(R)-(+)-1-(2-Naphthyl)ethylamine (R)-(+)-1-(2-萘基)乙胺

CAS 3906-16-9 MFCD00085367

化学结构图

3906-16-9
SMILES: C[C@@H](N)C1C=C2C=CC=CC2=CC=1 |&1:1|

化学属性

Mol. FormulaC12H13N
Mol. Weight171.24
Melting Point47-50°C
TSCANo
Boiling Point301°C at 760 mmHg
Flash Point144.3°C
Stability对空气敏感

别名和识别编码

Chemical Name(R)-(+)-1-(2-Naphthyl)ethylamine
MDL NumberMFCD00085367
CAS Number3906-16-9
Beilstein Registry Number12(3)3113
Synonym (R)-(+)-1-(2-Naphthyl)ethylamine {LY} (R)-(+)-1-(2-Naphthyl)ethylamine {} {LY} (R)-(+)-1-(2-Naphthyl)ethylamine {} {} {LY} (R)-(+)-1-(2-Naphthyl)ethylamine {} {} {} {LY} (R)-(+)-1-(2-Naphthyl)ethylamine {} {} {} {} {LY} (R)-(+)-1-(2-Naphthyl)ethylamine {} {} {} {} {} {LY} (R)-(+)-1-(2-Naphthyl)ethylamine {} {} {} {} {} {} {LY} (R)-(+)-1-(2-Naphthyl)ethylamine {} {} {} {} {} {} {} {LY} (R)-(+)-1-(2-Naphthyl)ethylamine {} {} {} {} {} {} {} {} {LY} (R)-(+)-1-(2-Naphthyl)ethylamine {} {} {} {} {} {} {} {} {} {LY} (R)-(+)-1-(2-Naphthyl)ethylamine {} {} {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {} {} {LY} (R)-(+)-1-(2-Naphthyl)ethylamine {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} (R)-(+)-1-(2-Naphthyl)ethylamine {} {} {} {} {} {} {} {} {} {} {} {} {LY} (R)-(+)-1-(2-Naphthyl)ethylamine {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} (R)-(+)-1-(2-Naphthyl)ethylamine {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} (R)-(+)-1-(2-Naphthyl)ethy
PubChem Substance ID87560058
Reaxys-RN3195950
Chemical Name Translation(R)-(+)-1-(2-萘基)乙胺
InChIInChI=1S/C12H13N/c1-9(13)11-7-6-10-4-2-3-5-12(10)8-11/h2-9H,13H2,1H3/t9-/m1/s1
LabNetwork Molecule IDLN00240064
Canonical SMILESC[C@@H](N)C1=CC=C2C=CC=CC2=C1
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分类

  • {SNA} Amines, Asymmetric Synthesis, Chemical Synthesis, Chiral Building Blocks, Organic Building Blocks
  • {SNA} Amines, Asymmetric Synthesis, Chemical Synthesis, Chiral Building Blocks, Chiral Resolution Reagents, Chiral Resolving Reagents, Organic Building Blocks

产品应用

  • 常用的手性胺类，研究乙酰胺的醇醛反应。

相关文献及参考

  • Beilstein:12(3)3113

安全信息

Safety Statements
  • S36 Wear suitable protective clothing 穿戴适当的防护服；
  • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后，立即用大量水冲洗并征求医生意见；
  • S61 Avoid release to the environment. Refer to special instructions/safety data sheet 避免释放到环境中，参考特别指示/安全收据说明书；
  • S36/37/39 Wear suitable protective clothing, gloves and eye/face protection 穿戴适当的防护服、手套和眼睛/面保护；
  • S45 In case of accident or if you feel unwell seek medical advice immediately (show the label where possible) 发生事故时或感觉不适时，立即求医（可能时出示标签）；
Packing GroupIII
UN Number UN3259
Risk Statements
  • R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
  • R21/22 Harmful in contact with skin and if swallowed 皮肤接触和不慎吞咽有害
  • R34 Causes burns 会导致灼伤
  • R51/53
Storage condition 2-8°C, protect from light {LY} 2-8°C, protect from light Air Sensitive {} {LY} 2-8°C, protect from light {} {} {LY} 2-8°C, protect from light {} {} {} {LY} 2-8°C, protect from light {} {} {} {} {LY} 2-8°C, protect from light {} {} {} {} {} {LY} 2-8°C, protect from light {} {} {} {} {} {} {LY} 2-8°C, protect from light {} {} {} {} {} {} {} {LY} 2-8°C, protect from light {} {} {} {} {} {} {} {} {LY} 2-8°C, protect from light {} {} {} {} {} {} {} {} {} {LY} 2-8°C, protect from light {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, protect from light {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, protect from light {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, protect from light {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, protect from light {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, protect from light {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, protect from light {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, protect from
Hazard Codes Xi,N Xi
WGK Germany3
GHS Symbol
Precautionary statements
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P362 Take off contaminated clothing and wash before reuse. 脱掉污染的衣服，清洗后方可重新使用
  • P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
  • P332+P313
  • P305+P351+P338+P337+P313
  • P302+P350
  • P337+P313
  • P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P305+P351+P338
  • P273 Avoid release to the environment. 避免释放到环境中。
  • P302+P352+P332+P313+P362+P364
Hazard statements
  • H315 Causes skin irritation 会刺激皮肤
  • H319 Causes serious eye irritation 严重刺激眼睛
  • H335 May cause respiratory irritation 可能导致呼吸道刺激
  • H411 Toxictoaquaticlifewithlonglastingeffects 对水生生物有毒性并具有长期影响。
Signal word Warning
Personal Protective Equipment dust mask type N95 (US), Eyeshields, Gloves

系列性分类

  1. Chemical Synthesis 化学合成
  2. Asymmetric Synthesis 不对称合成
  3. Chiral Resolution Reagents - Asymmetric Synthesis
  4. Chiral Resolving Reagents - Chiral Resolution Reagents
  1. Chemical Synthesis 化学合成
  2. Asymmetric Synthesis 不对称合成
  3. Chiral Resolution Reagents - Asymmetric Synthesis
  4. Chiral Resolving Reagents - Chiral Resolution Reagents
  1. Chemical Synthesis 化学合成
  2. Asymmetric Synthesis 不对称合成
  3. Chiral Building Blocks 手性分子砌块
  4. Organic Building Blocks - Chiral Building Blocks
  5. Amines - Organic Building Blocks

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