Tert-Butyl 2,2,2-Trichloroacetimidate 叔丁基-2,2,2-三氯乙酰亚胺酯

CAS 98946-18-0 MFCD00077410

化学结构图

98946-18-0
SMILES: CC(C)(C)OC(=N)C(Cl)(Cl)Cl

化学属性

Mol. FormulaC6H10Cl3NO
Mol. Weight219
Boiling Point65
Melting Point21
Refractive index1.4540 to 1.4580
Density1.221
Flash Point55°C(lit.)
TSCANo

别名和识别编码

Chemical NameTert-Butyl 2,2,2-Trichloroacetimidate
CAS Number98946-18-0
Alfabeta NameBUTYLTRICHLOROACETIMIDATE TERT222--,,
MDL NumberMFCD00077410
Synonym 叔丁基 2,2,2-三氯亚氨逐乙酸酯 叔丁基三氯乙酰亚胺酯 2,2,2-Trichloroacetimidic acid tert-butyl ester 叔丁基 2,2,2-三氯亚氨逐乙酸酯 TBTA 叔丁基 2,2,2-三氯乙酰亚胺酯
PubChem Substance ID87564409
Beilstein Registry Number1770049
EC Number000-000-0
Reaxys-RN1770049
Chemical Name Translation叔丁基-2,2,2-三氯乙酰亚胺酯
LabNetwork Molecule IDLN00010888
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分类

  • {SNA} Amidates/Imidates, Building Blocks, Chemical Synthesis, Nitrogen Compounds, Organic Building Blocks

产品应用

  • 用于醇和羧酸的转化,生成他们各自的醚和酯。

相关文献及参考

  • Reagent for preparation of t-butyl ethers and esters under mild conditions: J. Chem. Soc., Perkin 1, 2247 (1985); Tetrahedron Lett., 29, 2483 (1988). See also Appendix 6.

安全信息

Warnings MOISTURE SENSITIVE, FLAMMABLE
GHS Symbol
WGK Germany3
Hazard statements
  • H226 Flammable liquid and vapour 易燃液体和蒸气
  • H315 Causes skin irritation 会刺激皮肤
  • H335 May cause respiratory irritation 可能导致呼吸道刺激
  • H302 Harmful if swallowed 吞食有害
  • H319 Causes serious eye irritation 严重刺激眼睛
Personal Protective Equipment Eyeshields, Faceshields, full-face respirator (US), Gloves, multi-purpose combination respirator cartridge (US), type ABEK (EN14387) respirator filter
Precautionary statements
  • P210 Keep away from heat/sparks/open flames/hot surfaces. — No smoking. 远离热源/火花/明火/热的表面。——禁止吸烟。
  • P233 Keep container tightly closed. ?保持容器密闭。
  • P240 Ground/bond container and receiving equipment. 与地面接触/连接集装箱和接受设备。
  • P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P302+P352+P332+P313+P362+P364
  • P305+P351+P338
  • P305+P351+P338+P337+P313
  • P362 Take off contaminated clothing and wash before reuse. 脱掉污染的衣服,清洗后方可重新使用
  • P501 Dispose of contents/container to..… 处理内容物/容器.....
Signal word Warning
Packing GroupIII
UN Number 1993
Risk Statements
  • R10 Flammable 易燃
  • R22 Harmful if swallowed 吞咽有害
  • R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
Safety Statements
  • S24/25 Avoid contact with skin and eyes 避免皮肤和眼睛接触;
Storage condition Moisture Sensitive 0-10°C 储存温度2-8°C
Hazard Codes 3
Hazard Class3

系列性分类


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