Mercurous Chloride 氯化亚汞

CAS 10112-91-1 MFCD00011043

化学结构图

10112-91-1
SMILES: Cl[Hg][Hg]Cl

化学属性

Mol. FormulaCl2Hg2
Mol. Weight472.08
Melting Point400° subl.
Density7.15
SolubilityInsoluble in water, alcohol, ether, dilute acids
TSCAYes
Stability对光敏感

别名和识别编码

Chemical NameMercurous Chloride
Synonym Quecksilber(I)-chlorid Mercurous chloride 一氯化汞(I),甘汞 甘汞 Mercury subchloride Precipite blanc Mercurous chloride (Hg2Cl2) 一氯化汞,甘汞 Dimercury Dichloride Calomel Mercury chloride (Hg2Cl2) Mild mercury chloride Diquecksilberdichlorid Kalomel Diquecksilber(I)dichlorid Calogreen Mercury(I) chloride Cyclosan Dimercury dichloride Mercury monochloride Chlorure mercureux Mercury subchlorideCalomel Mercury chloride (Hg2Cl2) Calotab Mercury(I) chloride USP Dimercury dichloride; Mercury(I) chloride Mercury (I) chloride USP 氯化亚汞 mercury (I) chloride
MDL NumberMFCD00011043
PubChem Substance ID24868461
CAS Number10112-91-1
EC Number233-307-5
Merck Number14,5894
Chemical Name Translation氯化亚汞
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分类

  • {uni_hamburg} no charge; 3fragments; ionic
  • {SNA} ACS Grade, Catalysis and Inorganic Chemistry, Chemical Synthesis, Essential Chemicals, Inorganic Salts, Solutions and Reagents, Mercury, Research Essentials

产品应用

  • 点滴分析测定钯和锆,用于制作甘汞电极,是电化学中常用的参比电极,也用于制轻泻剂、利尿剂、防腐剂等

相关文献及参考

  • Short: III/20b
  • Short: III/29a
  • Short: III/30A
  • Merck:14,5894

安全信息

GHS Symbol
Precautionary statements
  • P501 Dispose of contents/container to..… 处理内容物/容器.....
  • P273 Avoid release to the environment. 避免释放到环境中。
  • P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P305+P351+P338
Hazard statements
  • H410 Verytoxictoaquaticlifewithlonglastingeffects 对水生生物毒性非常大并具有长期影响。
  • H315 Causes skin irritation 会刺激皮肤
  • H335 May cause respiratory irritation 可能导致呼吸道刺激
  • H302 Harmful if swallowed 吞食有害
  • H319 Causes serious eye irritation 严重刺激眼睛
Hazard Codes Xn;N Xn,N
WGK Germany3
Signal word Warning
RTECSOV8740000
Safety Statements
  • S13 Keep away from food, drink and animal foodstuffs 远离食品、饮料和动物饲料保存;
  • S46 If swallowed, seek medical advice immediately and show this container or label 食入时,立即求医并出示容器/标签;
  • S24/25 Avoid contact with skin and eyes 避免皮肤和眼睛接触;
  • S60 This material and its container must be disposed of as hazardous waste 该物质及其容器必须作为危险废物处置;
  • S61 Avoid release to the environment. Refer to special instructions/safety data sheet 避免释放到环境中,参考特别指示/安全收据说明书;
UN Number 2811 UN2025
Risk Statements
  • R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
  • R22 Harmful if swallowed 吞咽有害
  • R50/53
Packing GroupII
Storage condition Moisture & Light Sensitive 密封避光保存。
Restrict 剧毒化学品
Warnings 危化品目录(2015) 危险化学品
TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Rodent - mouse
DOSE/DURATION           : 180 mg/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   GTPZAB Gigiena Truda i Professional'nye Zabolevaniya.  Labor Hygiene and
   Occupational Diseases. (V/O Mezhdunarodnaya Kniga, 113095 Moscow, USSR)
   V.1-36, 1957-1992. For publisher information, see MTPEEI
   Volume(issue)/page/year: 25(7),27,1981

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Administration onto the skin
SPECIES OBSERVED        : Rodent - rat
DOSE/DURATION           : 1500 mg/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   GTPZAB Gigiena Truda i Professional'nye Zabolevaniya.  Labor Hygiene and
   Occupational Diseases. (V/O Mezhdunarodnaya Kniga, 113095 Moscow, USSR)
   V.1-36, 1957-1992. For publisher information, see MTPEEI
   Volume(issue)/page/year: 25(7),27,1981

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Rodent - rat
DOSE/DURATION           : 210 mg/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   PEMNDP Pesticide Manual.  (The British Crop Protection Council, 20 Bridport
   Rd., Thornton Heath CR4 7QG, UK)  V.1-    1968-  Volume(issue)/page/year:
   9,552,1991

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Intraperitoneal
SPECIES OBSERVED        : Rodent - mouse
DOSE/DURATION           : 10 mg/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   GTPZAB Gigiena Truda i Professional'nye Zabolevaniya.  Labor Hygiene and
   Occupational Diseases. (V/O Mezhdunarodnaya Kniga,

其他信息

  • 不溶于水及有机溶剂,溶于硝酸,见光渐渐分解。400℃升华,在水中的溶解度极小,18℃时,100克水中只溶解0.02克氯化亚汞,有氯化氢或碱金属氯化物存在时,其溶解度增大。将氯化汞与汞放在一起研磨,可生成氯化亚汞:HgCl2+HgHg2Cl2。

系列性分类


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