(S)-(+)-Tetrahydrofurfurylamine (S)-(+)-2-四氢呋喃甲胺

CAS 7175-81-7 MFCD00085303

化学结构图

7175-81-7
SMILES: NCC1CCCO1

化学属性

Mol. FormulaC5H11NO
Mol. Weight101.15
Refractive index1.4520 to 1.4560
Boiling Point152-153°C at 760 mmHg
Density0.98 g/mL at 25 °C(lit.)
Flash Point46°C
TSCANo

别名和识别编码

Chemical Name(S)-(Tetrahydrofuran-2-yl)methanamine
CAS Number7175-81-7
PubChem Substance ID641530
MDL NumberMFCD00085303
Reaxys-RN5725996
Synonym (S)-Tetrahydrofurfurylamine {LY} (S)-Tetrahydrofurfurylamine {} {LY} (S)-Tetrahydrofurfurylamine {} {} {LY} (S)-Tetrahydrofurfurylamine {} {} {} {LY} (S)-Tetrahydrofurfurylamine {} {} {} {} {LY} (S)-Tetrahydrofurfurylamine {} {} {} {} {} {LY} (S)-Tetrahydrofurfurylamine {} {} {} {} {} {} {LY} (S)-Tetrahydrofurfurylamine {} {} {} {} {} {} {} {LY} (S)-Tetrahydrofurfurylamine {} {} {} {} {} {} {} {} {LY} (S)-Tetrahydrofurfurylamine {} {} {} {} {} {} {} {} {} {LY} (S)-Tetrahydrofurfurylamine {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} (S)-Tetrahydrofurfurylamine {} {} {} {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {} {} {} {LY} (S)-Tetrahydrofurfurylamine {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} (S)-Tetrahydrofurfurylamine {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} (S)-Tetrahydrofurfurylamine {} {} {} {} {} {} {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {}
Beilstein Registry Number5725996
Chemical Name Translation(S)-(+)-2-四氢呋喃甲胺
LabNetwork Molecule IDLN00335868
InChIInChI=1S/C5H11NO/c6-4-5-2-1-3-7-5/h5H,1-4,6H2/t5-/m0/s1
Canonical SMILESNC[C@@H]1CCCO1
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分类

  • Asymmetric Synthesis, Chemical Synthesis, Chiral Building Blocks, Furans, Heterocyclic Building Blocks
  • {SNA} Asymmetric Synthesis, Chemical Synthesis, Chiral Building Blocks, Furans, Heterocyclic Building Blocks

