5-Amino-1-Naphthalenesulfonic Acid 1-萘胺-5-磺酸

CAS 84-89-9 MFCD00014315

化学结构图

84-89-9
SMILES: Nc1cccc2c(S(=O)(=O)O)cccc12

化学属性

Mol. FormulaC10H9NO3S
Mol. Weight223.25
Melting Point>300 °C
TSCAYes
Density1.502
Appearance 工业品一般为膏状物,纯品为白色或浅粉红色针状结晶,稀水溶液带绿色荧光。 溶于950份冷水中,较易溶于热水。
Solubility溶于950份冷水中,较易溶于热水
Boiling Point220 °C at 760 mmHg

别名和识别编码

Chemical Name5-Amino-1-Naphthalenesulfonic Acid
Synonym 5-Aminonaphthalene-1-sulfonic acid {LY} 5-Aminonaphthalene-1-sulfonic acid {} {LY} 5-Aminonaphthalene-1-sulfonic acid {} {} {LY} 5-Aminonaphthalene-1-sulfonic acid {} {} {} {LY} 5-Aminonaphthalene-1-sulfonic acid {} {} {} {} {LY} 5-Aminonaphthalene-1-sulfonic acid {} {} {} {} {} {LY} 5-Aminonaphthalene-1-sulfonic acid {} {} {} {} {} {} {LY} 5-Aminonaphthalene-1-sulfonic acid {} {} {} {} {} {} {} {LY} 5-Aminonaphthalene-1-sulfonic acid {} {} {} {} {} {} {} {} {LY} 5-Aminonaphthalene-1-sulfonic acid {} {} {} {} {} {} {} {} {} {LY} 5-Aminonaphthalene-1-sulfonic acid {} {} {} {} {} {} {} {} {} {} {LY} 5-Aminonaphthalene-1-sulfonic acid {} {} {} {} {} {} {} {} {} {} {} {LY} 5-Aminonaphthalene-1-sulfonic acid {} {} {} {} {} {} {} {} {} {} {} {} {LY} 5-Aminonaphthalene-1-sulfonic acid {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 5-Aminonaphthalene-1-sulfonic acid {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 5-Aminonaphthalene-1-sulfonic acid {} {} {} {} {} {} {} {} {}
MDL NumberMFCD00014315
CAS Number84-89-9
PubChem Substance ID6793
Beilstein Registry Number14(3)2244
EC Number201-571-0
Reaxys-RN2214149
Merck Number6404
Chemical Name Translation1-萘胺-5-磺酸
LabNetwork Molecule IDLN01262364
InChIInChI=1S/C10H9NO3S/c11-9-5-1-4-8-7(9)3-2-6-10(8)15(12,13)14/h1-6H,11H2,(H,12,13,14)
Canonical SMILESO=S(C1=C2C=CC=C(N)C2=CC=C1)(O)=O
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分类

  • {SNA} Building Blocks, Chemical Synthesis, Organic Building Blocks, Sulfonic/Sulfinic Acids, Sulfur Compounds
  • {SA} Building Blocks, Chemical Synthesis, Organic Building Blocks, Sulfonic/Sulfinic Acids, Sulfur Compounds

