Hexafluorophosphoric Acid 六氟磷酸

CAS 16940-81-1 MFCD00011350

化学结构图

16940-81-1
SMILES:

化学属性

Mol. FormulaHPF6
Mol. Weight145.97
Density1.75
TSCAYes
Melting Point31°C
SolubilityHYDROLYZES SLOWLY
pH:A

别名和识别编码

Chemical NameHexafluorophosphoric Acid
Synonym Hydrogen hexafluorophosphate
MDL NumberMFCD00011350
PubChem Substance ID24851984
CAS Number16940-81-1
EC Number241-006-5
Chemical Name Translation六氟磷酸
InChIKeyLJQLCJWAZJINEB-UHFFFAOYSA-O
Wiswesser Line Notation..H..P-F6
LabNetwork Molecule IDLN01373788
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分类

  • {SNA} Acids, Alternative Energy, Chemical Synthesis, Electrolytes, Electronic Chemicals,
  • Acids, Alternative Energy, Chemical Synthesis, Electrolytes, Electronic Chemicals, Inorganic Acids, Materials Science, Micro/NanoElectronics, Organic Solvents, Synthetic Reagents
  • {SNA} Acids, Acids & Bases, Alternative Energy, Chemical Synthesis, Electrolytes, Electronic Chemicals, Inorganic Acids, Micro/NanoElectronics, Organic Solvents, Synthetic Reagents, 材料科学

相关文献及参考

  • Fieser 1 ,42 / Fieser 2 ,402
  • Corp MSDS 1 (1), 1847:B / RegBook 1 (3), 3249:E / Sax 6 , 1514
  • Thermal decomposition of diazonium hexafluorophosphates often gives better results in the synthesis of aryl fluorides than the classical Balz-Schiemann method via the tetrafluoroborates (see Tetrafluoroboric acid, L14037). For an example, see: Org. Synth. Coll., 5, 133 (1973).

安全信息

WGK Germany3
Precautionary statements
  • P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P301+P310
  • P302+P350
  • P305+P351+P338
Hazard statements
  • H314 Causes severe skin burns and eye damage 导致严重的皮肤灼伤和眼睛损伤
  • H331 Toxic if inhaled 吸入中毒
  • H310 Fatal in contact with skin 皮肤接触致命
  • H300 Fatal if swallowed 吞食致命
  • H290 May be corrosive to metals 可能腐蚀金属。
  • H300+H310
Hazard Codes 8 T+,C
GHS Symbol
Personal Protective Equipment Faceshields, full-face respirator (US), Gloves, Goggles, multi-purpose combination respirator cartridge (US), type ABEK (EN14387) respirator filter
Signal word Danger
RTECSSY7115000
Safety Statements
  • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后,立即用大量水冲洗并征求医生意见;
  • S28 After contact with skin, wash immediately with plenty of ... (to be specified by the manufacturer) 皮肤接触后,立即用大量…(由生产厂家指定)冲洗;
  • S36/37/39 Wear suitable protective clothing, gloves and eye/face protection 穿戴适当的防护服、手套和眼睛/面保护;
  • S45 In case of accident or if you feel unwell seek medical advice immediately (show the label where possible) 发生事故时或感觉不适时,立即求医(可能时出示标签);
UN Number 1782
Risk Statements
  • R23/24/25 Toxic by inhalation, in contact with skin and if swallowed 吸入,皮肤接触及吞食都有毒
  • R26/27/28 Very toxic by inhalation, in contact with skin and if swallowed 吸入,皮肤接触及吞食都有剧毒
  • R34 Causes burns 会导致灼伤
  • R35 Causes severe burns 会导致严重灼伤
Packing GroupII
Warnings 危化品目录(2015)
Restrict 危险品

其他信息

  • 在中性或缄性溶液中十分稳定。

系列性分类


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