Periodic Acid 高碘酸

CAS 10450-60-9 MFCD00011344

化学结构图

10450-60-9
SMILES: [O-][I+](O)(O)(O)(O)O

化学属性

Mol. FormulaH5IO6
Mol. Weight228
Melting Point122
TSCAYes
Solubility溶于水、乙醇，微溶于乙醚。
Stability对光敏感

别名和识别编码

Chemical NamePeriodic Acid
CAS Number10450-60-9
PubChem Substance ID24864643
EC Number233-937-0
MDL NumberMFCD00011344
Merck Number14,7171
Synonym Orthoperiodic acid 高碘酸 溶液 一缩原高碘酸 高碘酸 过碘酸 仲高碘酸 仲高碘酸;一缩原高碘酸;过碘酸
Beilstein Registry Number605317
Chemical Name Translation高碘酸
InChIKeyTWLXDPFBEPBAQB-UHFFFAOYSA-N
Alfabeta NamePENTAHYDROXYIODANEOXIDE L5--
LabNetwork Molecule IDLN00160175
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分类

  • {SNA} Chemical Synthesis, Histology Special Stains, Hypervalent Iodine, Oxidizing Agents, Synthetic Reagents, 细胞生物学, 血液学和组织学
  • {SA} Chemical Synthesis, Colorimetric Detection of PAGE and Western Blots, Electrophoresis of Glycans, Glycan Labeling and Analysis, Glycobiology, Glycoprotein Detection, Hypervalent
  • Chemical Synthesis,
  • {SNA} Acids, Chemical Synthesis, Electronic Chemicals, Hypervalent Iodine, Micro/NanoElectronics, Oxidizing Agents, Synthetic Reagents, 材料科学
  • {SNA} Acids, Acids & Bases, Chemical Synthesis, Hypervalent Iodine,

产品应用

  • 氧化剂。电泳级用于糖蛋白染色

相关文献及参考

  • 2. Thornton, D.J, et al., Walker, J.M., ed., Identification of glycoproteins on nitrocellulose membranes and gels. Methods Mol. Biol. Totowa, NJ , (1994) 32 , 119-128
  • Devine, P.L. and Warren, J.A., Glycoprotein detection on Immobilon PVDF transfer membrane using the Periodic Acid/Schiff Reagent. Biotechniques 8 , 492, (1990) 摘要
  • Jay, G.D., et al., Silver staining of extensively glycosylated proteins on sodium dodecyl sulfate-polyacrylamide gels: enhancement by carbohydrate-binding dyes. Anal. Biochem. 185 , 324-330, (1990) 摘要
  • Merck:14,7171
  • Oxidizing agent. For reactions of periodate ion, see Sodium metaperiodate, 13798. Reagent for deblocking of dithioacetal and oxathioacetal protecting groups under mild, non-aqueous conditions in THF-ether: Tetrahedron Lett., 37, 4331 (1996). Stoichiometric oxidant used in combination with catalytic Chromium(VI)­ oxide, 12522, for conversion of alcohols to carboxylic acids in wet acetonitrile: Tetrahedron Lett., 39, 5323 (1998).

安全信息

GHS Symbol
WGK Germany3
Hazard Codes C
Hazard statements
  • H314 Causes severe skin burns and eye damage 导致严重的皮肤灼伤和眼睛损伤
  • H272 May intensify fire; oxidizer 可能加剧火势；氧化剂。
  • H410 Verytoxictoaquaticlifewithlonglastingeffects 对水生生物毒性非常大并具有长期影响。
  • H271 May cause fire or explosion; strong oxidizer 可能会引起火宅或爆炸；强氧化剂。
Personal Protective Equipment Eyeshields, Faceshields, full-face particle respirator type N100 (US), Gloves, respirator cartridge type N100 (US), type P1 (EN143) respirator filter, type P3 (EN 143) respirator cartridges Faceshields, full-face respirator (US), Gloves, Goggles, multi-purpose combination respirator cartridge (US), type ABEK (EN14387) respirator filter
Precautionary statements
  • P260 Do not breathe dust/fume/gas/mist/vapours/spray. 不要吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P371+P380+P375
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P305+P351+P338
  • P210 Keep away from heat/sparks/open flames/hot surfaces. — No smoking. 远离热源/火花/明火/热的表面。——禁止吸烟。
  • P370+P378
  • P220 Keep/Store away from clothing/…/combustible materials. 保持远离/贮存远离服装/....../可燃材料。
  • P310 Immediately call a POISON CENTER or doctor/physician. 立即呼救解毒中心或医生/医师。
Signal word
Safety Statements
  • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后，立即用大量水冲洗并征求医生意见；
  • S36/37/39 Wear suitable protective clothing, gloves and eye/face protection 穿戴适当的防护服、手套和眼睛/面保护；
  • S20 When using do not eat or drink 使用时，不得进食，饮水；
  • S45 In case of accident or if you feel unwell seek medical advice immediately (show the label where possible) 发生事故时或感觉不适时，立即求医（可能时出示标签）；
  • S17 Keep away from combustible material 远离可燃物料；
UN Number
Risk Statements
  • R8 Contact with combustible material may cause fire 遇到易燃物会导致起火
  • R34 Causes burns 会导致灼伤
Storage condition Moisture & Light Sensitive Light Sensitive & Hygroscopic 密封干燥避光保存。 密封干燥保存。
RTECSNN1269700
Packing GroupII
Warnings 危化品目录(2015)
Restrict 危险品