相关文献及参考

  • Beilstein: 18,9,488

安全信息

GHS Symbol
WGK Germany3
Hazard Codes Xi
Hazard statements
  • H226 Flammable liquid and vapour 易燃液体和蒸气
  • H315 Causes skin irritation 会刺激皮肤
  • H319 Causes serious eye irritation 严重刺激眼睛
  • H335 May cause respiratory irritation 可能导致呼吸道刺激
Personal Protective Equipment Eyeshields, Faceshields, full-face respirator (US), Gloves, multi-purpose combination respirator cartridge (US), type ABEK (EN14387) respirator filter
Precautionary statements
  • P210 Keep away from heat/sparks/open flames/hot surfaces. — No smoking. 远离热源/火花/明火/热的表面。——禁止吸烟。
  • P233 Keep container tightly closed. ?保持容器密闭。
  • P240 Ground/bond container and receiving equipment. 与地面接触/连接集装箱和接受设备。
  • P241 Use explosion-proof electrical/ventilating/lighting/…/equipment. 使用防爆电气/通风/照明/ .../设备。
  • P242 Use only non-sparking tools. 只能使用无火花工具。
  • P243 Take precautionary measures against static discharge. 采取预防措施,防止静电放电。
  • P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
  • P264+P265
  • P271 Use only outdoors or in a well-ventilated area.? 只能在室外或通风良好的地方使用。
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P302+P352
  • P303+P361+P353
  • P304+P340
  • P305+P351+P338
  • P305+P351+P338+P337+P313
  • P312 Call a POISON CENTER or doctor/physician if you feel unwell. 如果你感觉不适,呼叫解毒中心或医生/医师。
  • P319
  • P321 Specific treatment (see … on this label). 具体治疗(见本标签上的)。
  • P332+P313
  • P332+P317
  • P337+P313
  • P337+P317
  • P362 Take off contaminated clothing and wash before reuse. 脱掉污染的衣服,清洗后方可重新使用
  • P362+P364
  • P370+P378
  • P403+P233
  • P403+P235
  • P405 Store locked up. 上锁保管。
  • P501 Dispose of contents/container to..… 处理内容物/容器.....
Signal word Warning
UN Number UN 2943 3/PG 3 UN2943 2943
Risk Statements
  • R10 Flammable 易燃
  • R34 Causes burns 会导致灼伤
  • R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
Safety Statements
  • S37/39 Wear suitable gloves and eye/face protection 穿戴适当的手套和眼睛/面保护;
  • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后,立即用大量水冲洗并征求医生意见;
  • S16 Keep away from sources of ignition - No smoking 远离火源,禁止吸烟;
  • S36/37/39 Wear suitable protective clothing, gloves and eye/face protection 穿戴适当的防护服、手套和眼睛/面保护;
  • S20 When using do not eat or drink 使用时,不得进食,饮水;
  • S45 In case of accident or if you feel unwell seek medical advice immediately (show the label where possible) 发生事故时或感觉不适时,立即求医(可能时出示标签);
  • S23 Do not breathe gas/fumes/vapour/spray (appropriate wording to be specified by the manufacturer) 不要吸入气体/烟雾/蒸汽/喷雾;
Storage condition 2-8°C, protect from light {LY} 2-8°C, protect from light Flammables area Hygroscopic {} {LY} 2-8°C, protect from light {} {} {LY} 2-8°C, protect from light {} {} {} {LY} 2-8°C, protect from light {} {} {} {} {LY} 2-8°C, protect from light {} {} {} {} {} {LY} 2-8°C, protect from light {} {} {} {} {} {} {LY} 2-8°C, protect from light {} {} {} {} {} {} {} {LY} 2-8°C, protect from light {} {} {} {} {} {} {} {} {LY} 2-8°C, protect from light {} {} {} {} {} {} {} {} {} {LY} 2-8°C, protect from light {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, protect from light {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, protect from light {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, protect from light {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, protect from light {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, protect from light {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, protect from light {} {} {} {} {} {} {} {} {} {} {} {} {} {} {
Packing GroupIII
Hazard Class3

其他信息

  • TCI Shanghai:(S)-(+)-2-四氢糠胺 (S)-(+)-Tetrahydrofurfurylamine,>;98.0%(GC)(T)(7175-81-7)
  • F:10-34
  • MOL 文件:7175-81-7.mol
  • MSDS 信息:(S)-(+)-2-(Aminomethyl)tetrahydrofurane(7175-81-7).msds
  • Alfa Aesar:(S)-(+)-四氢呋喃甲胺,98+% (S)-(+)-Tetrahydrofurfurylamine, 98+%(7175-81-7)
  • Acros Organics:(s)-(+)-四氢糠胺 (S)-(+)-Tetrahydrofurfurylamine, 98%(7175-81-7)
  • (S)-(+)-四氢糠胺价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2014/06/02 T2552 (S)-(+)-2-四氢糠胺 (S)-(+)-Tetrahydrofurfurylamine 200MG 422元 2014/06/02 T2552 (S)-(+)-2-四氢糠胺 (S)-(+)-Tetrahydrofurfurylamine 1G 1280元 2010/05/25 L10790 (S)-(+)-四氢呋喃甲胺, 98+% (S)-(+)-Tetrahydrofurfurylamine, 98+% 250mg 416元
  • 比旋光度:13.5 ° (c=4, MeOH)
  • Sigma Aldrich:7175-81-7(sigmaaldrich)

系列性分类


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