三溴氧磷 氧溴化磷

CAS 7789-59-5 MFCD00036298

化学结构图

7789-59-5
SMILES: O=P(Br)(Br)Br

化学属性

Mol. FormulaBr3OP
Mol. Weight287
Boiling Point192
Density2.82
Melting Point56
SolubilityDecomposes in water. Soluble in ether, benzene, and sulfuric acid
TSCAYes
Stability对光敏感

别名和识别编码

Chemical Name三溴氧磷
Synonym Phosphoric tribromide Phosphoroxybromid Phosphorus (V) tribromide oxide Phosphorus bromide oxide (PBr3O) Phosphorus oxide bromide, Phosphoryl bromide Phosphorus oxide bromide,Phosphoryl bromide Phosphorus oxide bromide; Phosphoryl bromide Phosphorus oxybromide Phosphorus oxytribromide Phosphorus(V) Oxybromide {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {}
CAS Number7789-59-5
PubChem Substance ID24863480
EC Number232-177-7
MDL NumberMFCD00036298
Merck Number7348
Beilstein Registry Number2384789
Chemical Name Translation氧溴化磷
Reaxys-RN956582
LabNetwork Molecule IDLN00226992
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分类

  • {SNA} Bromination, C-X Bond Formation (Halogen), Chemical Synthesis, Synthetic Reagents
  • {SNA} Bromination, Building Blocks, C-X Bond Formation (Halogen), Chemical Synthesis, Organic Building Blocks, Other Phosphorus Compounds, Phosphorus Compounds, Synthetic Reagents
  • {uni_hamburg} no charge; 1fragment
  • {SNA} Bromination,

产品应用

  • 用于无机磷阻燃剂、含磷催化剂、磷引入剂、氧化剂等。

相关文献及参考

  • Merck: 14,7348
  • Short: II/25A
  • Short: III/35E
  • Short: III/20b

安全信息

GHS Symbol
WGK Germany3
Hazard Codes 8 C
Hazard statements
  • H314 Causes severe skin burns and eye damage 导致严重的皮肤灼伤和眼睛损伤
Personal Protective Equipment Eyeshields, Faceshields, full-face particle respirator type N100 (US), Gloves, respirator cartridge type N100 (US), type P1 (EN143) respirator filter, type P3 (EN 143) respirator cartridges
Precautionary statements
  • P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P301+P330+P331
  • P303+P361+P353
  • P304+P340
  • P305+P351+P338
  • P310 Immediately call a POISON CENTER or doctor/physician. 立即呼救解毒中心或医生/医师。
  • P405 Store locked up. 上锁保管。
  • P501 Dispose of contents/container to..… 处理内容物/容器.....
Signal word Danger
Safety Statements
  • S20 When using do not eat or drink 使用时,不得进食,饮水;
  • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后,立即用大量水冲洗并征求医生意见;
  • S30 Never add water to this product 切勿将水加入该产品中;
  • S36/37/39 Wear suitable protective clothing, gloves and eye/face protection 穿戴适当的防护服、手套和眼睛/面保护;
  • S43 In case of fire use ... (indicate in the space the precise type of fire-fighting equipment. If water increases the risk add -?Never use water) 着火时使用(指明具体的消防器材种类,如果用水增加危险,注明“禁止用水”
  • S45 In case of accident or if you feel unwell seek medical advice immediately (show the label where possible) 发生事故时或感觉不适时,立即求医(可能时出示标签);
  • S60 This material and its container must be disposed of as hazardous waste 该物质及其容器必须作为危险废物处置;
  • S8 Keep container dry 保持容器干燥;
UN Number 1939
Risk Statements
  • R14 Reacts violently with water 遇水会猛烈反应
  • R34 Causes burns 会导致灼伤
  • R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
Storage condition Moisture Sensitive N/A N/A℃ No Data Available 密封避光保存
Packing GroupII
Hazard Class8
Warnings 危化品目录(2015)
Restrict 危险品

其他信息

  • 溶于苯、乙醚、氯仿、二硫化碳、硫酸,在冷水中缓慢水解而生成磷酸和氢溴酸,

系列性分类


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