其他信息

  • 具潮解性，能溶于水、醇，微溶于醚。水中溶解度：300g/100ml (20 C)

系列性分类

  1. Life Science 生命科学
  2. Hematology and Histology 血液学和组织学
  3. Histology Special Stains - Hematology and Histology
  1. Research Essentials 基础科研
  2. Essential Chemicals - Research Essentials
  3. Acids & Bases - Essential Chemicals
  4. ACS Grade - Acids & Bases
  1. Chemical Synthesis 化学合成
  2. Synthetic Reagents 合成试剂
  3. Inorganic Acids - Synthetic Reagents
  1. Analytical & Chromatography 分析化学与色谱
  2. Analytical Reagents
  3. Analytical Reagents for General Use - Analytical Reagents
  4. Puriss p.a. ACS - Analytical Reagents for General Use
  1. Chemical Synthesis 化学合成
  2. Synthetic Reagents 合成试剂
  3. Oxidation - Synthetic Reagents
  4. Chromates - Oxidation
  1. Chemical Synthesis 化学合成
  2. Synthetic Reagents 合成试剂
  3. Oxidation - Synthetic Reagents
  4. Hypervalent Iodine - Oxidation
  1. Analytical & Chromatography 分析化学与色谱
  2. Analytical Reagents
  3. Analytical Reagents for General Use - Analytical Reagents
  4. Puriss p.a. ACS - Analytical Reagents for General Use
  5. O-P, Puriss p.a. ACS - Puriss p.a. ACS
  1. Materials Science 材料科学
  2. Micro/NanoElectronics - Materials Science
  3. Electronic Chemicals - Micro/NanoElectronics
  4. Electronic Chemicals: Acids
  1. Life Science 生命科学
  2. Proteomics 蛋白质组学
  3. Protein Electrophoresis - Proteomics
  4. Protein Stains and Staining Reagents - Protein Electrophoresis
  5. Other Stains for Electrophoresis - Protein Stains and Staining Reagents
  1. Analytical & Chromatography 分析化学与色谱
  2. Acids & Bases
  1. Analytical & Chromatography 分析化学与色谱
  2. Adsorbents, Filter Aids and Drying Agents
  3. Other Drying Agents
  1. Life Science 生命科学
  2. Biochemicals and Reagents
  3. Acids & Bases
  1. Life Science 生命科学
  2. Biochemicals and Reagents
  3. Glycobiology
  4. Glycan Labeling and Analysis
  1. Life Science 生命科学
  2. Biochemicals and Reagents
  3. Glycobiology
  4. Glycoprotein Detection
  1. Life Science 生命科学
  2. Biochemicals and Reagents
  3. Molecular Biology
  4. Protein Electrophoresis
  5. Protein Stains and Staining Reagents
  6. Fluorescent Protein Electrophoresis Stains
  1. Life Science 生命科学
  2. Biochemicals and Reagents
  3. Proteomics
  4. Post-Translational Modification
  5. Glycobiology
  6. Glycan Component Classes
  1. Life Science 生命科学
  2. Biochemicals and Reagents
  3. Proteomics
  4. Post-Translational Modification
  5. Glycobiology
  6. Glycan Labeling and Analysis
  1. Life Science 生命科学
  2. Biochemicals and Reagents
  3. Proteomics
  4. Protein Electrophoresis
  5. Protein Stains and Staining Reagents
  6. Fluorescent Protein Electrophoresis Stains
  1. Life Science 生命科学
  2. Biochemicals and Reagents
  3. Plant Biotechnology
  4. Plant Proteomics
  5. Protein Electrophoresis
  6. Protein Stains and Staining Reagents
  7. Fixing Reagents

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