Butyl methacrylate 甲基丙烯酸丁酯

CAS 97-88-1 MFCD00009444

化学结构图

97-88-1
SMILES: C=C(C)C(=O)OCCCC

化学属性

Mol. FormulaC8H14O2
Mol. Weight142
Density0.894
Refractive index1.4220 to 1.4260
Autoignition Point562 °F
Vapor Density4.91 (15 °C, vs air)
Boiling Point160-163
Vapor Pressure2 mmHg ( 20 °C)
Flash Point51°C(lit.)
TSCAYes
Melting Point-76
Solubility3 G/L (20 ºC)

别名和识别编码

Chemical NameButyl methacrylate, 99%, reference material
CAS Number97-88-1
EC Number202-615-1
Beilstein Registry Number773960
MDL NumberMFCD00009444
Synonym butyl methacrylate monomer {} {} {} {} Methacrylic acid butyl ester
PubChem Substance ID7354
Reaxys-RN773960
Chemical Name Translation甲基丙烯酸丁酯
Wiswesser Line Notation4OVY1&U1
LabNetwork Molecule IDLN00220234
InChIInChI=1S/C8H14O2/c1-4-5-6-10-8(9)7(2)3/h2,4-6H2,1,3H3
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分类

  • {uni_hamburg} no charge; ester; 1fragment
  • {SNA} Acrylic Monomers, Building Blocks, C8 to C9, Carbonyl Compounds, Chemical Synthesis, Esters, Materials Science, Methacrylate, Monomers, Organic Building Blocks, Polymer Science
  • {SNA} Acrylic Monomers, Building Blocks, C8 to C9, Carbonyl Compounds, Chemical Synthesis, Esters, Methacrylate, Monomers, Organic Building Blocks, Polymer Science, 材料科学

产品应用

  • 制备高聚物或共聚物的单体，塑料及光学玻璃的接合剂，纺织、皮革及造纸的乳化剂。

相关文献及参考

  • Short: III/47
  • Beilstein:2(3)1286
  • Short: III/38B

安全信息

Signal word Warning
GHS Symbol
WGK Germany1
Safety Statements
  • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后，立即用大量水冲洗并征求医生意见；
  • S36/37/39 Wear suitable protective clothing, gloves and eye/face protection 穿戴适当的防护服、手套和眼睛/面保护；
Risk Statements
  • R10 Flammable 易燃
  • R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
  • R43 May cause sensitisation by skin contact 皮肤接触会产生过敏反应
Precautionary statements
  • P203
  • P210 Keep away from heat/sparks/open flames/hot surfaces. — No smoking. 远离热源/火花/明火/热的表面。——禁止吸烟。
  • P233 Keep container tightly closed. ?保持容器密闭。
  • P240 Ground/bond container and receiving equipment. 与地面接触/连接集装箱和接受设备。
  • P241 Use explosion-proof electrical/ventilating/lighting/…/equipment. 使用防爆电气/通风/照明/ .../设备。
  • P242 Use only non-sparking tools. 只能使用无火花工具。
  • P243 Take precautionary measures against static discharge. 采取预防措施，防止静电放电。
  • P260 Do not breathe dust/fume/gas/mist/vapours/spray. 不要吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
  • P264+P265
  • P271 Use only outdoors or in a well-ventilated area.? 只能在室外或通风良好的地方使用。
  • P272 Contaminated work clothing should not be allowed out of the workplace. 污染的工作服不得带出工作场所。
  • P273 Avoid release to the environment. 避免释放到环境中。
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P302+P352
  • P303+P361+P353
  • P304+P340
  • P305+P351+P338
  • P318
  • P319
  • P321 Specific treatment (see … on this label). 具体治疗（见本标签上的）。
  • P332+P317
  • P333+P317
  • P337+P317
  • P362+P364
  • P370+P378
  • P403+P233
  • P403+P235
  • P405 Store locked up. 上锁保管。
  • P501 Dispose of contents/container to..… 处理内容物/容器.....
Hazard statements
  • H226 Flammable liquid and vapour 易燃液体和蒸气
  • H315 Causes skin irritation 会刺激皮肤
  • H317 May cause an allergic skin reaction 可能导致皮肤过敏
  • H319 Causes serious eye irritation 严重刺激眼睛
  • H335 May cause respiratory irritation 可能导致呼吸道刺激
Personal Protective Equipment Eyeshields, Faceshields, full-face respirator (US), Gloves, multi-purpose combination respirator cartridge (US), type ABEK (EN14387) respirator filter
RTECSOZ3675000
Packing GroupIII
UN Number 2227
Hazard Codes 3
Storage condition 密封阴凉处保存。 Refrigerator (+4°C) + Flammables area
Hazard Class3
Warnings 危化品目录(2015) 
TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Administration onto the skin
SPECIES OBSERVED        : Rodent - rabbit
DOSE/DURATION           : 11300 uL/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   AIHAAP American Industrial Hygiene Association Journal.  (AIHA, 475 Wolf
   Ledges Pkwy., Akron, OH 44311)  V.19-    1958-  Volume(issue)/page/year:
   30,470,1969