产品应用

  • 该品是偶氮染料(酸性染料和活性染料)的中间体,也用于制造1-萘酚磺酸类产品。

相关文献及参考

  • Merck: 14,6404 Beilstein:14(3)2244
  • Merck: 14,6404

安全信息

GHS Symbol
Precautionary statements
  • P260 Do not breathe dust/fume/gas/mist/vapours/spray. 不要吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
  • P264+P265
  • P271 Use only outdoors or in a well-ventilated area.? 只能在室外或通风良好的地方使用。
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P301+P330+P331
  • P302+P350
  • P302+P352
  • P302+P352+P332+P313+P362+P364
  • P302+P361+P354
  • P303+P361+P353
  • P304+P312
  • P304+P340
  • P305+P351+P338
  • P305+P351+P338+P337+P313
  • P305+P354+P338
  • P310 Immediately call a POISON CENTER or doctor/physician. 立即呼救解毒中心或医生/医师。
  • P312 Call a POISON CENTER or doctor/physician if you feel unwell. 如果你感觉不适,呼叫解毒中心或医生/医师。
  • P316
  • P317
  • P319
  • P321 Specific treatment (see … on this label). 具体治疗(见本标签上的)。
  • P322 Specific measures (see …on this label). 具体治疗(见本标签上的)。
  • P332+P313
  • P332+P317
  • P337+P313
  • P337+P317
  • P362 Take off contaminated clothing and wash before reuse. 脱掉污染的衣服,清洗后方可重新使用
  • P362+P364
  • P363 Wash contaminated clothing before reuse. 被污染的衣服洗净后方可重新使用。
  • P403+P233
  • P405 Store locked up. 上锁保管。
  • P501 Dispose of contents/container to..… 处理内容物/容器.....
Hazard statements
  • H312 Harmful in contact with skin 皮肤接触有害
  • H314 Causes severe skin burns and eye damage 导致严重的皮肤灼伤和眼睛损伤
  • H315 Causes skin irritation 会刺激皮肤
  • H319 Causes serious eye irritation 严重刺激眼睛
  • H332 Harmful if inhaled 吸入有害
  • H335 May cause respiratory irritation 可能导致呼吸道刺激
Hazard Codes C
WGK Germany3
RTECSQK1270500
Personal Protective Equipment Eyeshields, Faceshields, full-face particle respirator type N100 (US), Gloves, respirator cartridge type N100 (US), type P1 (EN143) respirator filter, type P3 (EN 143) respirator cartridges
Signal word Danger
Safety Statements
  • S36/37/39 Wear suitable protective clothing, gloves and eye/face protection 穿戴适当的防护服、手套和眼睛/面保护;
  • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后,立即用大量水冲洗并征求医生意见;
  • S45 In case of accident or if you feel unwell seek medical advice immediately (show the label where possible) 发生事故时或感觉不适时,立即求医(可能时出示标签);
  • S37 Wear suitable gloves 戴适当手套;
Risk Statements
  • R34 Causes burns 会导致灼伤
  • R20/21/22 Harmful by inhalation, in contact with skin and if swallowed 吸入、皮肤接触和不慎吞咽有害
  • R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
UN Number UN 2585 8/PG 3 2585
Packing GroupIII
Hazard Class8
TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Intraperitoneal
SPECIES OBSERVED        : Rodent - mouse
DOSE/DURATION           : 2990 mg/kg
TOXIC EFFECTS :
   Behavioral - somnolence (general depressed activity)
   Behavioral - food intake (animal)
REFERENCE :
   GISAAA Gigiena i Sanitariya.  For English translation, see HYSAAV.  (V/O
   Mezhdunarodnaya Kniga, 113095 Moscow, USSR)  V.1-    1936-
   Volume(issue)/page/year: 51(1),87,1986

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Rodent - mouse
DOSE/DURATION           : >5 gm/kg
TOXIC EFFECTS :
   Behavioral - somnolence (general depressed activity)
   Behavioral - food intake (animal)
   Behavioral - muscle weakness
REFERENCE :
   GISAAA Gigiena i Sanitariya.  For English translation, see HYSAAV.  (V/O
   Mezhdunarodnaya Kniga, 113095 Moscow, USSR)  V.1-    1936-
   Volume(issue)/page/year: 51(1),87,1986

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Rodent - rat
DOSE/DURATION           : >5 gm/kg
TOXIC EFFECTS :
   Behavioral - somnolence (general depressed activity)
   Behavioral - food intake (animal)
   Behavioral - muscle weakness
REFERENCE :
   GISAAA Gigiena i Sanitariya.  For English translation, see HYSAAV.  (V/O
   Mezhdunarodnaya Kniga, 113095 Moscow, USSR)  V.1-    1936-
   Volume(issue)/page/year: 51(1),87,1986

