(R)-(+)-N-Benzyl-1-Phenylethylamine (R)-(+)-N-苄基-1-苯乙胺

CAS 38235-77-7 MFCD00015010

化学结构图

38235-77-7
SMILES: C[C@@H](NCc1ccccc1)c1ccccc1

化学属性

Mol. FormulaC15H18ClN
Mol. Weight248
Refractive index1.5620 to 1.5640
Boiling Point171
Density1.01
Flash Point158°C(lit.)
TSCANo
Stability对空气敏感
pH:A

别名和识别编码

Chemical Name(R)-(+)-N-Benzyl-1-Phenylethylamine
CAS Number38235-77-7
Alfabeta NameBENZYLPHENYLETHYLAMINE R+N1()-----
MDL NumberMFCD00015010
Synonym (R)-(+)-N-(1-Phenylethyl)benzylamine (R)-(+)-N-(1-苯乙基)苄胺 (R)-(+)-N-(1-苯乙基)苄胺 (R)-(+)-N-苄基-1-苯乙胺 (R)-(+)-N-苄基-1-苯乙胺 (R)-(+)-N-苄基-α-甲基苄胺
PubChem Substance ID87564434
Beilstein Registry Number3589990
Reaxys-RN3589990
EC Number250-023-7
Chemical Name Translation(R)-(+)-N-苄基-1-苯乙胺
LabNetwork Molecule IDLN00174318
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分类

  • {SNA} Amines, Asymmetric Synthesis, Chemical Synthesis, Chiral Building Blocks, Organic Building Blocks
  • {SA} Amines, Asymmetric Synthesis, Chemical Synthesis, Chiral Building Blocks, Organic Building Blocks
  • {SNA} Asymmetric Synthesis, Chemical Synthesis, Chiral Building Blocks, Organic Building Blocks,

相关文献及参考

  • N-Metallated derivatives are useful chiral bases. The Mg derivative effects the enantioselective deprotonation of 2,6-disubstituted cyclohexanones: Chem. Commun., 479 (2000); Synlett, 1253 (2001); 1017 (2003):

安全信息

Warnings IRRITANT
GHS Symbol
WGK Germany3
Hazard statements
  • H315 Causes skin irritation 会刺激皮肤
  • H319 Causes serious eye irritation 严重刺激眼睛
  • H335 May cause respiratory irritation 可能导致呼吸道刺激
  • H302 Harmful if swallowed 吞食有害
Personal Protective Equipment Eyeshields, full-face respirator (US), Gloves, multi-purpose combination respirator cartridge (US), type ABEK (EN14387) respirator filter
Precautionary statements
  • P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P302+P352+P332+P313+P362+P364
  • P305+P351+P338
  • P305+P351+P338+P337+P313
  • P332+P313
  • P362 Take off contaminated clothing and wash before reuse. 脱掉污染的衣服，清洗后方可重新使用
Signal word Warning
Risk Statements
  • R22 Harmful if swallowed 吞咽有害
  • R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
  • R36/38 Irritating to eyes and skin 对眼睛和皮肤有刺激性
Safety Statements
  • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后，立即用大量水冲洗并征求医生意见；
  • S36 Wear suitable protective clothing 穿戴适当的防护服；
  • S36/37 Wear suitable protective clothing and gloves 穿戴适当的防护服和手套；
  • S36/37/39 Wear suitable protective clothing, gloves and eye/face protection 穿戴适当的防护服、手套和眼睛/面保护；
Storage condition 对空气敏感,密封保存. Air Sensitive
Hazard Codes Xn Xi

系列性分类

  1. Chemical Synthesis 化学合成
  2. Asymmetric Synthesis 不对称合成
  1. Chemical Synthesis 化学合成
  2. Asymmetric Synthesis 不对称合成
  3. Chiral Building Blocks 手性分子砌块
  4. Organic Building Blocks - Chiral Building Blocks
  5. Amines - Organic Building Blocks
  1. Chemical Synthesis 化学合成
  2. Asymmetric Synthesis 不对称合成
  3. Chiral Building Blocks 手性分子砌块
  4. Organic Building Blocks - Chiral Building Blocks
  5. Amines - Organic Building Blocks
  1. Chemical Synthesis 化学合成
  2. Asymmetric Synthesis 不对称合成
  3. Chiral Building Blocks 手性分子砌块
  4. Organic Building Blocks - Chiral Building Blocks
  5. Protected Amines - Organic Building Blocks
  1. Chemical Synthesis 化学合成
  2. Asymmetric Synthesis 不对称合成
  3. Chiral Building Blocks 手性分子砌块
  4. Organic Building Blocks - Chiral Building Blocks
  5. Amides - Organic Building Blocks
  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Organic Building Blocks 有机砌块
  4. Amides 酰胺

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