O-Benzylhydroxylamine hydrochloride O-苯基羟胺盐酸盐

CAS 2687-43-6 MFCD00012952

化学结构图

2687-43-6
SMILES: Cl.NOCc1ccccc1

化学属性

Mol. FormulaC7H10ClNO
Mol. Weight159.61
Density1.422
Melting Point238 °C
TSCANo
Appearance 苄氧基胺盐酸盐(2687-43-6)为白色片状结晶,熔点238℃,溶于热水。

别名和识别编码

Chemical NameO-Benzylhydroxylamine Hydrochloride
CAS Number2687-43-6
Alfabeta NameBENZYLHYDROXYLAMINEHYDROCHLORIDE O-
MDL NumberMFCD00012952
EC Number220-249-0
Beilstein Registry Number6,440
Synonym O-Benzylhydroxylamine (hydrochloride) {LY} O-Benzylhydroxylamine (hydrochloride) O-benzylhydroxylamine benzyloxyamine benzyloxyamine hydrochloride {} {LY} O-Benzylhydroxylamine (hydrochloride) {} {} {LY} O-Benzylhydroxylamine (hydrochloride) {} {} {} {LY} O-Benzylhydroxylamine (hydrochloride) {} {} {} {} {LY} O-Benzylhydroxylamine (hydrochloride) {} {} {} {} {} {LY} O-Benzylhydroxylamine (hydrochloride) {} {} {} {} {} {} {LY} O-Benzylhydroxylamine (hydrochloride) {} {} {} {} {} {} {} {LY} O-Benzylhydroxylamine (hydrochloride) {} {} {} {} {} {} {} {} {LY} O-Benzylhydroxylamine (hydrochloride) {} {} {} {} {} {} {} {} {} {LY} O-Benzylhydroxylamine (hydrochloride) {} {} {} {} {} {} {} {} {} {} {LY} O-Benzylhydroxylamine (hydrochloride) {} {} {} {} {} {} {} {} {} {} {} {LY} O-Benzylhydroxylamine (hydrochloride) {} {} {} {} {} {} {} {} {} {} {} {} {LY} O-Benzylhydroxylamine (hydrochloride) {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} O-Ben
PubChem Substance ID102312
Chemical Name TranslationO-苯基羟胺盐酸盐
Reaxys-RN3595440
InChIKeyHYDZPXNVHXJHBG-UHFFFAOYSA-N
Wiswesser Line NotationZO1R &GH
LabNetwork Molecule IDLN00123833
InChIInChI=1S/C7H9NO.ClH/c8-9-6-7-4-2-1-3-5-7;/h1-5H,6,8H2;1H
Canonical SMILESNOCC1=CC=CC=C1.[H]Cl
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分类

  • {SNA} Building Blocks, Chemical Synthesis, Hydroxylamines, Nitrogen Compounds, Organic Building Blocks

相关文献及参考

  • In the peptide field, Palladium, 11722 is a useful selective catalyst for deprotection of the benzyl hydroxamates: Tetrahedron Lett., 36, 197 (1995).
  • For use in the formation of nitrones from carbonyl compounds and their use in cycloaddition reactions, see: J. Org. Chem., 47, 2328 (1982); 52, 2179 (1987).