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Intraperitoneal
SPECIES OBSERVED        : Rodent - rat
DOSE/DURATION           : 2880 mg/kg
TOXIC EFFECTS :
   Behavioral - somnolence (general depressed activity)
   Behavioral - food intake (animal)
REFERENCE :
   GISAAA Gigiena i Sanitariya.  For English translation, see HYSAAV.  (V/O
   Mezhdunarodnaya Kniga, 113095 Moscow, U

Storage condition 2-8°C, protect from light {LY} 2-8°C, protect from light {} {LY} 2-8°C, protect from light {} {} {LY} 2-8°C, protect from light {} {} {} {LY} 2-8°C, protect from light {} {} {} {} {LY} 2-8°C, protect from light {} {} {} {} {} {LY} 2-8°C, protect from light {} {} {} {} {} {} {LY} 2-8°C, protect from light {} {} {} {} {} {} {} {LY} 2-8°C, protect from light {} {} {} {} {} {} {} {} {LY} 2-8°C, protect from light {} {} {} {} {} {} {} {} {} {LY} 2-8°C, protect from light {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, protect from light {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, protect from light {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, protect from light {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, protect from light {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, protect from light {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, protect from light {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {}

其他信息

  • 溶于950份冷水中,较易溶于热水。经干燥或加热至110℃时变成无水物。该品的钠盐易溶于水和乙醇,稀水溶液呈淡绿色荧光。
  • 用途一:用于制备酸性染料和活性染料,也是制1-萘酚-5-磺酸的中间体
  • 下游产品:酸性黑B --> 丹酰氯 --> 5-二甲氨基-1-萘磺酸
  • 储运特性:库房通风低温干燥
  • 用途二:该品是偶氮染料的中间体,也用于制造1-萘酚磺酸类产品。
  • Sigma Aldrich:84-89-9(sigmaaldrich)
  • 用途三:该品是偶氮染料(酸性染料和活性染料)的中间体,也用于制造1-萘酚磺酸类产品。
  • 毒性分级:低毒
  • 急性毒性:口服-大鼠 LD50: >; 5000 毫克/公斤; 口服-小鼠LD50: LD50: >; 5000 毫克/公斤
  • TCI Shanghai:5-氨基-1-萘磺酸 5-Amino-1-naphthalenesulfonic Acid,>;98.0%(T)(84-89-9)
  • 方法一:萘经低温磺化得萘磺酸,用硝酸硝化得5-硝基-1-萘磺酸,再用碳酸镁中和分离出1-萘胺-8-磺酸镁盐,经铁粉还原、硫酸酸化制得周位酸。将中和分离得到的滤液进行还原、酸化即得1-萘胺-5-磺酸。
  • 可燃性危险特性:可燃;燃烧产生有毒氮氧化物和硫氧化物烟雾
  • 图谱信息:5-氨基-1-萘磺酸(84-89-9)红外图谱(IR1) 5-氨基-1-萘磺酸(84-89-9)质谱(MS) 5-氨基-1-萘磺酸(84-89-9)红外图谱(IR2)
  • Alfa Aesar:5-氨基萘-1-磺酸,97% 5-Aminonaphthalene-1-sulfonic acid, tech. 90%(84-89-9)
  • 5-氨基-1-萘磺酸价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2014/06/02 A0345 5-氨基-1-萘磺酸 5-Amino-1-naphthalenesulfonic Acid 25G 746元 2010/05/25 A11433 5-氨基萘-1-磺酸, 97% 5-Aminonaphthalene-1-sulfonic acid, tech. 90% 50g 924元 2010/05/25 A11433 5-氨基萘-1-磺酸, 97% 5-Aminonaphthalene-1-sulfonic acid, tech. 90% 25g 501元
  • 类别:有毒物品
  • 灭火剂:干粉、泡沫、砂土、二氧化碳, 雾状水
  • MOL 文件:84-89-9.mol
  • 上游原料:硫酸 --> 硝酸 --> 铁粉 --> 萘 --> 碳酸镁 --> 周位酸 --> 1-萘磺酸

系列性分类


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