原料,合成全氟化人造血浆和石油化工季铵分子筛催化剂。在激光技术上也有重要用途。
  • 灭火剂:干粉、干砂、二氧化碳、泡沫、1211灭火剂
  • 用途二:有机合成原料。用于合成全氟化人造血浆和石油化工季铵分子筛催化剂。在激光技术上也有重要用途。
  • 有氨的气味。对二氧化碳敏感。能与乙醇、乙醚混溶,微溶于水。
  • 海关编码:29211980
  • F:34
  • 类别:易燃液体
  • 急性毒性:口服-大鼠 LD50:72 毫克/公斤; 吸入-小鼠 LC50:3800 毫克/立方米/2小时
  • Acros Organics:三丙胺 Tripropylamine, 98%(102-69-2)
  • 可燃性危险特性:遇明火、高温、氧化剂较易燃; 燃烧产生有毒氮氧化物烟雾
  • 方法一:以正丙醇为原料在Ni-Cu-Al2O3催化剂作用下,脱氢生成丙醛,然后与氨加成,脱水、加氢生成丙胺,再经反复脱水、加氢生成二丙胺和三丙胺。反应温度为(210±10)℃,压力为396.66kPa。正丙醇空速为0.25-0.51L/L·h-1。原料配比为醇:氨:氢=4:2:4。正丙醇转化率为75%-83%,二、三丙胺总产率为75%-80%,其中二丙胺37%-41%,三丙胺35%-40%。原料消耗定额:丙醇3500kg/t、氨500kg/t、氢气1200m3。
  • 下游产品:正丙胺 --> 二正丙胺
  • MSDS 信息:三正丙胺(102-69-2).msds
  • 三正丙胺价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2011/08/23 80137127 三正丙胺 250ml 37元 2011/04/16 T0522 三丙胺 Tripropylamine 500ML 371元 2011/04/16 T0522 三丙胺 Tripropylamine 25ML 124元
  • 蒸气密度:4.9 (vs air)
  • 毒性分级:高毒
  • 蒸气压:2.9 mm Hg ( 20 °C)
  • FEMA:4247
  • 储运特性:库房通风低温干燥; 与氧化剂、酸类分开存放
  • 用途一:用于制药物、农药、橡胶和纤维加工助剂等
  • MOL 文件:102-69-2.mol
  • 外观性质:无色液体,有氨的气味。
  • Sigma Aldrich:102-69-2(sigmaaldrich)

系列性分类


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