安全信息

Warnings IRRITANT
Signal word Warning
GHS Symbol
WGK Germany3
Safety Statements
  • S22 Do not breathe dust 不要吸入粉尘;
  • S24/25 Avoid contact with skin and eyes 避免皮肤和眼睛接触;
  • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后,立即用大量水冲洗并征求医生意见;
  • S36/37/39 Wear suitable protective clothing, gloves and eye/face protection 穿戴适当的防护服、手套和眼睛/面保护;
Risk Statements
  • R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
Precautionary statements
  • P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
  • P264+P265
  • P271 Use only outdoors or in a well-ventilated area.? 只能在室外或通风良好的地方使用。
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P302+P352
  • P304+P340
  • P305+P351+P338
  • P312 Call a POISON CENTER or doctor/physician if you feel unwell. 如果你感觉不适,呼叫解毒中心或医生/医师。
  • P319
  • P321 Specific treatment (see … on this label). 具体治疗(见本标签上的)。
  • P332+P313
  • P332+P317
  • P337+P313
  • P337+P317
  • P362 Take off contaminated clothing and wash before reuse. 脱掉污染的衣服,清洗后方可重新使用
  • P362+P364
  • P403+P233
  • P405 Store locked up. 上锁保管。
  • P501 Dispose of contents/container to..… 处理内容物/容器.....
RTECSNC3040000
Personal Protective Equipment Eyeshields, Gloves, type N95 (US), type P1 (EN143) respirator filter
Storage condition 2-8°C, sealed storage, away from moisture {LY} 2-8°C, sealed storage, away from moisture Hygroscopic Store at RT. Store at room temperature Store at room temperature, keep dry and cool {} {LY} 2-8°C, sealed storage, away from moisture {} {} {LY} 2-8°C, sealed storage, away from moisture {} {} {} {LY} 2-8°C, sealed storage, away from moisture {} {} {} {} {LY} 2-8°C, sealed storage, away from moisture {} {} {} {} {} {LY} 2-8°C, sealed storage, away from moisture {} {} {} {} {} {} {LY} 2-8°C, sealed storage, away from moisture {} {} {} {} {} {} {} {LY} 2-8°C, sealed storage, away from moisture {} {} {} {} {} {} {} {} {LY} 2-8°C, sealed storage, away from moisture {} {} {} {} {} {} {} {} {} {LY} 2-8°C, sealed storage, away from moisture {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, sealed storage, away from moisture {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, sealed storage, away from moisture {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°
Hazard Codes Xi
TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Intraperitoneal
SPECIES OBSERVED        : Rodent - mouse
DOSE/DURATION           : 250 mg/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   NTIS** National Technical Information Service.  (Springfield, VA 22161)
   Formerly U.S. Clearinghouse for Scientific & Technical Information.
   Volume(issue)/page/year: AD691-490

Hazard statements
  • H315 Causes skin irritation 会刺激皮肤
  • H319 Causes serious eye irritation 严重刺激眼睛
  • H335 May cause respiratory irritation 可能导致呼吸道刺激

其他信息

  • 苄氧基胺盐酸盐价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2014/06/02 B1079 O-苄胲盐酸盐 O-Benzylhydroxylamine Hydrochloride 250G 2280元 2014/06/02 B1079 O-苄胲盐酸盐 O-Benzylhydroxylamine Hydrochloride 25G 300元 2010/06/21 105970250 苄氧基胺盐酸盐 O-Benzylhydroxylamine hydrochloride 99% 25 GR 1543元
  • Alfa Aesar:O-苄基羟胺盐酸盐,99% O-Benzylhydroxylamine hydrochloride, 99%(2687-43-6)
  • TCI Shanghai:O-苄胲盐酸盐 O-Benzylhydroxylamine Hydrochloride,>;98.0%(T)(2687-43-6)
  • MSDS 信息:Benzylhydroxylamine hydrochloride(2687-43-6).msds
  • F:3
  • 检测方法:T,NMR
  • MOL 文件:2687-43-6.mol
  • 敏感性:Hygroscopic
  • 图谱信息:苄氧基胺盐酸盐(2687-43-6)质谱(MS) 苄氧基胺盐酸盐(2687-43-6)核磁图( 13 CNMR) 苄氧基胺盐酸盐(2687-43-6)红外图谱(IR1) 苄氧基胺盐酸盐(2687-43-6)红外图谱(IR2) 苄氧基胺盐酸盐(2687-43-6)核磁图( 1 HNMR) 苄氧基胺盐酸盐(2687-43-6)Raman光谱
  • Acros Organics:O-苄基羟胺盐酸盐 O-Benzylhydroxylamine hydrochloride, 99%(2687-43-6)
  • Sigma Aldrich:2687-43-6(sigmaaldrich)

系列性分类


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