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Intraperitoneal
SPECIES OBSERVED        : Rodent - rat
DOSE/DURATION           : 2304 mg/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   JDREAF Journal of Dental Research.  (International Assoc. for Dental
   Research, 734 15th St., NW, Suite 809, Washington, DC 20005)  V.1-    1919-
   Volume(issue)/page/year: 51,1632,1972

TYPE OF TEST            : LC50 - Lethal concentration, 50 percent kill
ROUTE OF EXPOSURE       : Inhalation
SPECIES OBSERVED        : Rodent - rat
DOSE/DURATION           : 4910 ppm/4H
TOXIC EFFECTS :
   Sense Organs and Special Senses (Olfaction) - effect, not otherwise
   specified
   Sense Organs and Special Senses (Eye) - effect, not otherwise specified
   Lungs, Thorax, or Respiration - dyspnea
REFERENCE :
   JTEHD6 Journal of Toxicology and Environmental Health.  (Hemis

{hazard_com}

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Administration onto the skin
SPECIES OBSERVED        : Rodent - guinea pig
DOSE/DURATION           : >20 mL/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   NTIS** National Technical Information Service.  (Springfield, VA 22161)
   Formerly U.S. Clearinghouse for Scientific & Technical Information.
   Volume(issue)/page/year: 0TS0516721

TYPE OF TEST            : TDLo - Lowest published toxic dose
ROUTE OF EXPOSURE       : Intraperitoneal
SPECIES OBSERVED        : Rodent - rat
DOSE                    : 690 mg/kg
SEX/DURATION            : female 5-15 day(s) after conception
TOXIC EFFECTS :
   Reproductive - Effects on Embryo or Fetus - fetotoxicity (except death,
   e.g., stunted fetus)
   Reproductive - Specific Developmental Abnormalities - other developmental
   abnormalities
REFERENCE :
   JDREAF Journal of Dental Research.  (International Assoc. for Dental
   Research, 734 15th St., NW, Suite 809, Washington, DC 20005)  V.1-    1919-
   Volume(issue)/page/year: 51,1632,1972

TYPE OF TEST            : TDLo - Lowest published toxic dose
ROUTE OF EXPOSURE       : Intraperitoneal
SPECIES OBSERVED        : Rodent - rat
DOSE                    : 2304 mg/kg
SEX/DURATION            : female 5-15 day(s) after conception
TOXIC EFFECTS :
   Reproductive - Fertility - post-implantation mortality (e.g. dead and/or
   resorbed implants per total number of implants)
REFERENCE :
   JDREAF Journal of Dental Research.  (International Assoc. for Dental
   Research, 734 15th St., NW, Suite 809, Washington, DC 20005)  V.1-    1919-
   Volume(issue)/page/year: 51,1632,1972

