Diethyl ((Methylthio)Methyl)Phosphonate 硫代甲氧基磷酸二乙酯
CAS 28460-01-7 MFCD00015131
化学结构图
SMILES: CSCP(=O)(OCC)OCC
化学属性
| Mol. Formula | C6H15O3PS |
|---|---|
| Mol. Weight | 198.22 |
| Density | 1.13 g/mL at 25 °C(lit.) |
| Boiling Point | 119-120 °C/10 mmHg(lit.) |
| Refractive index | 1.4650 to 1.4690 |
| Flash Point | 101°C(lit.) |
| TSCA | No |
别名和识别编码
| Chemical Name | Diethyl ((Methylthio)Methyl)Phosphonate |
|---|---|
| Synonym | 1-(diethoxyphosphoryl)methyl methyl sulphide Diethoxyphosphorylmethyl methyl sulfide Diethyl(methylthiomethyl)phosphonate Diethyl-(methylthiomethyl)-phosphonat [(Methylthio)methyl]phosphonic acid diethyl ester diethyl methylthiomethylphosphonate Methylsulfanylmethyl-phosphonic acid diethyl ester Methylthiomethylphosphonic acid diethyl ester (Methylmercapto)-methanphosphonsäurediethylester (methylsulfanyl-methyl)-phosphonic acid diethyl ester 甲硫甲基膦酸二乙酯 Diethyl (methylthiomethyl)phosphonate |
| MDL Number | MFCD00015131 |
| PubChem Substance ID | 87573168 |
| CAS Number | 28460-01-7 |
| Beilstein Registry Number | 1(4)3084 |
| Reaxys-RN | 1705833 |
| Chemical Name Translation | 硫代甲氧基磷酸二乙酯 |
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分类
- {SNA} C-C Bond Formation, Chemical Synthesis, Horner-Wadsworth-Emmons Reagents, Olefination, Synthetic Reagents
- {uni_hamburg} no charge; 1fragment
相关文献及参考
- Short: III/35C4 Title: Nuclear Magnetic Resonance (NMR) Data: Chemical Shifts and Coupling Constants for Hydrogen-1, Part 4: Inorganic and Organometallic Compounds Author: Gupta, R.R.; Platzer, N. Editor: Gupta, R.R.; Lechner, M.D. Source: Landolt-Börnstein, New Series Volume: III/35C4 Year: 2001 Keyword: Hydrogen 1; Nuclear Magnetic Resonance ISBN: 3-540-41059-7 ISBN: 978-3-540-41059-1 Internet Resource: DOI:10.1007/b76570 RefComment: VII, 299 pages. With CD-ROM. Hardcover Abstract: This volume provides a comprehensive and evaluated compilation of nuclear magnetic resonance data. Chemical shifts and coupling constants of boron-11 and phosphorus-31 (subvol. A), fluorine-19 and nitrogen-15 (subvol. B), hydrogen-1 (subvol. C), and carbon-13 (subvol. D) compounds are tabulated together with the gross- and structure formulas and the most readily available solvents. Due to the large amount of the data merely chemical shifts are presented in the printed versions, and all the data, chemical shifts and coupling constants are provided on CD-ROM's.
安全信息
- P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
- P362 Take off contaminated clothing and wash before reuse. 脱掉污染的衣服，清洗后方可重新使用
- P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
- P302+P352+P332+P313+P362+P364
- P332+P313
- P305+P351+P338+P337+P313
- P302+P350
- P337+P313
- P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
- P305+P351+P338
- H315 Causes skin irritation 会刺激皮肤
- H319 Causes serious eye irritation 严重刺激眼睛
- H335 May cause respiratory irritation 可能导致呼吸道刺激
GHS Symbol
- R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
- R20/21/22 Harmful by inhalation, in contact with skin and if swallowed 吸入、皮肤接触和不慎吞咽有害
- S37/39 Wear suitable gloves and eye/face protection 穿戴适当的手套和眼睛/面保护；
- S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后，立即用大量水冲洗并征求医生意见；
- S9 Keep container in a well-ventilated place 保持容器在通风良好的场所；
- S60 This material and its container must be disposed of as hazardous waste 该物质及其容器必须作为危险废物处置；
- S36/37 Wear suitable protective clothing and gloves 穿戴适当的防护服和手套；
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