Restrict 危险品

其他信息

  • 海关编码:29161490
  • 储运特性:库房通风低温干燥; 与氧化剂分开储运
  • 蒸气密度:4.91 (15 °C, vs air)
  • 毒性分级:低毒
  • 上游原料:硫酸 --> 正丁醇 --> 2-甲基丙烯酸 --> 丙酮氰醇
  • 方法一:甲基丙烯酸与正丁醇在硫酸催化下进行酯化反应，再经盐析、精馏得成品。
  • 用途三:制备高聚物或共聚物的单体。用于有机玻璃改性，并可用作纸张、皮革、纺织品的整理剂、乳化剂、上光剂、防臭剂。还可用作油漆涂料的溶剂，用作石油添加剂和粘结剂的组分。
  • 可燃性危险特性:易燃; 聚合大量放热
  • Alfa Aesar:正丁基甲基丙烯酸酯,99% n-Butyl methacrylate, 99%, stab. with 15-20 ppm 4-methoxyphenol(97-88-1)
  • 爆炸物危险特性:蒸气与空气混合可爆
  • 常规方法:镀锌铁桶包装。要求在阴凉处存放，贮存温度＜20℃。注意防火。成品加阻聚剂后保存期为三个月。
  • 下游产品:卡波姆树脂 --> 网印印花粘合剂 --> 东风牌粘合剂 RF
  • 极易聚合，常加入对苯二酚0.01%作阻聚剂。溶于乙醇、乙醚，不溶于水。
  • 防护措施:与甲基丙烯酸甲酯基本相同，毒性较低。大鼠经口LD50为20ml/kg体重。防护要求与甲基丙烯酸甲酯同。
  • 类别:易燃液体
  • TCI Shanghai:甲基丙烯酸丁酯(含稳定剂氢醌) Butyl Methacrylate (stabilized with HQ),>;99.0%(GC)(97-88-1)
  • 用途四:制备高聚物或共聚物的单体，塑料及光学玻璃的接合剂，纺织、皮革及造纸的乳化剂。
  • Sigma Aldrich:97-88-1(sigmaaldrich)
  • 用途一:用作聚合物的单体，用于生产改性有机玻璃、透明胶片，制造纸张、织物、皮革等整理剂、上光剂，用作涂料溶剂
  • 图谱信息:甲基丙烯酸丁酯(97-88-1)核磁图( 13 CNMR) 甲基丙烯酸丁酯(97-88-1)核磁图( 1 HNMR) 甲基丙烯酸丁酯(97-88-1)红外图谱(IR2) 甲基丙烯酸丁酯(97-88-1)红外图谱(IR1) 甲基丙烯酸丁酯(97-88-1)质谱(MS)
  • MOL 文件:97-88-1.mol
  • 灭火剂:干粉, 二氧化碳, 砂土, 泡沫
  • MSDS 信息:甲基丙烯酸正丁酯(97-88-1).msds
  • 急性毒性:口服-小鼠 LD50: 11990 毫克/公斤
  • Acros Organics:甲基丙烯酸正丁酯 Butyl methacrylate, stabilized, 99%(97-88-1)
  • 蒸气压:2 mm Hg ( 20 °C)
  • 外观性质:无色、具有甜味和酯气味的液体。
  • 甲基丙烯酸丁酯价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2011/08/23 81003428 甲基丙烯酸正丁酯 500ml 34.3元 2011/04/16 M0081 甲基丙烯酸丁酯(含稳定剂HQ) Butyl Methacrylate (stabilized with HQ) 500ML 248元 2011/04/16 M0081 甲基丙烯酸丁酯(含稳定剂HQ) Butyl Methacrylate (stabilized with HQ) 25ML 117元
  • 职业标准:TWA 300 毫克/立方米; STEL 450 毫克/立方米
  • 用途二:用于塑料及有机物的合成

系列性分类

  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Organic Building Blocks 有机砌块
  4. Carbonyl Compounds 羰基化合物
  5. Esters - Carbonyl Compounds
  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Organic Building Blocks 有机砌块
  4. Carbonyl Compounds 羰基化合物
  5. Esters - Carbonyl Compounds
  6. C8 to C9 - Esters
  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Organic Building Blocks 有机砌块
  4. Carbonyl Compounds 羰基化合物
  5. Hydrazides - Carbonyl Compounds
  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Organic Building Blocks 有机砌块
  4. Carbonyl Compounds 羰基化合物
  5. Esters
  6. C6 to C7
  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Monomers
  4. Acrylic Monomers 丙烯酸单体
  5. Fluorinated Acrylics

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